SAFETY DATA SHEET 1. Identification Product identifier Other means of identification Synonyms SC Recommended use Silver Jewelry Cleaner Recommended restrictions None known. Manufacturer/Importer/Supplier/Distributor information Company name The Kingswood Company Address 3065 Switzer Avenue Columbus, OH 43219 USA Telephone (614) 252-6400 E-mail msds@thekingswoodcompany.com Emergency phone number (800) 848-3582 2. Hazard(s) identification Physical hazards Not classified. Health hazards Carcinogenicity Category 2 OSHA defined hazards Reproductive toxicity Not classified. Category 2 This is a consumer care product that is safe for consumers when used according to the label directions. Label elements Signal word Hazard statement Precautionary statement Prevention Response Storage Disposal Hazard(s) not otherwise classified (HNOC) Supplemental information Warning Suspected of causing cancer. Suspected of damaging fertility or the unborn child. Observe good industrial hygiene practices. Wash hands after handling. Store away from incompatible materials. Dispose of waste and residues in accordance with local authority requirements. None known. None. 3. Composition/information on ingredients Mixtures Chemical name TRADE SECRET TRADE SECRET Other components below reportable levels CAS number % Proprietary 5 - < 10 Proprietary 3 - < 5 90-100 4. First-aid measures Inhalation Move to fresh air. Call a physician if symptoms develop or persist. 928831 Version #: 01 Revision date: - Issue date: 08-October-2015 1 / 6
Skin contact Eye contact Ingestion Most important symptoms/effects, acute and delayed Indication of immediate medical attention and special treatment needed General information 5. Fire-fighting measures Suitable extinguishing media Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for firefighters Fire fighting equipment/instructions Specific methods General fire hazards Wash off with soap and water. Get medical attention if irritation develops and persists. Rinse with water. Get medical attention if irritation develops and persists. Rinse mouth. Get medical attention if symptoms occur. Direct contact with eyes may cause temporary irritation. Provide general supportive measures and treat symptomatically. Symptoms may be delayed. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Use fire-extinguishing media appropriate for surrounding materials. None known. During fire, gases hazardous to health may be formed. Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Move containers from fire area if you can do so without risk. Use standard firefighting procedures and consider the hazards of other involved materials. This product is an aqueous mixture which will not burn. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Methods and materials for containment and cleaning up Keep unnecessary personnel away. For personal protection, see section 8 of the SDS. This product is miscible in water. Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Environmental precautions 7. Handling and storage Precautions for safe handling Conditions for safe storage, including any incompatibilities Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Prevent further leakage or spillage if safe to do so. Observe good industrial hygiene practices. Store in original tightly closed container. Store away from incompatible materials (see Section 10 of the SDS). 8. Exposure controls/personal protection Occupational exposure limits Biological limit values Appropriate engineering controls No exposure limits noted for ingredient(s). No biological exposure limits noted for the ingredient(s). Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Individual protection measures, such as personal protective equipment Eye/face protection Avoid direct contact with eyes. If contact is likely, safety glasses with side shields are recommended. Not normally needed. Skin protection Hand protection Other Not normally needed. Protective clothing is not required under normal conditions. 928831 Version #: 01 Revision date: - Issue date: 08-October-2015 2 / 6
Respiratory protection Thermal hazards General hygiene considerations As supplied, respiratory protection is not typically required during normal use and handling operation. Wear appropriate thermal protective clothing, when necessary. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Physical state Liquid. Form Liquid. Color Pale blue. Odor Slight Medicinal. Rotten eggs. (Hydrogen sulfide odor). Slight Lavendar. Odor threshold ph 4-4.5 Melting point/freezing point 32 F (0 C) Initial boiling point and boiling 212 F (100 C) range Flash point Evaporation rate Flammability (solid, gas) Not applicable. Upper/lower flammability or explosive limits Flammability limit - lower Not Applicable (%) Flammability limit - upper Not Applicable (%) Explosive limit - lower (%) Not Applicable Explosive limit - upper (%) Not Applicable Vapor pressure Vapor density Relative density Solubility(ies) Solubility (water) Soluble Partition coefficient (n-octanol/water) Auto-ignition temperature Decomposition temperature Viscosity Other information Explosive properties Not explosive. Oxidizing properties Not oxidizing. 10. Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products The product is stable and non-reactive under normal conditions of use, storage and transport. Material is stable under normal conditions. No dangerous reaction known under conditions of normal use. Contact with incompatible materials. Strong oxidizing agents. Carbon oxides, Nitrogen oxides 928831 Version #: 01 Revision date: - Issue date: 08-October-2015 3 / 6
