Fueling the Commercializationof Cellulosic Ethanol

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University of Massachusetts Amherst ScholarWorks@UMass Amherst Conference on Cellulosic Biofuels September 2008 Fueling the Commercializationof Cellulosic Ethanol John Howe Verenium Corp., John.Howe@verenium.com Follow this and additional works at: https://scholarworks.umass.edu/timbr Howe, John, "Fueling the Commercializationof Cellulosic Ethanol" (2008). Conference on Cellulosic Biofuels. 6. Retrieved from https://scholarworks.umass.edu/timbr/6 This Article is brought to you for free and open access by ScholarWorks@UMass Amherst. It has been accepted for inclusion in Conference on Cellulosic Biofuels by an authorized administrator of ScholarWorks@UMass Amherst. For more information, please contact scholarworks@library.umass.edu.

Fueling the Commercialization of Cellulosic Ethanol TIMBR Cellulosic Biofuels Conference Amherst, Massachusetts September 19, 2008 John B. Howe Vice President, Public Affairs 55 Cambridge Parkway Cambridge, MA 02142 617.674.5300 www.verenium.com

Overview of Presentation Introduction to Verenium Process technology overview Commercial development focus Evaluating feedstocks: key criteria Geography of CEtOH production in the US Near term Long term Time cycle for CEtOH development and deployment as a complement / successor to today s petroleum fuels Massachusetts opportunity for CEtOH industry leadership 2

Verenium Today: Two Commercially-Focused, Complementary Businesses Biofuels Research & Development Specialty Enzymes Significant Market Opportunities Unmatched In-house Know-How Intellectual Property Infrastructure Development Skills 3

Next-Generation, Cellulosic Biofuels: Supportive Factors in the External Environment Traditional Drivers Immediate Drivers Cellulosic Ethanol From renewable cellulosic biomass 4

Verenium s C5 / C6 Process: Full Use of Sugars from Non-Food Feedstocks Conventional (corn) ethanol is made from 6-carbon sugars in starch using yeast Biomass has 6-carbon sugars and many 5-carbon sugars in hemicellulose (which are not commercially fermentable by yeast) Verenium s unique, proprietary technology converts 5-carbon sugars directly into ethanol, in addition to 6-carbon sugars Typical Biomass Composition (Bagasse) Corn Kernel Composition Other 25% C 5 sugars 30% C 6 sugars 45% C 5 sugars 9% Other 21% Glucose (C 6 ) 70% Fermenting both C 5 and C 6 sugars drastically raises ethanol yields 5

The Verenium CEtOH Production Process: A High Level Overview 6

The Verenium Production Process: Delivery and Storage Once delivered to site, we have a well understood process for managing the bagasse pile 7

The Verenium Production Process: First-stage Hydrolysis of C5 Sugar Stream Dilute acid steam explosion hydrolyzes hemicellulose to 5 carbon sugars and produces a cellulose cake Utilize off-the-shelf technology from pulp and paper industry optimized for our process 9

The Verenium Production Process: Liquid / Solid Separation Hydrolyzed bagasse (mixture of C5 sugar syrup and cellulose fiber) sent to liquid/solid separation system where C5 sugar syrup is washed and separated from cellulose fiber C5 syrup sent to C5 Fermentation process Washed cellulose (C6 cake) sent to C6 fermentation process 10

The Verenium Production Process: Fermentation of Mixed Sugars Two organisms for fermentation: V5 for C5 fermentation V6 for C6 fermentation Saccharification of cellulose by enzymes produced on-site 11

The Verenium Production Process: Distillation and Stillage Processing C5 and C6 beers blended and stored in a beer well, then run through traditional three-stage distillation process (stripping, rectification, and dehydration) to produce fuel grade ethanol 12

Jennings Pilot Plant: A Core Part of Verenium s Biofuels R&D Program Modernized and Expanded During 2006 13

Overseas Licensing of Technology: Extending Verenium s Reach Through Partnerships Bioenergy Japan (Marubeni/TSK, 2007); 2 nd in Thailand (2008) 14

