Nuclear Fission Renaissance: Opportunities for Research

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Nuclear Fission Renaissance: Opportunities for Research Mujid S. Kazimi Director, Center for Advanced Nuclear Energy Systems TEPCO Professor of Nuclear Engineering Professor of Mechanical Engineering Kazimi@mit.edu, tel 1-617-253-4206 November 29, 2007 MIT Center for Advanced Nuclear Energy Systems

Center For Advanced Nuclear Energy Systems Advanced Power Reactors Research Programs Nuclear Fuel Cycle Economics and Policy Education Programs Professional Courses - N u c lear Plant Safety - R e actor Technology for Power Plant Executives with INPO - R i s k-informed Operational Decision Making - M a terials Degradation Management now EPR I Nuclear Systems Performance Management Symposium Series - H i g h Burnup LWR Fuel - N u c lear Energy and the Hydrogen Econom y - S i mulation of Fuel Cycle - N e x t Generation Reacto r - I n n ovative Nuclear System s - R e t hinking the Fuel Cycle - S u percrit. CO2 Power Cycl e - D i r ections for Breakthrough Researc h Nuclear Energy and Sustainability National & International Collaborations * Battelle Energy Alliance for INL management * Nuclear Regulatory Commission for Adv. React. EPRI/ENI Waste Manage. * TEPCO on BWR advanced technology * CEA on fuel cycle issues * INET-Tsinghua Univ. on gas reactors MIT Center for Advanced Nuclear Energy Systems

Looking for the next technology High power density fuel for PWRs and BWRs Annular Fuel for PWRs (DOE, proposed for KAERI) Slim Fuel for BWRs (TEPCO) Cross Shaped Fuel for BWRs (TEPCO) Ceramic cladding materials for high temperature water reactors (W, proposed for EPRI) The use of nuclear energy to enhance economics of liquid fuels Design of a nuclear system to heat up oil fields. (proposed for ENI) design of a hydrogen production system using a medium temperature reactor (MIST) Fuel Cycle Options for An Expanding Nuclear Energy (EPRI/NEI) Assessment of Uranium resource magnitude and cost Physics of actinide burning designs for LWRs, Gas Reactors and Fast reactors. Fuel Cycle System Simulation Code Assessment - CAFCA, others Economics of separation and manufacturing of actinide fuels MIT reactor redesign for higher power with LEU (DOE-ANL)

Ceramic SiC as a Clad for LWR Fuel A project involving MIT, Westinghouse, Gamma Engineering, and ORNL Objective is to enable high power density, higher burnup, and higher water exit temperatureas a means to improve future LWR economics Zr SiC Long-term Service Temperature ~750ºC -1700ºC Cross-Section ~193 mb ~148 mb Thermal Conductivity 33 watt/m/ºk 5 watt/m/ºk 17% Steam Corrosion in 400 sec <12OOºC -19OOºC BWR water corrosion @360ºC@ 32 days (recision rate) 1 micron <0.1 micron 1. Good performance during irradiation Gap changes slowly with time, even during a transient due to low creep below 1000 ºC. Large margin to dissociation at 2000 ºC Relevant clad properties do not degrade with time, temperature, or radiation (after initial conductivity reduction) 2. Very low operating and accident corrosion rates Estimated <10% Zr corrosion rate in BWR conditions UO 2 /SiC interaction not an issue SiC/steam/air corrosion rates 10-6 to 10-7 of Zr corrosion rates Reduced hydrogen production during severe accidents 3. Potential for allowing high clad temperature during transients, thus eliminating Critical Heat Flux issues 4. Reduced cladding neutron absorption cross sections

Gamma/NovaTech Winding Architectures Bamboo-A 2 Layers 3 Layers Thick at Inter-Weaves Inter-weaves Align Axially Bamboo-C 2 Layers 3 Layers Thick at Inter-Weaves Inter-weaves Align Circumferentially Max Interweave 2 Layers 3 Layers Thick at Inter-Weaves Inter-weaves Distributed

Summary of MITR Irradiation Testing Specimens under PWR coolant conditions (300 C, 10 MPa, 20 cc/kg H 2, 800 ppm B, 2.2 ppm Li) Initial exposure of 24 in-core samples and 15 above-core samples for 68 EFP Days, 4 months elapsed time, with interim examination of sample subset (see figure) Weighing and visual inspection at MIT, mechanical property testing at ORNL Second exposure of 12 new and 12 continued samples for 156 EFP Days ended October 9. Examination is now beginning. Failure Load (lbs) 1000 900 800 700 600 500 400 300 200 100 0 F H B D Specimen Type Several samples showed promise, But not all As-Fabricated Irradiated Out-of-core

Expanding to new sciences Nanotechnology Solid surfaces manufacturing of actinide fuels Nanofluids in radiation environments Improve efficiency of energy conversion Simulation/Computation Connecting the atomic scale to the macroengineering Reducing design development time and effort Understanding the impact of fuel cycle options Electrochemistry Reducing the costly corrosion rates Boosting the performance of solid oxide electrolyzers Boosting the performance of catalysts in separation processes

Near-term markets Fertilizers Oil Refining Why nuclear For Heat and Hydrogen? Mid-term markets Coal Liquefaction Tar Sands Remote Power Long-term markets Transportation Nuclear Energy CO2-free Efficient and cost-competitive Size/location to address the industry needs Energy Products Electricity Heat Hydrogen Synthetic fuels Services Chemical Industry Transportation Illumination Heating * The use of heat and/or hydrogen from nuclear energy in place of natural gas Reduces carbon emissions, Provides a hedge against natural gas price fluctuations, and Prolongs the availability of natural gas for other applications * Oil industry should benefit from an advanced technology to aid in oil production and refining without requiring a large network of transportation infrastructure.

Can economic H 2 be made with medium temp.? PRECOOLER 1 8 MAIN COMPRESSOR 2 LOW TEMPERATURE RECUPERATOR Nuclear plant SCO2-GFR and AGR were evaluated. But FSR or SCWR are also possible. 8 FLOW MERGE 3 3 7 8 6 3 8 RECOMPRESSING COMPRESSOR FLOW SPLIT 5 6 TURBINE 650 C 473 C 4 HIGH TEMPERATURE RECUPERATOR 527 C REACTOR Steam 100 C 1bar Electrolyzer Yes and at very attractive efficiencies 45% at 650 C IHX material problem eliminated (T=525 C) Materials problem for heat transport eliminated (steam line at 200 C) Reactor operates between 475 and 650 C and only electrochemical plant runs at 900 C 30 C H 2 O Electricity to grid H 2 266 C Electrochemical plant 870 C 870 C O 2 266 C Electricity 900 C Key enabling features: Recover heat from H 2 and O 2 Ohmic heating helps keep cell hot