GTC Conference. Advanced IGCC with Partial Carbon Capture. October Jacobs. Presented at:

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Advanced IGCC with Partial Carbon Capture Presented at: GTC Conference October 2013 Jacobs 1500 Hughes Way, Pod B Suite 400 Long Beach, CA 90810 www.jacobs.com

Introduction to Jacobs Safety is key to everything we do A global leader in technical professional services 65,000 professional staff at 200+ locations in 25 countries $11 billion in revenue $16 billion in backlog Publicly traded on NY stock exchange Sound financial base Business model is long term client alliances Slide 2

Who Is the CCPC? The CCPC is an association of Canadian and U.S. coal and coal-fired electricity producers, government agencies and research organizations Industry participants include: Alberta Innovates Energy and Environment Solutions Capital Power Corporation Electric Power Research Institute (EPRI) Nova Scotia Power Inc. Sherritt International Corporation SaskPower TransAlta Corporation The CCPC's mandate is to research technologies with the goal of developing and advancing commercially viable solutions that lower coal power plant emissions Slide 3

Introduction Canadian and US Government have new regulations limiting the emissions from new Fossil Fuel power plants to below 500 kg CO 2 /MWh. This equates to about 60% carbon capture. Most published work on carbon capture has focused on capturing over 90% of the carbon emitted with a limited number of processes and configurations. Limiting the level of carbon captured enables alternative technologies and process configurations to be used. Significant increase in overall plant efficiency and reduced capital cost. Slide 4

Base Case Unit Operations Coal Gasification Raw Syngas Sour Shift & Gas Cooling Combined Cycle Electricity Nitrogen Oxygen Shifted Syngas Conditioned Fuel Gas ASU Sulphur Removal CO2 Removal CO2 Sulphur Slide 5

Base Cases Unit Operation Technology Air Separation Cryogenic Cryogenic Gasifier AR (Aerojet Rocketdyne formerly PWR) Shift Sour Full SES U-Gas Sour Full Sulphur Removal Selective Selexol Selective Selexol CO2 Removal Selective Selexol Selective Selexol Sulphur Recovery Claus Claus Gas Turbine 2 x GE 7 F 2 x GE 7 F Slide 6

Technologies Identified for Evaluation Unit Operation Technology Air Separation Cryogenic Air Products ITM Gasifier AR SES U-Gas Shift Sweet Full Sour Partial Sulphur Removal RTI WGCU Selective Solvent CO2 Removal CO2 Selective Membrane High Recovery PSA Selective Solvent Non-selective solvent H2 selective membrane Cryogenics Sulphur Recovery Claus Wet Sulphuric Acid RTI Direct Sulphur Recovery Process (DSRP) LoCat Slide 7

Option Matrix ASU Gasifier Shift Shift Extent Sulphur Removal CO2 Removal Sulphur Recovery ITM Cryogenic AR SES Sour Shift Full Partial High Pressure LoCat Selective Selexol Non-Selective Solvent Sour CO2 membrane Sour H2 membrane Sour High Recovery PSA Non-Selective Solvent CO2 membrane Claus Modified Claus Low Pressure LoCat High Pressure LoCat H2 membrane Sweet High Recovery PSA Sweet Shift Full Partial RTI Warm Gas Cryogenic Separation Non-Selective Solvent CO2 membrane Wet Sulphuric Acid H2 membrane RTI DSRP Sweet High Recovery PSA Slide 8 Cryogenic Separation

Selected Configurations (1) Case 1 2 3 ASU Cryogenic Cryogenic Cryogenic Feed Preparation Dry Milling Dry Milling Dry Milling Gasification AR AR AR Shift & Gas Cooling Double Sour Shift Double Sour Shift Double Sour Shift Sulphur Removal LoCat LoCat LoCat CO 2 Removal Partial Condensation with by-pass High Recovery PSA with by-pass CO 2 Membrane with by-pass CO 2 Compression & Drying Pumped Liquid CO 2, Included with CO 2 Removal CO 2 Compressor CO 2 is compressed, Liquefied, then Pumped Sulphur Recovery Unit LoCat LoCat LoCat Power Block 2 x 1 7F Syngas no airside integration 2 x 1 7F Syngas no airside integration 2 x 1 7F Syngas no airside integration Slide 9

