Revision date: 10/15/2015 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Product name : Mixture Product code : 20112 : Green Glass Cleaner- GR2252 1.2. Relevant identified uses of the substance or mixture and uses advised against 1.3. Details of the supplier of the safety data sheet Advantage Chemical, LLC Temecula, CA, 92590 T 1-855-238-2436 1.4. Emergency telephone number Emergency number : 1-800-424-9300 ChemTrec SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Not classified 2.2. Label elements GHS-US labelling No labelling applicable 2.3. Other hazards 2.4. Unknown acute toxicity (GHS-US) SECTION 3: Composition/information on ingredients 3.1. Substance 3.2. Mixture Name Product identifier % GHS-US classification ethanol, conc=90%, aqueous solution (CAS No) 64-17-5 1-10 Flam. Liq. 2, H225 Carc. 1A, H350 Full text of H-statements: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Remove victim to fresh air and keep at rest in a position comfortable for breathing. : Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. : Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER or doctor/physician. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries : Causes severe skin burns and eye damage. Symptoms/injuries after inhalation : May cause cancer by inhalation. Symptoms/injuries after eye contact : Causes serious eye damage. 10/15/2015 EN (English) Page 1
4.3. Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture Fire hazard : Heating increases the fire hazard. 5.3. Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Remove ignition sources. Use special care to avoid static electric charges. No open flames. No smoking. 6.1.1. For non-emergency personnel Emergency procedures 6.1.2. For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Ventilate area. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. : Avoid contact with skin, eyes and clothing. 7.2. Conditions for safe storage, including any incompatibilities Technical measures Storage conditions Incompatible products Incompatible materials : Do not eat, drink or smoke when using this product. Always wash hands after handling the product. : Does not require any specific or particular technical measures. : Do not expose to temperatures exceeding 50 C/ 122 F. : Strong bases. Strong acids. Storage temperature : 25 (5-42) C 7.3. Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters Green Glass Cleaner- GR2252 ACGIH OSHA ACGIH : Sources of ignition. Direct sunlight. Heat sources. 10/15/2015 EN (English) 2/6
OSHA 8.2. Exposure controls Personal protective equipment : Avoid all unnecessary exposure. Hand protection Eye protection Skin and body protection : Wear protective gloves. : Chemical goggles or face shield. : Wear suitable protective clothing. : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Colour Odour Odour threshold : Liquid : Blue : characteristic ph : >= 11 Melting point Freezing point : <= 0 C Boiling point : >= 100 C Flash point : >= 90 C Relative evaporation rate (butylacetate=1) Flammability (solid, gas) Explosive limits Explosive properties Oxidising properties Vapour pressure Relative density Relative vapour density at 20 C Density Solubility Log Pow Log Kow Auto-ignition temperature Decomposition temperature Viscosity Viscosity, kinematic Viscosity, dynamic : >= 1.02 (1.01-1.03) g/ml : Soluble in water. Water: Solubility in water of component(s) of the mixture : ethanol, conc=90%, aqueous solution: Complete triethanolamine, conc >85%, aqueous solutions: Complete 9.2. VOC content : <= 51 g/l SECTION 10: Stability and reactivity 10.1. Reactivity 10.2. Chemical stability 10.3. Possibility of hazardous reactions 10/15/2015 EN (English) 3/6
10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures. 10.5. Incompatible materials Strong acids. Strong bases. 10.6. Hazardous decomposition products fume. Carbon monoxide. Carbon dioxide. May release flammable gases. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity LD50 oral rat > 5000 mg/kg (Rat) LD50 dermal rabbit > 5000 mg/kg (Rabbit) LC50 inhalation rat (mg/l) > 20 mg/l/4h (Rat) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity ph: >= 11 ph: >= 11. IARC group 1 - Carcinogenic to humans Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Potential adverse human health effects and symptoms Symptoms/injuries after inhalation Symptoms/injuries after eye contact : Based on available data, the classification criteria are not met. : May cause cancer by inhalation. : Causes serious eye damage. SECTION 12: Ecological information 12.1. Toxicity LC50 fish 1 7750 mg/l (96 h; Pisces; Pure substance) EC50 Daphnia 1 9300 mg/l (48 h; Daphnia magna; Pure substance) LC50 fish 2 13000 mg/l (96 h; Salmo gairdneri (Oncorhynchus mykiss); Pure substance) EC50 Daphnia 2 10800 mg/l (24 h; Daphnia magna; Pure substance) Threshold limit other aquatic organisms 1 65 mg/l (72 h; Protozoa; Pure substance) Threshold limit algae 1 1450 mg/l (192 h; Microcystis aeruginosa; Pure substance) Threshold limit algae 2 5000 mg/l (168 h; Scenedesmus quadricauda; Pure substance) 12.2. Persistence and degradability Green Glass Cleaner- GR2252 Persistence and degradability Persistence and degradability Readily biodegradable in water. No (test)data on mobility of the components available. Biochemical oxygen demand (BOD) 0.8-0.967 g O₂/g substance Chemical oxygen demand (COD) 1.70 g O₂/g substance 10/15/2015 EN (English) 4/6
ThOD 2.10 g O₂/g substance BOD (% of ThOD) 12.3. Bioaccumulative potential Green Glass Cleaner- GR2252 Bioaccumulative potential 0.43 % ThOD Log Pow -0.32 Bioaccumulative potential Bioaccumulation: not applicable. 12.4. Mobility in soil 12.5. Other adverse effects Effect on the global warming : No known ecological damage caused by this product. : Avoid release to the environment. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations Ecology - waste materials SECTION 14: Transport information : Dispose of contents/containers in hazardous or special waste collection point, an approved disposal plant, a licensed hazardous waste disposal contractor or authorized waste collection site in accordance with local, regional and/or international regulation, except for empty clean containers which can be disposed of as non hazardous waste. : Avoid release to the environment. Department of Transportation (DOT) In accordance with DOT Not regulated for transport Additional information : No supplementary information available. ADR Transport by sea Air transport SECTION 15: Regulatory information 15.1. US Federal regulations Listed on the United States TSCA (Toxic Substances Control Act) inventory 15.2. International regulations CANADA EU-Regulations Classification according to Regulation (EC) No. 1272/2008 [CLP] Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] Not classified 10/15/2015 EN (English) 5/6
National regulations Listed on IARC (International Agency for Research on Cancer) 15.3. US State regulations U.S. - New Jersey - Right to Know Hazardous Substance List SECTION 16: Revision date : 10/15/2015 : None. Full text of H-statements: ------ Carc. 1A Carcinogenicity, Category 1A ------ Flam. Liq. 2 Flammable liquids, Category 2 ------ H225 Highly flammable liquid and vapour ------ H350 May cause cancer NFPA health hazard NFPA fire hazard NFPA reactivity NFPA specific hazard : 0 - Exposure under fire conditions would offer no hazard beyond that of ordinary combustible materials. : 1 - Must be preheated before ignition can occur. : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. : None HMIS III Rating Health Flammability Physical Personal Protection : 0 Minimal Hazard - No significant risk to health : 1 Slight Hazard - Materials that must be preheated before ignition will occur. Includes liquids, solids and semi solids having a flash point above 200 F. (Class IIIB) : 0 Minimal Hazard - Materials that are normally stable, even under fire conditions, and will NOT react with water, polymerize, decompose, condense, or self-react. Non-Explosives. : B B - Safety glasses, Gloves SDS US (GHS HazCom 2012) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 10/15/2015 EN (English) 6/6