Simulation of the Spray Characteristics of Black Liquor. Colloquium on BL Combustion and Gasification Denise Levesque

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Simulation of the Spray Characteristics of Black Liquor Colloquium on BL Combustion and Gasification Denise Levesque May 2003 1

Co-Authors Mohammad Fard, Simulent Inc. Stuart Morrison, ALSTOM Canada Javad Mostaghimi, University of Toronto 2

Agenda Project Goals Need for Code Development Code Development Code Validation Full Simulation Test Cases Summary 3

Long Term Goals Create a code which can be used to: Optimise nozzle design Predict droplet size for a particular operation Provide input for CFD modeling 4

Objective of New Code Develop a code (computer program) which can properly simulate the liquid sheet formation and its breakup in a splash plate nozzle 5

Objective of New Code 6

Need for Code Development Difficulty in testing spray characteristics in-situ Difficulty in reproducing firing conditions in the laboratory. Equations developed by Dombrowski and coworkers to predict droplet size are not general in nature. Improve spreadsheet which is currently used to predict droplet size based on boiler operating conditions. 7

Code Development Work initiated to develop BLSpray in Sept 2000 Numerical Methods: Basic Assumptions Laminar, Newtonian, incompressible flow 3D Cartesian coordinate system, using a finite volume scheme Full Navier-Stokes equations 8

Code Capabilities Model any shape of solid object Handle a wide range of liquid properties Handle continuous fluid boundary conditions, inflow and outflow Provide liquid film thickness and its velocity distribution at any desired location and crosssection Plot results in the form of 3D images Include internal and external disturbances Simulate, with further development, other types of nozzles Can be coupled with CFD modeling software 9

Steps in Development of BLSpray Step 1: Develop BLSpray to model normal impact of a liquid jet on a solid plate Step 2: Develop BLSpray to accurately predict black liquor sheet thickness and velocity at the tip of the splash plate Step 3: Develop BLSpray to enable the code to determine droplet size and distribution 10

Initial Code Validation Quantitative validation using Ashgriz et al. Jet velocity m/s Measured Mean Droplet Dia. Simulation: Droplet Dia range Simulation: Droplet Dia average 12 ~ 160 µm 100-200 µm 150 µm 26.8 ~ 80 µm 50-100 µm 80 µm 11

Initial Code Validation Numerical simulation Azuma and Wakimoto Int. Conference on Multiphase Flow, 2001 Qualitative validation: liquid film and finger formation at high speed jet impact 12

BLSpray: Step 2 40 ms Impingement of black liquor on a plate at an angle Progressed from a flat plate to a full nozzle body 13

Step 2 Validation Corn syrup experiments by Obuskovic and Adams Validation of sheet thickness and velocity at the tip of the splash plate 14

Step 2 Validation Film Thickness BLSpray vs experimental results for two different viscosities 0 o 25 o 50 o 15

Step 2 Validation Film Top Surface Velocity BLSpray vs experimental results for two different viscosities 0 o 25 o 50 o 16

Full Simulation: Step 3 Increased computational domain to capture breakup point Droplet size distribution obtained from the liquid volume fraction data calculated by the code 17

Full Simulation: Computational Domain The large domain is broken into smaller simulation blocks Simulation continues until droplet formation Block 1 Block 2 Block 3 Block 1 Block 4 Block 5 18

Images from Full Simulation 45 o 25 o 19

Images of Full Simulation 0 o <θ <10 o 25 o <θ <45 o 20

Test Cases One simulation using BLSpray gives all flow information in the entire domain of computation Results were analysed at three different crosssections jet angle Υ 23

Test Cases: First Set Black liquor properties held constant Viscosity 100 mpa s Surface Tension 60 mn/m Density 1350 kg/m 3 Varied splash plate conditions Nozzle Diameter Jet Velocity Jet Angle Looking at effect on sheet characteristics 24

Nozzle Diameter Nozzle Diameter (mm) Jet Velocity (m/s) Jet Angle (degrees) 12 10 45 22 10 45 32 10 45 25

Nozzle Diameter As nozzle diameter increases Film thickness increased Sheet breaks up further from the plate Radial distribution remained fairly constant 20 h(mm) 15 10 5 0 12 mm 22 mm 32 mm nozzle diameter 0 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 r(mm) (d) 26

Nozzle Diameter Top surface velocity increased with increasing nozzle diameter 12 mm 22 mm 32 mm 27

Jet Angle Nozzle Diameter (mm) Jet Velocity (m/s) Jet Angle (degrees) 22 10 35 22 10 45 22 10 55 28

Jet Angle 35 o 45 o 55 o 35 o 45 o 55 o Nozzle angle As jet angle increases: more atomisation towards side of splash plate, creates more uniform thickness distribution atomisation occurs closer to plate at plane of symmetry little effect on top surface velocity 29

Jet Velocity Nozzle Diameter (mm) Jet Velocity (m/s) Jet Angle (degrees) 22 5 45 22 10 45 22 18 45 30

Jet Velocity 5 m/s 10 m/s 18 m/s 5 m/s 10 m/s 18 m/s As jet velocity increases there is no effect on sheet thickness or radial distribution velocity distribution increases proportionally 31

Test Cases: Second Set Splash plate configuration held constant Nozzle Diameter 32 mm Jet Angle 45 degrees Varied key properties affecting droplet size Viscosity Jet Velocity Surface Tension Looking at effect on droplet size. Only 0 to 10 o from plane of symmetry was analysed. 32

Test Cases: Second Set Breakup angle Breakup point Breakup length 33

Low Black Liquor Viscosity: Case 1 Viscosity 50 mpa s Jet Velocity 4 m/s Surface Tension 60 mn/m Density 1350 kg/m 3 34

Low Black Liquor Viscosity: Case 1 35

Low Black Liquor Viscosity: Case 1 Average Droplet Diameter 6.08 mm Breakup Length 270 mm Breakup Angle 8.4 degrees 36

Typical Splash Plate Conditions: Case 2 Viscosity 200 mpa s Jet Velocity 4 m/s Surface Tension 60 mn/m Density 1350 kg/m 3 37

Typical Splash Plate Conditions: Case 2 38

Typical Splash Plate Conditions: Case 2 Average Droplet Diameter 6.16 mm Breakup Length 270 mm Breakup Angle 9.5 degrees 39

Low Jet Velocity: Case 4 Viscosity 200 mpa s Jet Velocity 1 m/s Surface Tension 60 mn/m Density 1350 kg/m 3 41

Low Jet Velocity: Case 4 42

Low Jet Velocity: Case 4 Average Droplet Diameter 6.39 mm Breakup Length 120 mm Breakup Angle 36.9 degrees 43

Summary of Test Case Results: Second Set Case # Visc (mpa s) Nozzle Velocity (m/s) Surface Tension (mn/m) Droplet Size (mm) Breakup Length (mm) Breakup Angle (degrees) 1 50 4 60 6.08 270 8.4 2 200 4 60 6.16 270 9.5 3 700 4 60 6.58 320 10.6 4 200 1 60 6.39 120 36.9 5 200 10 60 4.49 270 3.8 6 200 4 30 5.48 270 9.5 7 200 4 90 7.6 280 10.1 47

Summary Preliminary BLSpray has been developed and validated Current BLSpray can be used to: optimise current nozzle designs test new nozzle designs understand effects of varying black liquor properties Work is continuing to improve the code to include in-situ influences such as vapourisation, vertical velocity 48

Actual Spray 49