Greenlane Biogas Gas Cleanup Technology. Developments and Key Considerations.

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Greenlane Biogas Gas Cleanup Technology. Developments and Key Considerations. Cash Cow. RNG for Transportation in Washington. University Place, July 16 th, 2013 www.americanbiogascouncil.org

Our Company

Greenlane Greenlane started as Flotech, which was founded 1986 in New Zealand to provide machinery installation services to the compressed natural gas industry. Greenlane is the global leader in the biogas upgrading market, with ~70 installations in 15 countries. The company uses a water scrubbing and pressure / temperature adsorption gas cleaning process to produce renewable natural gas (RNG) from biogas and landfill gas. The organization operates internationally, offering solutions for: Gas Purification, Drying and Conditioning Industrial Heat Exchange Gas Compression Technical Support, Field Services and Spare Parts

Biogas to Renewable Natural Gas

Biogas to RNG BIOGAS requires upgrading to be used as CNG or LNG Vehicle Fuel

Raw Biogas Characteristics Pressure: Common: 2 8 inches of water column Municipal applications: up to 15 inches Major Constituents: Constituent Concentration Methane (CH 4 ) 55-60% Carbon Dioxide (CO 2 ) 40-45% Nitrogen (N 2 ) 0.4-1.2% Oxygen (O 2 ) 0.0-0.4% Hydrogen Sulfide (H 2 S) 0.02-0.4% Water (H 2 O) Saturated

Biogas Use Options Heat Only: ~92% Heat Recovery Efficiency Power Only: ~38% Electrical Efficiency Increasing Capital Costs Renewable Natural Gas: ~99% Energy Available to Pipeline Combined Heat and Power (CHP): ~65% Electrical and Heat Recovery Efficiency CNG Vehicle Fuel: ~99% Energy Available to Vehicle

Vehicle Fuel vs Other Uses 2010 Canada Gas Association

Biogas to Vehicle Fuel Examples Greenlane Manuka Motala, Sweden Greenlane Totara+ Fair Oaks, Indiana Greenlane Rimu Hamilton, Ontario Greenlane 2 x Totara Madrid, Spain

Fair Oaks Process Overview Electric Generation 300 SCFM Anaerobic Digestion 1,800 SCFM Biogas Upgrading System 1,500 SCFM 891 SCFM Biomethane Testing Secondary Compression and Utility Injection Fueling Station with Compression

Case Study Fair Oaks, IN A Greenlane Totara+ system upgrades up to 1500 scfm of biogas to both vehicle fuel and pipeline injection The installation is at a large dairy farm in NW Indiana. Anaergia integrated and operates the overall system and the renewable natural gas (RNG) station was installed and operated by Clean Energy Fuels The biomethane is used to fuel the dairy trucks delivering the milk, though the fuelling station is open to the public Fair Oaks, Indiana Totara+ System Installation The plant was commissioned in 2012 Greenlane Totara Compression System Fair Oaks, Indiana

Fair Oaks Indiana Reasons for RNG Low Avoided Price for Electricity High Gas Output Location Close to Fuelling Station Dedicated Routes Dedicated Fleets RIN s Tax Credits and Incentives Industry Commitment to Sustainability

Digester to Biogas Upgrading

Technical Considerations

RNG Interchangeability Upgraded biogas can be interchangeable with natural gas Selected standard requirements for grid injection or for utilization as vehicle fuel. Compound Units Reported Tariff Range Heating Value Btu/scf 950-1000 (min) 1075-1200 (max) Carbon Dioxide % volume 1-3 Nitrogen % volume 1-4 Oxygen % volume 0.001-1 Hydrogen Sulfide grains of H2S/100scf 0.25-1 Water Content lb/mmscf 4-7 Source: AGA Report No. 4A - Natural Gas Contract Measurement and Quality Clauses (DRAFT update, 2009)

Upgrading Steps Humidity Control Sulfide & Siloxane Removal Raw Biogas CO 2 Removal Water Wash Amine Scrubber Compression & Offtake Tube Trailers (4000 psi) Biogas Dryer Chiller Dry Gas Biofiltration Iron Sponge Sulfatreat Sulfide 20-200 ppm Membrane Cryogenic PSA Pressure 100-500 psi Gas Grid Injection (50-1000 psi) Vehicles (3500 Psi) Activated Carbon Silica Gel Medium BTU Biogas To on site Power Generation Or Direct use www.americanbiogascouncil.org

Water Scrubbing - a Simple Concept Biogas is primarily methane (CH 4 ) and carbon dioxide (CO 2 ) Water under pressure can be used to separate these two gases through their different solubility in H 2 O

Water Regeneration Water from the scrubber is sent to flash tank to depressurize, so the small amount of absorbed methane can be removed from the water The water is then sent to a stripper that removes the gases absorbed in the water The water can now be reused to clean biogas

How Water Scrubbing Works The raw biogas is compressed, then fed to a scrubbing vessel where it is contacted with water. CO2, H2S, siloxanes and other trace contaminants are preferentially absorbed by the water Absorbed methane is flashed off, in a vessel at a lower pressure and recovered by returning it to the start of the process Product gas is further purified by a proprietary TSA, before being analyzed and delivered

Thank You for Your Attention! sean.mezei@greenlanebiogas.com