Jennings Demo Plant: First Completed Demonstration-Scale Facility in USA Fully integrated, large-scale cellulosic ethanol facility Rated capacity: 1.4 million gallons-per-year Feedstock: initially bagasse/energy crops; wide range thereafter Currently in start-up and commissioning phase First Commercial Plant Targeted to Break Ground in 2009 15

Verenium s Biofuels Growth Strategy: Rapid Deployment of Facilities Following CP1 CAPACITY & FEEDSTOCK VARIETY Pilot- Scale Demo-Scale 1.4 MGY First Commercial-Scale 25-30 MGY (bagasse / energy cane) First-Generation Commercial-Scale 25-30 MGY (multiple feedstocks) Next-Generation Commercial-Scale 25-60+ MGY (multiple feedstocks/regions) 2007 2008 2011 2011+ 2012+ 16

BP / Verenium Strategic Partnership: A Transformational Alliance For CEtOH Industry Companies share a vision for the near-term commercial scale production of cellulosic ethanol BP a leader energy, including biofuels with 10% global market share Verenium a technology development leader; proven science, existing production assets, including pilot and demonstration-scale facilities K Landmark, 50/50 partnership to accelerate the development of low-cost, environmentally-sound cellulosic ethanol in the U.S. To date, largest (disclosed) single investment in a cellulosic biofuels company in the U.S. BP s largest investment in the U.S. biofuels industry Indicative of commitment to leverage leading technology to advance more sustainable fuels to the market 17

Feedstocks for CEtOH Production: Key Criteria for Broad-Scale Commercialization Availability in high concentration Industrial sites (e.g., pulp and paper mills) Dedicated energy crops Yield/acre (= crop yield x process yield) Supplemental input requirements Transportation costs Harvest and collection Proximity to underserved markets Impact on the food chain Recalcitrance of biomass (woody vs. grassy crops) 18

Feedstock Availability: Conventional View Metrics in feedstock studies (e.g., Billion Ton Study) have tended to focus attention on grain belt sources of cellulose (stover, switchgrass) These metrics reflect existing land use patterns and use criteria that measure aggregate supply (vs. local, economically accessible supply) Biomass per county Biomass per capita Biomass per km 2 What if we focus on maximizing biomass production in our most naturally fertile regions? 19

Dedicated Grass Crops in the Gulf Coast: Maximizing the Potential for CEtOH Production High-fiber Energy Cane (close to original cultivars) is bred for biomass growth Compositionally the most similar to sugar cane bagasse Among the highest yielding ethanol yielding agricultural feedstocks Feedstock Technology Ethanol Yield Gallons / Acre Energy Cane SE U.S. Cellulosic 1,830 Switchgrass U.S. Cellulosic 732 Sugar - Brazil Sugar Fermentation 653 Sugar U.S. Sugar Fermentation 493 Corn U.S. Grain Dry Mill 402 20

Five-Year Commercial Development Plan: Near-Term Focus on Gulf Coast Region Ultimately national / global play; Gulf region is first leg Initial focus: position 6 projects for close between 2009 and 2011 Projects in Development: Grasses/energy cane/bagasse Local agricultural partners Good logistical interfaces Some co-located Three energy crop plantations ~100 acres / plantation Energy cane and sorghum Energy cane expandable in two years to 17k acres Validation platform for growers 21

Closing Thoughts: Peak Oil and the Impact of Near-Term Volatility in Oil Markets Oil prices are in retreat from $145 But global discoveries (not reserve development or production) have declined since the 1960s Unconventional oil resources (offshore, Arctic, tar sands, CTL) will be costly and carbon-intensive Whether the global peak occurs now, in 5 or 20 years is almost immaterial we have no time to lose in developing low-carbon, liquid fuel alternatives! As of 2007, production in 43 countries (out of 55 that have ever produced petroleum) was in decline 22

The Biofuels Industry in Massachusetts Several factors (e.g., climate, size, cost of land, type of industry) will limit the opportunity for biofuels production within our borders But Massachusetts has an unparalleled opportunity to be a biofuels technology leader through biotech/university collaboration Public policy leadership (e.g., biofuels law) can foster a receptive market and set a strong example for other states Technologies originating here can be deployed on a global scale Who will be the Apple Computer of the biofuels industry? 23

Thank You? Questions? john.howe@verenium.com www.verenium.com 24