Rusty Boicourt, P.G. NDE & Materials Specialist Materials Testing & Inspection

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Corrosion Damaged Concrete Causes & Repair Presented by Rusty Boicourt, P.G. NDE & Materials Specialist Materials Testing & Inspection

Examples of Corrosion Damage

Examples of Corrosion Damage

Examples of Corrosion Damage

Examples of Corrosion Damage

Examples of Corrosion Damage

Examples of Corrosion Damage

Corrosion of Embedded Metals Steel is not naturally occurring: highly processed. Metals are thermodynamically unstable (except gold and platinum). Release energy and revert to natural iron oxide. Corrosion occurs when: Two metals or two sites having different energy levels. An electrolyte (concrete). A metallic connection.

Causes of Corrosion Damage Steel reinforcing is protected by a passive oxide layer on the rebar surface. Passive corrosion rate of <0.1µm/year. The high ph prevents corrosion of rebar even in wet conditions. Image courtesy PCA

Causes of Corrosion Damage Chloride Chloride (Chlorine ion, Cl-) penetrates into concrete from environmental sources. Migration of chloride occurs by diffusion according to Ficke s 2 nd Law. At >0.1% weight of cement, corrosion begins. Chloride destroys the passive layer: corrosion rate increases by >1000X.

Causes of Corrosion Damage Chloride Profile Acid-Soluble Chlor ride (wt%) 0.3 0.25 0.2 0.15 0.1 0.05 0 0.22 corrosion initiation threshold 0.18 0.15 top rebar y = 0.3217e -0.191x middle rebar diffusion curve 0 1 2 3 4 5 6 7 8 9 10 11 12 Depth (inches)

Causes of Corrosion Damage Chloride Anode cells develop within charged regions of the concrete. Water and air sustain the reaction. As long as chloride is present, corrosion continues. Image courtesy PCA

Causes of Corrosion Damage Sources of Chloride Seawater spray Chloride-based accelerant admixtures De-icing agents: MgCl, MgSO 4, NaSO 4, NaCl, KCl

Causes of Corrosion Damage Carbonation High ph prevents corrosion of steel even in wet conditions. Cement is composed of C-S-H. Once exposed to CO 2 in the atmosphere, C-S-H converts to CaCO 3. CaCO 3 is acidic and changes the high ph to low ph. This allows corrosion of steel, provided O 2 is present.

Causes of Corrosion Damage Phenolphthalein carbonation test.

Causes of Corrosion Damage Dissimilar Metals Much more rare than chloride and carbonation problems. Aluminum handrails embedded in steel reinforced concrete. Bronze items embedded in steel reinforced concrete.

Causes of Corrosion Damage Cracking and Cover Problems Minimum cover thickness is intended to protect rebar from carbonation and chloride exposure. Flexural cracks in beams open pathways for air and moisture. Inadequate cover thickness reduces the durability of reinforcing.

The Problem of Corrosion Loss of anchorage Cracking and spalling of cover Section loss

The Problem of Corrosion Loss of Anchorage FeO 2 is a friable mineral; scale forms quickly. The bond between concrete and steel is lost soon after the onset of corrosion. Development of the rebar is lost for the length of segment corroded.

The Problem of Corrosion Cracking and Spalling of Cover FeO 2 expands in volume, force exceeds tensile strength of concrete. Exposure leads to acceleration of corrosion. Compromises adjacent elements of the structure. Poses a safety risk for people and equipment. Looks really bad.

The Problem of Corrosion Section Loss Typical occurs last in the progression of failure. >10% loss seems to be cause for concern. >15% loss seems to be cause for panic. Rebar surface becomes brittle. Must be considered when restoring rebar.

The Problem of Corrosion Section Loss Repair by lap splice per ACI 318. Image courtesy ICRI

The Problem of Corrosion

Repair of Corrosion Damage So we have corrosion, now what? Evaluate the nature and extent of corrosion. What is damage condition: minor/moderate/severe? Can we salvage the rebar? How much corrosion is not yet evident?

Repair of Corrosion Damage Evaluate the Nature and Extent Crack mapping: ACI 201.1R-08 Manual sounding: too low-tech for a standard Oxidation staining: visual Half-cell method: ASTM C876-09 Cover thickness: GPR Chloride profiling: ASTM C1152-04 Carbonation analysis: phenolphthalein stain

Repair of Corrosion Damage Remove cover Saw-cut edges of repair areas, ½-inch minimum. Chip out damaged cover to expose rebar.

Repair of Corrosion Damage Undercut rebar Typically ½-inch undercut. Creates an integrated bond. Removes contaminated material.

Repair of Corrosion Damage Proper tools Typically pneumatic chipping hammers. 15-lb maximum force. Smaller hammers for delicate work.

Repair of Corrosion Damage Clean rebar Wire brushes. Media blasting. ~200 psi compressed air.

Repair of Corrosion Damage Galvanic protection Sacrificial anodes 35 to 100 g zinc bar Activated mortar Wired to rebar

Repair of Corrosion Damage Why is galvanic protection necessary? Because not all chloride contaminated concrete will be removed. Chloride will diffuse from areas of high concentration (remaining concrete) into areas of low concentration (repair mortar). This is known as the Anode Halo Effect Destroys repairs in 2-5 years.

Repair of Corrosion Damage

Repair of Corrosion Damage Simplified repair geometry

Repair of Corrosion Damage Stay out of the core Majority of column strength is inside the rebar cage (the core). Avoid removing concrete inside the core. The column cannot be completely unloaded. Repair material will shrink. Load capacity will be reduced.

Repair of Corrosion Damage Images courtesy ICRI

Repair of Corrosion Damage

Repair of Corrosion Damage Additional considerations Shoring Priming Coated reinforcing Overbuilding

Repair of Corrosion Damage Form-and-pour Forms fastened to host concrete. Adequate rebar clearance. Vented at top.

Repair of Corrosion Damage

Repair of Corrosion Damage Hand-Pack Earth-dry, stiff mortar. Early-strength. Short working time. 3-steps: Trowel pack mortar into gaps and around rebar. While wet, trowel additional mortar and press. Cut excess flush and level.

Repair of Corrosion Damage Inspection and Testing Saw-cut depths and repair edges. Soundness of host (remaining) concrete. Rebar undercut gap. Dust free surface, SSD condition. Electrical continuity of rebar for anodes.

Repair of Corrosion Damage Inspection and Testing Manual sounding. Pull-off testing. UPV to detect voids.

Repair of Corrosion Damage Completed repair

Repair of Corrosion Damage Repair Standards: ACI RAPs: 1 through 8 ICRI Guidelines: Rebar repair Materials selection Substrate preparation ICRI committee 150 will advise on ACI 562, which will be incorporated into next ICC.

Corrosion Damaged Concrete Causes & Repair Thank you!