Phosphorus and Sulphur Management for Canola Production

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Phosphorus and Sulphur Management for Canola Production Cynthia Grant AAFC - Brandon Research Centre Cynthia.grant@agr.gc.ca

Canola is a Heavy User of Phosphorus and Sulphur Removal of P is slightly higher than that of wheat on a per bushel basis Requirement and removal of S is much higher than that of wheat Nutrient management decisions are affected by both plant characteristics and chemical behavior of P and S 2

Principles of Phosphorus Nutrition that Affect Fertilizer Management Choices P is not very mobile Ties up with Ca, Mg, Al and Fe Will not normally leach on most soils Roots must intercept P since P won t move to roots P is needed early in growth Plants must have adequate supply in first 3-6 weeks Soil supply is reduced under wet, cold conditions Adequate P needs to be near the seed-row so the plants can access it early in the season May need to apply starter near the seed-row unless the soil level is high

How Much Phosphorus is Needed by a Canola Crop? A 40 bu/acre canola removes about 38 lb P 2 O 5 per acre in the seed About 20 lb more taken up but recycled in residue Total of about 58 lb needed for growth Without an adequate P supply, crop yield will be reduced But not all crop requirement has to come from fertilizer 4

Plants Access P from Soil Solution Low concentration of P in the solution is replenished from other pools Soil solution phosphorus HPO 4-2 H 2 PO 4-2

Crops Differ in Ability to Access Soil and Fertilizer P (Flax Council of Canada) (Canola Council of Canada) Flax has poor ability to take up fertilizer P relies more strongly on soil P poor response to fertilizer P Cereals moderate in their ability to use soil and fertilizer P Canola effective at feeding from both fertilizer and soil P modification of rhizosphere proliferation of roots in fertilizer reaction zone 6

Canola Canola is highly responsive to P on very low P soils Can use soil P well if soil test P is moderate to high Yield will usually be optimized with 15 to 20 lb P 2 O 5 ac -1 -As long as adequate soil P is present for later uptake Place as starter near or in the seed-row Response to starter more likely on cold soils, with early seeding an low P content No Starter P 25 bu/acre 25 lb P 2 O 5 applied as MAP 35 bu/acre 7 15 lb NW MKP per ac, equiv. to ~ 7 ppm Olsen P

Can Different Fertilizer Formulations Improve P Availability? Monoammonium phosphate is the standard fertilizer source for the prairies Ammonium in formulation enhances efficiency Ammonium polyphosphate is standard fluid form Other novel formulations include: Fluid orthophosphates such as Alpine Avail additive

Fluids Versus Dry Under arid, highly calcareous conditions in Australia, fluid forms of P are more available than dry Water moving toward granule carries Ca Ca precipitates P and leads to small reaction zone Fluid forms increase reaction zone and allow greater root uptake Similar benefit has not shown up in tests in Manitoba and is unlikely in humid areas

There was no difference between dry MAP and fluid APP in wheat yield over three years at two sites near Brandon Similar results in previous studies by Racz and in later studies on wheat and soybean Soils are more humid and much less calcareous than the 70% calcium carbonate in the Australian trials

Orthophosphates versus Polyphosphates Polyphosphates are chains of orthophosphates Most polyphosphate fertilizers still have 40-60% of the phosphate in the orthophosphate form Polyphosphate converts to orthophosphate in soils rapidly Half usually is converted within a week, Conversion may be slower if soils are cool and dry Generally no difference in effectiveness under field conditions http://www.extension.umn.ed u/distribution/cropsystems/d C6288.html

In studies by Tom Jensen at Brandon, 10-34-0 and MAP performed as well or better than enhanced P products (Average of 8, 16 and 32 kg P ha -1 ) Grain yield, bu/acre a 42 41.2 41 b 40 ns 39.2 39 38.2 38.1 38.5 38.0 38 37.2 37 35.7 36 35 34 33 32 10-34-0 Simplot 7-25-6-4 MAP or 11-52-0 Omex 10-34- 0 plus TPA Alpine 6-22-4 Alpine 6-24-6 AVAIL No AVAIL