11. Toxicological information Information on likely routes of exposure Inhalation No adverse effects due to inhalation are expected. Skin contact No adverse effects due to skin contact are expected. Eye contact Direct contact with eyes may cause temporary irritation. Ingestion Expected to be a low ingestion hazard. Symptoms related to the Direct contact with eyes may cause temporary irritation. physical, chemical and toxicological characteristics Information on toxicological effects Acute toxicity Components Acute Dermal LD50 Species Rabbit Rat Test Results > 2800 mg/kg > 6810 mg/kg * Estimates for product may be based on additional component data not shown. Skin corrosion/irritation May cause mild skin irritation upon prolonged and excessive contact. Serious eye damage/eye Direct contact with eyes may cause temporary irritation. irritation Respiratory or skin sensitization Respiratory sensitization Not a respiratory sensitizer. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity Suspected of causing cancer. IARC Monographs. Overall Evaluation of Carcinogenicity 3 Not classifiable as to carcinogenicity to humans. NTP Report on Carcinogens Reasonably Anticipated to be a Human Carcinogen. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Reproductive toxicity Suspected of damaging fertility or the unborn child. Specific target organ toxicity - Not classified. single exposure Specific target organ toxicity - Not classified. repeated exposure Aspiration hazard Not an aspiration hazard. 12. Ecological information Ecotoxicity Persistence and degradability The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. No data is available on the degradability of this product. Bioaccumulative potential Partition coefficient n-octanol / water (log Kow) TRADE SECRET -1.08 Mobility in soil Mobile in soil. Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 928831 Version #: 01 Revision date: - Issue date: 08-October-2015 4 / 6
13. Disposal considerations Disposal instructions Local disposal regulations Hazardous waste code Waste from residues / unused products Contaminated packaging 14. Transport information DOT Not regulated as dangerous goods. IATA Not regulated as dangerous goods. IMDG Not regulated as dangerous goods. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information Disposal recommendations are based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. Dispose in accordance with all applicable regulations. Dispose of waste and residues in accordance with local authority requirements. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty packaging materials should be recycled or disposed of in accordance with applicable regulations and practices. Not established. US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) CERCLA Hazardous Substance List (40 CFR 302.4) LISTED Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - No Delayed Hazard - Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous chemical SARA 313 (TRI reporting) Chemical name CAS number % by wt. TRADE SECRET Proprietary 3 - < 5 Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Safe Drinking Water Act (SDWA) US state regulations US. Massachusetts RTK - Substance List US. New Jersey Worker and Community Right-to-Know Act 928831 Version #: 01 Revision date: - Issue date: 08-October-2015 5 / 6
US. Pennsylvania Worker and Community Right-to-Know Law US. Rhode Island RTK US. California Proposition 65 WARNING: This product contains a chemical known to the State of California to cause cancer. US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance International Inventories Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Canada Domestic Substances List (DSL) Canada Non-Domestic Substances List (NDSL) No China Inventory of Existing Chemical Substances in China (IECSC) Europe European Inventory of Existing Commercial Chemical Substances (EINECS) Europe European List of Notified Chemical Substances (ELINCS) No Japan Inventory of Existing and New Chemical Substances (ENCS) Korea Existing Chemicals List (ECL) New Zealand New Zealand Inventory Philippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "" indicates this product complies with the inventory requirements administered by the governing country(s). A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date 08-October-2015 Revision date - Version # 01 HMIS ratings Health: 1* Flammability: 0 Physical hazard: 0 Disclaimer The Kingswood Company cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information in the sheet was written based on the best knowledge and experience currently available. 928831 Version #: 01 Revision date: - Issue date: 08-October-2015 6 / 6