according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 07/07/2015 Version: 1.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Product name : Mixture : Foundation MVR Other means of identification : 7-21-1-.5 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture 1.3. Details of the supplier of the safety data sheet MarVista Resources 745 North Ave. Corcoran, Ca. 93212 - USA T 559-992-4535 1.4. Emergency telephone number : Agricultural industry Fertilizer Emergency number : 24 Hour Emergency Response Chemtrec: 1-800-424-9300 SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Eye Irrit. 2A Full text of H-phrases: see section 16 H319 2.2. Label elements GHS-US labelling Hazard pictograms (GHS-US) : Signal word (GHS-US) Hazard statements (GHS-US) Precautionary statements (GHS-US) GHS07 : Warning : H319 - Causes serious eye irritation : P264 - Wash face, hands thoroughly after handling P280 - Wear eye protection, protective clothing P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P337+P313 - If eye irritation persists: Get medical advice/attention 2.3. Other hazards 2.4. Unknown acute toxicity (GHS US) SECTION 3: Composition/information on ingredients 3.1. Substance 3.2. Mixture 07/07/2015 EN (English) Page 1
Name Product identifier % GHS-US classification urea (CAS No) 57-13-6 1.644 Eye Irrit. 2B, H320 zinc sulfate, monohydrate (CAS No) 7446-19-7 1.35356 Acute Tox. 4 (Oral), H302 Eye Dam. 1, H318 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 Ammonium Citrate Tribasic (CAS No) 3458-72-8 1.025976 Skin Irrit. 2, H315 Eye Irrit. 2B, H320 Full text of H-phrases: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation Symptoms/injuries after skin contact Symptoms/injuries after eye contact Symptoms/injuries after ingestion : Remove person to fresh air and keep comfortable for breathing. : Wash skin with plenty of water. Take off contaminated clothing. If skin irritation occurs: Get medical advice/attention. : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. : May cause slight irritation. : Irritation. : Eye irritation. : May cause gastrointestinal discomfort. 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media 5.2. Special hazards arising from the substance or mixture Reactivity 5.3. Advice for firefighters Protection during firefighting SECTION 6: Accidental release measures : Water spray. Dry powder. Foam. Carbon dioxide. 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel Emergency procedures 6.1.2. For emergency responders Protective equipment 6.2. Environmental precautions Avoid release to the environment. 6.3. Methods and material for containment and cleaning up For containment Methods for cleaning up Other information : The product is non-reactive under normal conditions of use, storage and transport. : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. : Ventilate spillage area. Avoid contact with skin and eyes. : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection". : Dam up the liquid spill. : Take up liquid spill into absorbent material. : Dispose of materials or solid residues at an authorized site. 6.4. Reference to other sections For further information refer to section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Ensure good ventilation of the work station. Avoid contact with skin and eyes. Wear personal protective equipment. : Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. Always wash hands after handling the product. 07/07/2015 EN (English) 2/7
7.2. Conditions for safe storage, including any incompatibilities Storage conditions Incompatible products : Store in a well-ventilated place. Keep cool. : Strong oxidisers. 7.3. Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters Foundation MVR Ammonium Citrate Tribasic (3458-72-8) 8.2. Exposure controls Appropriate engineering controls Hand protection Eye protection Skin and body protection Respiratory protection Environmental exposure controls : Ensure good ventilation of the work station. : Protective gloves. : Safety glasses. : Wear suitable protective clothing. : In case of insufficient ventilation, wear suitable respiratory equipment. : Avoid release to the environment. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Liquid. Colour : Yellow-brown Odour : characteristic Odour threshold ph : 7-8 Melting point : Freezing point Boiling point : > 100 C Flash point : Not Available Relative evaporation rate (butylacetate=1) Flammability (solid, gas) Explosive limits Explosive properties Oxidising properties Vapour pressure Relative density Relative vapour density at 20 C Density : 1.26 g/ml Solubility : Water: Solubility in water of component(s) of the mixture : 07/07/2015 EN (English) 3/7
Log Pow Log Kow Auto-ignition temperature Decomposition temperature Viscosity Viscosity, kinematic Viscosity, dynamic 9.2. Other information SECTION 10: Stability and reactivity 10.1. Reactivity The product is non-reactive under normal conditions of use, storage and transport. 10.2. Chemical stability Stable under normal conditions. 10.3. Possibility of hazardous reactions No dangerous reactions known under normal conditions of use. 10.4. Conditions to avoid None under recommended storage and handling conditions (see section 7). 10.5. Incompatible materials Strong oxidisers. 10.6. Hazardous decomposition products SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity LD50 oral rat LD50 dermal rat LD50 dermal rabbit ATE US (oral) ATE US (oral) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Symptoms/injuries after inhalation 8471 mg/kg (Rat; OECD 401: Acute Oral Toxicity; Literature study; 14300 mg/kg bodyweight; Rat; Experimental value) > 3200 mg/kg (Rat; Literature study) > 21000 mg/kg (Rabbit; Literature study) 8471.000 mg/kg bodyweight 500.000 mg/kg bodyweight ph: 7-8 : Causes serious eye irritation. ph: 7-8 : May cause slight irritation. 07/07/2015 EN (English) 4/7
