MARITIME ACADEMY ONLINE: Course: IMDG CODE TRAINING MODULE of SHORE- BASED PERSONNEL Module 2

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MARITIME ACADEMY ONLINE: Course: IMDG CODE TRAINING MODULE of SHORE- BASED PERSONNEL Module 2 Basic qualifications in cargo handling, which everyone in logistics must know.

Contents of Module 2 Chapter 4 Marking and labelling of packages... 3 Chapter 5 Documentation... 14 Chapter 6 Segregation... 17 Please study carefully and complete the final test 2

Chapter 4 Marking and labelling of packages An examples of packing marking (Codes for designated types of packagings) Numerals for different kinds (Types) of packagings: 1. Drum; 2. (reserved); 3. Jerrican; 4. Box; 5. Bag; 6. Composite packaging 3

Capital letters for the different types of material: A Steel (all types and surface treatment); B Aluminium; C Natural wood; F Reconstituted wood; G Fibreboard; H Plastics material; L Textile; M Paper, multiwall; N Metal (other than steel or aluminium); P Glass, porcelain or stoneware A letter designating the packing group or groups for which the design type has been successfully tested: X for packing groups I, II and III ; Y for packing groups II and III ; Z for packing group III only Proper shiping name, proceded UN shall be displayed on each package. Labels in accordance with class or division and subsidiary risk(s) if any shall be displayed on each package. 4

An example of packing marking and labeling for Dangerous goods UN1921, PROPYLENEIMINE, STABILIZED 3(6.1), PGI, (-4 Cc.c) PROPYLENEIMINE, STABILIZED UN1921 5

Intermediate Bulk containers (IBC) The IBC is a packing method that falls between the carriage of a substance in bulk and in normal packagings. The purpose is to gain efficiency in handling but to retain,manoeuvrability. An IBC can be rigid or flexible, made of any material sich as paper, metal, wood or plastic. It can have a variety of opening arrangement and can be used to carry liquids or solids. An IBC must be suitable for handling by mechanical means. An IBC must bear markings in a similar manner to other packaging. The IBC have a capacity of: 1. not more than 3.0 m³ (3000 litres) for solids and liquids of packing groups II and III; 2. not more than 1.5 m³ for solids of packing group I when packed in flexible,rigid plastics, composite, fibreboard or wooden IBCs; 3. not more than3.0 m³ for solids of packing group I when packed in metal IBC; 4. Not more than 3.0 m³ fot radioactive material of class 7. 6

Kinds of IBC. 7

An example of packing marking (Codes for designated types of packagings) Month and year Stacking test Max. permissible of manufacture load gross mass in kg. Material 11A/Y/0216/NL/007/13500/1500 13H3/Z/0716/F/1713/0/1500 31HA1/Y/0501/D/1683/10800/1200 For solids, filled or discharged Type By gravity Under pressure For of more than liquids 10kPa (0.1 bar) Rigid 11 21 31 Flexible 13 - - 8

Capital letters for the different types of material: A Steel (all types and surface treatment); B Aluminium; C Natural wood; F Reconstituted wood; G Fibreboard; H Plastics material; L Textile; M Paper, multiwall; N Metal (other than steel or aluminium); P Glass, porcelain or stoneware A letter designating the packing group or groups for which the design type has been successfully tested: X for packing groups I, II and III ; Y for packing groups II and III ; Z for packing group III only Manufactured: in month and year; Authorized by the: country; Manufactured code; Stacking test load in kilograms; Max. Permissible gross mass in kilograms. Proper shiping name, proceded UN shall be displayed on each package. Labels in accordance with class or division and subsidiary risk(s) if any shall be displayed on each package. 9

An example of marking and labeling IBC for Dangerous goods UN2008, ZIRCONIUM POWDER, DRY 4.2 PG III ZIRCONIUM POWDER, DRY UN2008 11A/Y/0216/NL/007/13500/1500 10

