FRIALIT -DEGUSSIT Oxide Ceramics. Materials, Applications and Properties

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- Oxide Ceramics Materials, Applications and Properties

Team and Application Areas 02 03 Materials and Typical Applications 04 05 Material Properties 06 07

Team and Application Areas - Oxide Ceramics and an experienced Team solve your problems. The more combined demands a material has to fulfil, the more convincing become the outstanding properties of our ceramics. Your Contact Global Sales Phone: +49 621 486-1353 Fax: +49 621 486-25 1353 Electrical Engineering Sales Phone: +49 621 486-1366 Fax: +49 621 486-25 1366 We are represented worldwide. We would be pleased to give you the details of our foreign partners. 02 - Oxide Ceramics

Electrical Engineering Mechanical Engineering electrical feedthroughs and insulating tubes for vacuum equipment inspection equipment for semi conductors/photovoltaics apparatus for research and development (accelerator technology) high-quality electronics probe technology sensor housings onshore-/offshore-technology (high pressure) pistons for dosing pumps plungers for high pressure pumps glide rings for sealing pumps shaft protection sleeve plain bearings and roller bearings nozzles guides shaped parts for demanding wear resistance drawing cones and guides for the wire industries W W pressing dies High Temperature Technology tubes and insulating rods for protection and insulation of thermocouples, and for gas inlet and exhaust tubes externally-grooved tubes and special heating tubes for construction of electrically heated furnaces diffusion tubes for the semiconductor industry laboratory ware, e.g. crucibles, boats, combustion trays and plates for heat treatment and melting at high temperatures Surface Finishing fine grinding tools, e.g. whetstones, abrasive and fine files, fine grinding wheels, mounted points and burnishing wheels for machining metals, glass and porcelain - Oxide Ceramics 03

Materials and Typical Applications Material FRIATEC Trade Name Properties Typical Applications F99,7 Pure Al 2, dense, extremely resistant to wear and corrosion, very high electrical insulating properties Matched piston/cylinder units, bearings, shafts and valve components, electrical feedthroughs, brazed ceramic to metal seals for x-ray-technology and ionic accelarators for medical technology, dielectrics for fuel cells, sensor caps DD57 Pure Al 2, dense, red colour, wear resistant and tough, also called sintered ruby Fine grinding tools for finishing hard materials for precision engineering, knife sharpener Al 2 Aluminium Oxide AL23 Pure Al 2, dense, excellent thermal and electrical resistance properties, corrosion resistant, permeable for microwaves Protection tubes for thermocouples, furnace construction parts, laboratory ware e.g. crucibles, boats and plates, reactor lining in the chemical industry, microwave-technology AL24 Pure Al 2, slightly porous, good resistance to thermal shock, extremely good creep strength Tubes, laboratory ware, furnace construction parts AL25 Pure Al 2, very porous, good thermal insulation, highest resistance to thermal shock of all the Al 2 materials Tubes, laboratory ware, furnace construction parts Al 2 (+ZrO 2 ) Aluminium Oxide, fine grain stabilized FZT Al 2 toughened with ZrO 2, dense, high strength, good resistance to thermal shock, extremely resistant to wear and corrosion, fine grain size Vacuum plates for paper-making, flow meter tubes for chemical industry, positioning pins for automotive industry 04 - Oxide Ceramics

Material FRIATEC Trade Name Properties Typical Applications FZM ZrO 2 partially stabilized with MgO, dense, high strength and highly wear resistant, extremely resistant to corrosion and thermal shock High pressure pistons, pressing dies, components for mills, ceramic isolation shells for magnetic drive centrifugal pumps, metal forming tools ZrO 2 Zirconium Oxide FZY Partially stabilized with Y 2, dense, high purity ZrO 2, high temperature and corrosion resistance, ion conducting for measuring oxygen Crucibles, heat-treatment bowls, oxygen measurement FZM/K Tetragonally stabilized with Y 2, dense, very fine grain size, highest breaking strength and wear resistance Cutting elements, wear protection plates SiC Silicon Carbide SiC 198D SSiC, highly wear resistant, good corrosion resistance, excellent sliding properties Slide rings, bearings, slide bushings, axial sleeves Si 3 N 4 Silicon Nitride HP 79 High purity Silicon Nitride, high wear resistance, excellent bending strength, highest thermal shock resistance Metal forming tools, rollers, plates - Oxide Ceramics 05