Symptoms/injuries after skin contact Symptoms/injuries after eye contact Symptoms/injuries after ingestion SECTION 12: Ecological information 12.1. Toxicity Ecology - general LC50 fish 1 EC50 Daphnia 1 LC50 fish 2 EC50 Daphnia 2 TLM fish 1 Threshold limit other aquatic organisms 1 Threshold limit other aquatic organisms 2 Threshold limit algae 1 Threshold limit algae 2 LC50 fish 1 EC50 Daphnia 1 LC50 fish 2 EC50 Daphnia 2 : Irritation. : Eye irritation. : May cause gastrointestinal discomfort. : The product is not considered harmful to aquatic organisms nor to cause long-term adverse effects in the environment. > 6810 mg/l (96 h; Leuciscus idus; Nominal concentration) > 10000 mg/l (48 h; Daphnia magna; Nominal concentration) 17500 mg/l (96 h; Poecilia reticulata) > 10000 mg/l (24 h; Daphnia magna) 17500 ppm (96 h; Poecilia reticulata) 120000 mg/l (16 h; Bacteria; Toxicity test) > 10000 mg/l (Pseudomonas putida) > 10000 mg/l (168 h; Scenedesmus quadricauda; Growth rate) 47 mg/l (192 h; Microcystis aeruginosa; Growth rate) 1.7 mg/l (96 h; Poecilia reticulata; Anhydrous form) 0.56 mg/l (48 h; Daphnia magna; Anhydrous form) 2.4 mg/l (96 h; Salmo gairdneri (Oncorhynchus mykiss); Anhydrous form) 1 mg/l (24 h; Daphnia magna; Anhydrous form) 12.2. Persistence and degradability Persistence and degradability ThOD Persistence and degradability Biochemical oxygen demand (BOD) Chemical oxygen demand (COD) ThOD BOD (% of ThOD) Inherently biodegradable. Hydrolysis in water. Highly mobile in soil. 0.27 g O₂ /g substance Biodegradability: not applicable. 12.3. Bioaccumulative potential BCF fish 1 BCF other aquatic organisms 1 Log Pow Bioaccumulative potential BCF fish 1 BCF fish 2 Bioaccumulative potential 1 (72 h; Brachydanio rerio; Fresh water) 11700 (Chlorella sp.) < -1.73 (Experimental value; EU Method A.8: Partition Coefficient) Bioaccumulation: not applicable. 59-242 (Cyprinus carpio; Anhydrous form) 59-242 (Cyprinus carpio; Test duration: 8 weeks) Bioaccumable. 12.4. Mobility in soil 12.5. Other adverse effects Effect on the global warming : No known ecological damage caused by this product. 07/07/2015 EN (English) 5/7
SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations SECTION 14: Transport information : Dispose in a safe manner in accordance with local/national regulations. Department of Transportation (DOT) In accordance with DOT Not regulated for transport Additional information Other information : No supplementary information available. ADR Transport by sea Air transport SECTION 15: Regulatory information 15.1. US Federal regulations Foundation MVR Not listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on the United States TSCA (Toxic Substances Control Act) inventory Ammonium Citrate Tribasic (3458-72-8) Listed on the United States TSCA (Toxic Substances Control Act) inventory Not listed on the United States TSCA (Toxic Substances Control Act) inventory 15.2. International regulations CANADA EU-Regulations Classification according to Regulation (EC) No. 1272/2008 [CLP] Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] Not classified National regulations 15.3. US State regulations SECTION 16: Other information Indication of changes Training advice : Updated to GHS-US format. : Normal use of this product shall imply use in accordance with the instructions on the packaging. 07/07/2015 EN (English) 6/7
Full text of H-phrases: ------ Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 ------ Aquatic Acute 1 Hazardous to the aquatic environment Acute Hazard, Category 1 ------ Aquatic Chronic 1 Hazardous to the aquatic environment Chronic Hazard, Category 1 ------ Eye Dam. 1 Serious eye damage/eye irritation, Category 1 ------ Eye Irrit. 2A Serious eye damage/eye irritation, Category 2A ------ Eye Irrit. 2B Serious eye damage/eye irritation, Category 2B ------ Skin Irrit. 2 Skin corrosion/irritation, Category 2 ------ H302 Harmful if swallowed ------ H315 Causes skin irritation ------ H318 Causes serious eye damage ------ H319 Causes serious eye irritation ------ H320 Causes eye irritation ------ H400 Very toxic to aquatic life ------ H410 Very toxic to aquatic life with long lasting effects NFPA health hazard NFPA fire hazard NFPA reactivity : 1 - Exposure could cause irritation but only minor residual injury even if no treatment is given. : 0 - Materials that will not burn. : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. SDS US (GHS HazCom 2012) All information contained in this is furnished free of charge and is intended for your evaluation. In our opinion the information is, as of the date of this, reliable, however, it is your responsibility to determiine the suitability of the information for your use. You are advised not to construe the information as absolutely complete since additonal information may be necessary or desirable when particular, exceptional or variable conditions or circumstances exist or because of applicable laws or government regulations. Therefore, you should use this information only as a supplement to other informations gathered by you, and you must make independent determinations of the suitability and completeness of the information from all souces to assure both proper use of the material described herein and the safety and health of employees. Accordingly, no guarantee is expressed or implied as to the results to be obtained based upon your use of the information. 07/07/2015 EN (English) 7/7