Lec #20: Fossil Fuels. III. F.F. 1. Supply, Extraction, Use (Chap 7) coal, gas, oil; what are they; how formed? where to find? hidden costs F.F. 2. Combustion of FF & The Byproducts (Chap 8) Combustion Process and Byproducts Pollutants Atmospheric Structure and Dynamics Pollution Control Technology and Techniques F.F. 3. Global Environmental Impacts of FF Burning (Chap 9) The Facts About Global Warming 1. Greenhouse Effect is Real well understood, natural phenomenon it can be beneficial but non-linear, subject to feedbacks, therefore it is hard to predict changes 2. Global Warming is Real Earth is warming up at a measurable rate rate corresponds to... 3. CO 2 Concentration is Increasing huge growth corresponds to history of fossil fuel burning 4. Earth has always been either heating up or cooling off, and the behavior has been (quasi) cyclic astronomical causes geological activity cycles? solar activity or luminosity cycles? 5. Amplitude of natural temperature cycles exceeds current warming trend, but 6. Timescale of current CO 2 trend is shorter than any natural cycles The Greenhouse Effect ENERGY IN = ENERGY OUT otherwise, Temperature changes radiant energy only possible mechanism IN: solar radiation (mostly visible) OUT: reflected sunlight (visible) thermal emission from surface and atmosphere (infrared, microwave) Earth s interior cooling (infrared; 2700 times less) H 2 O, CO 2, CH 4, etc. absorb infrared block a fixed fraction from escaping tiny changes in composition can change temperature Blackbody Radiation : Electromagnetic Radiation emitted by a dense object in thermal equilibrium energy emitted at all wavelengths higher temperature emits more at all wavelengths total energy emitted = (area) x σt 4 peak wavelength proportional to temperature [play with Spectrum Explorer] 1
Earth s Equilibrium Temperature Solar Luminosity L s =4πR s2 σt s 4 = 10 26 W T s ~ 5800 K Intensity of electromagnetic radiation decreases as square of distance Flux at Earth: F = L s /4πd 2 = 1356 W/m 2 albedo = fraction not reflected ~ 0.5 Radiant Energy IN = flux x albedo x πr E 2 Earth Luminosity L E =4πR E2 σt E 4 must equal energy IN T E will adjust to make it so Without atmosphere, T E ~ 250 K (brrr!!) With atmosphere, T E ~ 300 K (mostly b/c H 2 O) NOAA Climate Monitoring & Air Sample Stations Temperature and CO 2 Concentration Correlate 2
CO 2 is not the only culprit The Ozone Hole US, Canada, Australia: Largest Per Capita Emissions China and India are also big problems 3
Earth s Surface Temperature is Increasing Astronomical Changes & Climate Drivers molten blob 4.6 GYA radiate to space: cool outgas atmosphere life <--> atmosphere 3 Types of Change: EVOLUTIONARY CYCLIC CATASTROPHIC rapid decrease in solar activity clearing phase in early solar system gradual increase in solar luminosity regular impacts since clearing phase mass extinctions cyclic? (rotation of galaxy, nemesis) orbital changes month of perihelion; eccentricity axis tilt changes gradual spindown (due to tides) solar irradiance variations ongoing solar activity Earth s changing magnetic field Astronomical Causes of Climate Cycles Solar Cycles 20,000 years 43,000 years 1992 1996 Minimum Maximum 100,000 years Number of Sunspots 1850 1860 1870 1880 1890 1900 1910 1920 1930 1940 1950 1960 1970 1980 1990 2000 4
Correlations between activity and climate are highly suggestive, but what is the mechanism?. Some correlations could be spurious: Earth s Interactions & Cycles Interior Lithosphere Hydrosphere Biosphere Atmosphere Magnetosphere Heliosphere Number of Sunspots vs. # of Republicans in US Senate Water Cycle Salt Cycle Carbon Cycle Climate Cycles Extinction Cycle? Impact Cycle? Geological Activity Cycle? Why Is Any Of This Controversial? Rio, Kyoto, IPCC very little disagreement on facts Scientists are their own worst enemies focus on uncertainties and on what we don t know Non-scientists misinterpret this focus AS uncertainty and ignorance Hindsight does not necessarily lead to foresight. Understanding components in a complex system doesn t necessarily lead to predictability. Waiting is not always counterproductive (but it is in this case) What Can, Should, Must We Do? Nothing? Mother Earth will find a way to protect us from our own behavior. (will it?) Research? Wait til there s no uncertainty? Develop alternatives to replace fossil fuels? eventually, we have to do this anyway Drive Economic Changes? (cost accounting) Political Action? Manage the Earth? (introduce counter-effects) 5
Summary fossil fuels are our primary energy source burning them produces CO 2 & pollutants we breathe the pollutants CO 2 --> global warming fossil fuel supply is finite Pick your favorite reason; We ve got to change our ways. (and soon!) How? Thermal Energy w/out burning (solar, geothermal, nuclear) Mechanical Energy directly (wind, water, tides) Radiant Energy (direct, or convert to TE or ME) 6