Material Properties Material Al 2 Aluminium Oxide FRIATEC Trade Name F99,7 DD57 AL23 AL24 AL25 FZT Properties of Microstructure Apparent Density g/cm 3 3,90-3,95 3,70-3,80 3,70-3,95 3,40-3,60 2,80-3,10 4,05-4,15 Open Porosity % 0 0 0 0-5 20-30 0 Mean Grain Size µm 10 10 10 40 70 5 Mechanical Properties 20 C Hardness (Knoop, 100g) N/mm 2 (MPa) 23 000 23 000 23 000 - - 20 000 Compressive Strength N/mm 2 (MPa) 3 500 3 000 3 500 1 000 300 3 000 Bending Strength N/mm 2 (MPa) 350 300 300 150 70 460 Modulus of Elasticity GPa 380 380 380 - - 360 Thermal Properties Maximum Operating Temperature C 1 950 1 950 1 950 1 950 1 950 1 700 Specific Heat 20 C J/kg/K 850 900 850 - - 850 Thermal Conductivity 100 C W/m/K 30 30 30 - - 25 Expansion Coefficient 20-1 000 C 10-6 /K 8,5 8,5 8,5 8,5 8,5 8,6 Electrical Properties Specific Resistance 20 C Ω cm 10 15 10 14 10 14 - - - Specific Resictance 500 C Ω cm 10 11 10 10 10 10 - - - Specific Resistance 1 000 C Ω cm 10 7 10 7 10 7 - - - 06 - Oxide Ceramics

Material ZrO 2 Zirconium Oxide Non-Oxides FRIATEC Trade Name FZM FZY FZM/K SiC 198D HP 79 Properties of Microstructure Apparent Density g/cm 3 5,70-5,80 5,50-5,80 6,00-6,10 3,1 3,25 Open Porosity % 0 0 0 3 < 1 Mean Grain Size µm 50 50 0,5 10 10 Mechanical Properties 20 C Hardness (Knoop 100g) N/mm 2 (MPa) 16 000 17 000 18 000 26 000 16 000 Compressive Strength N/mm 2 (MPa) 2 000 2 000 2 200 > 3 000 3 000 Bending Strength N/mm 2 (MPa) 500 400 800 450 850 Modulus of Elasticity GPa 185 200 200 400 320 Thermal Properties Maximum Operating Temperature C 900 1 700 1 200 1650-1900 1 200 Specific Heat 20 C J/kg/K 400 400 400 1 000 700 Thermal Conductivity 100 C W/m/K 2,5 2,5 2,5 125 30 Expansion Coefficient 20-1 000 C 10-6 /K 11,1 11,2 10,8 4,5 3,2 Electrical Properties Specific Resistance 20 C Ω cm 10 10 10 10 10 10 10-1 10 10 Specific Resistance 500 C Ω cm 10 4 5 * 10 3 10 2 - - Specific Resistance 1 000 C Ω cm 25 15 - - 10 7 The data indicated in this table is in line with the introductory German Industrial Standard DIN 40685 and relates to the specimens from which is was obtained and is not unconditionally applicable to other forms of the same material. The data must, therefore, be regarded as indicative only. - Oxide Ceramics 07

- Oxide Ceramics for: Electrical Engineering High Temperature Technology Mechanical Engineering Surface Finishing Competence plus Responsibility Our customers rightly expect first-class performance with lasting value. Besides the competence to achieve this, we also undertake the responsibility for it. Ask for the evidence: FRIATEC is the technological and market leader in ceramic materials for the 21st Century. FRIATEC Aktiengesellschaft Ceramics Division Steinzeugstrasse 50 68229 Mannheim (Germany) Phone: +49 621 486-0 info-frialit@friatec.de www.friatec.de

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