In wheat on the prairies, yield was similar if MAP was applied with or without Avail 34 Grain yield, bu/acre 32 30 28 26 - Avail + Avail 24 22 0 10 20 30 40 Wheat (6 site-years) Phophorus rate, lb P 2 O 5 /acre Karamanos

MicroEssentials S-15 Blend of monoammonium phosphate, ammonium sulphate and elemental sulphur (13-33-0-15) Onion-skin layers of sulphur Mosaic product Good product for seed-placement Good distribution and seed safety P availability is as good as MAP

Canola Seed Yield was Similar with Use of MES and other S and P Sources at Two Responsive Sites 20 Phosphate and 9 S 15

What about the microbial products? Two major products sold in western Canada Mycorrhizal inoculants not for use with canola since canola does not form mycorrhizal associations Provide (Jumpstart and part of Tagteam - ) Penicillium bilaii (also classified as P. bilaji and P. bilaiae) is a fungus that colonizes the rhizosphere Effective in solubilizing phosphorus (P) under controlled conditions Under field conditions, results have been inconsistent 16

Provide did not benefit canola yield in studies in Manitoba and Saskatchewan * P=0.09 Ramona Mohr 17

Banding Is the Main Way of Improving P Availability Slows tie-up of P in soil Having some N in the band is beneficial Bands must be placed where roots will contact them early in season Seed-placed Side-banded Canola roots proliferate in bands Fertilizer bands provide high concentration More roots in the band increase uptake Especially important with low soil P, cool soils and early seeding 18

Seed-Placed MAP or APP May Cause Seedling Damage Most damage occurred with highest rates of MAP and ammonium sulphate Additive effect of two fertilizer salts Quebec 2010

Relying on only the safe rate of seed-placed MAP can lead to depletion in canola and soybean crops Crop Yield P Removal Seed Limit Difference bu/acre ------------------ lb P 2 O 5 ha -1 ------------ Wheat 40 29 50 +21 Canola 40 40 20-20 Soybeans 40 32 10-22 Barley 80 38 50 +12 Flax 32 20 20 0 Peas 50 38 20-18 Oats 100 29 50 +21 *Rates are based on disk or knife openers with a 1 in. spread, 6 to 7 in. row spacing and good to excellent soil moisture

Need to Maintain Soil P at Reasonable Levels Excesses can cause environmental problems Deficits can reduce potential crop yield Especially if seed-placed P is reduced in sensitive crops Target Olsen P levels of around 15 ppm Build levels in cereal years, with large broadcast applications, or with manure Consider replacement strategy when target soil levels are attained 21

Sulphur Deficiencies are More Common in Canola than in the Other Annual Crops We Grow. A 40 bu/acre canola removes about 13 lb S per acre in the seed About 10 lb more taken up but recycled in residue Total of about 24 lb needed for growth Compares to about 4 lb removed in a 40 bu/ac wheat crop or 7 lb/ac in a 50 bu/ac pea crop 22

Plants Only Absorb Sulphate-S Sulphate forms are immediately available Soil solution SO 4-2 Elemental forms must oxidize to sulphate 23

A Range of Sulphur Sources Are Available Sulphate Sources Ammonium sulphate Ammonium thiosulphate Gypsum Microessentials S-15 Elemental Sources Elemental S Bentonite blends Vitasul Microessentials S-15 Manage sulphate and elemental sources differently

Ammonium Thiosulphate Converts Rapidly to Sulphate 25

Sulphate Sources Are Immediately Available so Timing of Application is Flexible Ahead of seeding S portion will not volatilize May possibly immobilize or leach but to lesser extent than nitrate Near seeding Readily available Reduces risk of leaching below rooting zone Post-seeding Can be effective, even when delayed Option where deficiencies are noticed late

Managing Post-Emergence Sulphur Response is still greatest when S is supplied early Watch for deficiencies early spraying time. Seed Yield Increase (T/ha) 1.2 1.0 0.8 0.6 0.4 0.2 0.0 Malhi and Leach 2002 100% 75% 60% At seeding At bolting At Flowering Application Timing Act quickly when you see a problem and use sulphate sulphur. Understand the deficiencies may disappear with crop rooting into gypsum, salts or leached S