Selected Configurations (2) Case 4 5-2 5-4 ASU Cryogenic ITM ITM Feed Preparation Dry Crushing Dry Milling Dry Crushing Gasification SES U-Gas AR SES U-Gas Shift & Gas Cooling Double Sour Shift, partial by-pass Double Sour Shift Sulphur Removal LoCat LoCat LoCat Double Sour Shift, partial by-pass CO 2 Removal Non-selective solvent High Recovery PSA with by-pass Non-selective solvent CO 2 Compression & Drying Sulphur Recovery Unit CO 2 Compressor CO 2 Compressor CO 2 Compressor LoCat LoCat LoCat Power Block 2 x 1 7F Syngas no airside integration 2 x 1 7F Syngas airside integration 2 x 1 7F Syngas airside integration Slide 10

Overall Summary of AR Cases Base Case Case 1 Case 2 Case 3 Case 5-2 Gasifier Technology AR AR AR AR AR Air Separation Cryo Cryo Cryo Cryo ITM Sulphur Capture Selexol LoCat LoCat LoCat LoCat CO2 Capture Selexol Partial Condensation PSA Membrane PSA Coal Feed (AR) t/d 6,881 7,011 7,053 6,994 7,948 CO2 Produced t/d 12,509 12,740 12,817 12,711 14,443 CO2 Captured t/d 11,626 7,544 7,280 7,752 7,844 CO2 Released t/d 883 5,196 5,537 4,959 6,599 CO2 Intensity kg/mwh 80.0 418.0 417.9 418.9 416.3 Gross Power Produced MW 656.4 681.1 693.7 678.8 653.1 Total Power Consumed MW 230.9 163.2 171.3 186.8 24.7 Net Power Output MW 425.5 517.9 522.4 492.0 628.4 Heat Rate LHV kj/kwh 12,159 10,178 10,152 10,688 9,510 Efficiency LHV % 29.61 35.37 35.42 33.68 37.86 Capital Cost (USCG) MM USD 2,303 2,107 2,126 2,108 2,616 Specific Cost $/kw 5,461 4,068 4,070 4,283 4,163 Slide 11

Overall Summary of SES Cases Base Case Case 4 Case 5-4 Gasifier Technology SES SES SES Air Separation Cryo Cryo ITM Sulphur Capture Selexol LoCat LoCat CO2 Capture Selexol Selexol CO2 Selexol CO2 Coal Feed (AR) t/d 6,401 6270.4 7,591 CO2 Produced 11,067 10,838 13,122 CO2 Captured t/d 8,711 5,796 6,766 CO2 Released t/d 2,356 5,042 6,356 CO2 Intensity kg/mwh 212.0 417.2 416.7 Gross Power Produced MW 604.7 639.1 584.5 Total Power Consumed MW 163.0 156.2-27.1 Net Power Output MW 441.8 482.9 611.6 Heat Rate LHV kj/kwh 10,894 9,763 9,334 Efficiency LHV % 33.05 36.88 38.57 Capital Cost (USCG) MM USD 2,129 1,892 2,238 Specific Cost $/kw 4,838 3,917 3,660 Slide 12

Cost of Electricity First Year 175 150 125 Cost of Electricity ($/MWh) 100 75 50 Transmission O & M Fuel Costs Capex 25 0 Slide 13

Cost of CO2 Capture First Year 200 180 160 140 Cost of CO2 Captured ($/MT 120 100 80 60 O & M Fuel Costs Capex 40 20 0 Slide 14

Avoided Cost of CO2 First Year 300 250 Avoided Cost of CO2 ($/MT) 200 150 100 O & M Fuel Costs Capex 50 0 Slide 15

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