Sulphate Sources Are Mobile in the Soil so Placement Options Are Flexible Banding pre-plant, mid-row or side-banding Broadcast Dribble-band Seed-placement Avoid excesses that could cause toxicity

Excess Seed-placed Ammonium Sulphate can Cause Seedling Damage in Canola Stand density decreased with increasing rates of ammonium sulphate Most damage occurred with highest rates of MAP and AS Greater risk on calcareous soils Soil from a Hilltop Soil from a Hollow 0 9 18 kg Figure 2: Effect of AS on canola seedling emergence in soils from Brandon Grenkow

Elemental Sources Must Oxidize to Sulphate Requires time and conditions for microbial activity Slower under very wet, dry or cool conditions Often too slow under Prairie conditions Apply far before crop requirement Use finely divided product Broadcast rather than band Want to maximize contact with microbes Leave on surface to weather Incorporate after weathering

Sulphur Source Study at Melfort from 1996 to 1998 One application of 20 kg S ha -1 in 1996 31

In-Soil Banding Delays the Availability of Elemental S 32

Weathering on the soil surface speeds breakdown, while band-placement restricts it Freshly applied T-90 pellet T-90 pellet after 90 days in seed-row Pellet after weathering on soil surface 33 Karamanos

New Products Aim to Hasten Conversion of Elemental S MicroEssentials S15 Onionskin Vitasul Greater dispersion Smaller particles Greater dispersion and contact with microorganisms should hasten oxidation 34

MicroEssentials S15 by Mosaic 13 33 0-15 Ammonium Phosphate Ammonium Sulphate Elemental S ½ S in sulphate form (plant available) ½ S in elemental form (requires conversion) 35

Advantages of MicroEssentials S15 Lower salt index than a blend of MAP and AS Improved seed safety Better distribution of P and sulphate in the seed-row Co-granulation of AS and MAP may improve P uptake Conversion of elemental to sulphate does not appear to be hastened -Only count on ½ of the S being available since elemental S will not convert rapidly 36

MicroEssentials S15 and Vitasul had lower seedling toxicity than ammonium sulphate 37

Canola yield was occasionally lower with elemental S than sulphate but modified products may provide some benefit P<0.02 ns 40 Phosphate and 18 S ns 38

Weather Can Affect S Deficiency

Leaching in Wet Years or Field Areas Increases Risk of Deficiency 40

Strong S Response Occurred after a Wet Season Be particularly alert for S deficiencies after a wet year that promoted leaching

Adding N without S Can Depress Canola Yield on an S-deficient soil Canola Yield (t/ha) 1.2 1.0 0.8 0.6 0.4 0.2 0.0 Control N banded N broadcast Exact N:S ratio is less important than having an adequate S supply Increasing N with No S Increasing N with S

Summary Principles of S fertilization apply Plants take up sulphate Elemental must convert to sulphate Conversion of elemental is slow in Canadian soils Conversion of elemental in new products may not be rapid enough to consistently supply S in year of application More research needed May be other benefits in seed safety or distribution Very wet conditions can lead to leaching and increase the risk of S deficiencies Keep alert for S problems in wet years 43

Summary Canola will respond well to starter P at low rates Response can occur even with moderate to high soil test P Both the likelihood and the size of P response are greater with low soil test P Band placement is generally the most reliable P application method Band in or near seed row where roots intercept early Risk of seedling damage from seed-placed MAP or APP With high rates and/or if combined with ammonium sulphate 44

Summary Under standard soil conditions, MAP and ammonium polyphosphate are effective sources Benefits of having some ammonium in product No benefits of fluids versus MAP Except on dry, highly calcareous conditions as occur in Australia No benefit of orthophosphate versus polyphosphate No evidence of consistent benefits from enhanced efficiency products or microbials Important to avoid excess accumulation or depletion of P Manage P through the rotation to maintain reasonable soil P 45

Thank You to Don Flaten, Laryssa Grenkow John Heard, and Rigas Karamanos for their input and to you for Your Attention