Types of containers. 11

Portable tanks Portable tanks are defined as a tank having a capacity of more than 450 litres and which is fitted with its own service equipment and is suitable for the transport of substances liquid and solid. There are 8 types of tank which are separated into 3 groups. 1. Portable tanks for the dangerous goods other than Class 2 1.1 IMO type 1 tank (portable tank) for transport of substances of classes 3 to 9 fitted with relief devices, having a max. allowable working pressure of 1.75 bar and above; 1.2 IMO type 2 tank (portable tank) for transport of substances of classes 3 to 9 fitted with relief devices, having a max. allowable working equal to or above 1.0 bar but below of 1.75 bar ; 1.3 IMO type 4 tank (road tank vehicle) for transport of substances of classes 3 to 9 fitted with relief devices, having a max. allowable working pressure of 1.75 bar and above; 2. Portable tanks for the non-refrigerated gases of Class 2 2.1 IMO type 5 tank (portable tank) fitted with pressure-relief devices which is used for non-refrigerated gases of class 2; 2.2 IMO type 6 tank (road tank vehicle) fitted with pressure-relief devices which is used for non-refrigerated gases of class 2 and includes a semi-trailer with a permanently attached tank or a tank attached to a chassis which is fitted with items of service equipment and structural equipment necessary for the transport of gases. 3. Portable tanks for the refrigerated gases of Class 2 3.1 IMO type 7 tank (portable tank) - thermally insulated portable tank fitted with items of service and structural equipment necessary for the transport of refrigerated liquefied gases. 3.2 IMO type 8 tank (road tank vehicle) for the transport of refrigerated liquefiedgases of class 2 and includes a semi-trailer with a permanently attached thermally insulated tank fitted with items of service equipment and structural equipment necessary for the transport of refrigerated liquefied gases 12

Placarding and marking requirements of cargo transport units 1. Placarding requirements Containers (cargo transport units) containing dangerous goods or residues of dangerous goods shall clearly display placards as follows: 1.1 a freight container, semi-trailer or portable tank; one on each side and one on each end of the unit; 1.2 portable tanks having a capacity of less than 3000 L on only two opposite sides; 1.3 any other cargo transport unit: at least on both sides and on the back of the unit. 2. Marking requirements Display of proper shipping name of the contents shall be durably marked on at least both sides of: 2.1. tank cargo transport units containing dangerous goods; 2.2. bulk containers containing dangerous goods; 2.3. any other cargo transport unit containing packaged dangerous goods of a single commodity for which no placard, UN number or marine pollutant mark is required. Alternatively, the UN number may be displayed. 3. Display of UN numbers (except for goods of class1) shall be displayed of: 3.1 solids, liquids or gases transported in tank cargo transport units, including on each compartment of a multi-compartment tank cargo transport unit; 3.2 packaged dangerous goods loaded in excess of 4000 kg gross mass, to which only one UN number has been assigned and which are the only dangerous goods in the cargo transport unit; 3.3 solid dangerous goods in bulk container. 13

Chapter 5 Documentation Mandatory content of the dangerous goods documentation The consignor who offers dangerous goods for transport shall give to the carrier the information applicable to those dangerous goods, including any additional information and documentation as specified in IMDG Code. This information my be provided on a dangerous goods transport document. The dangerous goods transport document shall contain the following information for each dangerous substance, material or article offered for transport: 1. the UN number preceded by the letters UN ; 2. the proper shipping name, including the technical name enclosed in parenthesis (if any); 3. the primary hazard class; 4. subsidiary hazard class (if any); 5. were assigned, the packing group for the substance. May be preceded by PG ; 6. Marine pollutant (if any); 7. Flashpoint: If the dangerous goods to be transported have a flashpoint of 60 C or below (in C closed-cup (c.c.); 8. When dangerous goods are transported according to the exception for the dangerous goods packed in limited quantities, the words limited quantity or LTD QTY shall be included. 14

Information required in addition to the dangerous goods description. I. Total quantity of dangerous goods (Gross mass/net mass); II. The number and kind of packages (e.g. drum, box,etc.) III. Container identification No/vehicle registration No. Examples of dangerous goods description: I. UN 1098, Allyl Alcohol, class 6.1, (class3), PG I, (21 C c.c); II. UN 1541, Acetone Cyanohydrin, Stabilized, class 6.1, PG I, Marine pollutant; III. Un 3082, Environmentally hazardous substance, liquid.n.o.s. (Neonol of AF 9-9 grade), class 9, PG III; 15

MULTIMODAL DANGEROUS GOODS FORM This form may be used as a dangerous goods declaration as its meets the requirements of SOLAS, chapter VII, regulation 4; MARPOL, Annex III, regulation4. 1.Shipper Nordichem Europe, SIA Ozolnieku iela 11, Marupe, Marupes nov. LV- 2167, Latvia 2.Transport document number 3 Page 1 of pages 4 Shipper s reference 5 Freight forwarder s reference 6 Consignee 7 Carrier ( to be completed by the carrier) Procon Engineering (PVT) LTD, D-54 to D-57, N.W.I. Zone, Port Qasim, Karachi, Pakistan SHIPPER S DECLARATION I hereby declare that the content of this consignment are fully and accurately described below by the proper shipping name, and are classified, packaged, marked and labeled/placarded and are in all respects in proper condition for transport according to the applicable international and national governmental regulations. 8 this shipment s is within the limitations for: 9 Additional handling information (Delete non-applicable) 10 Vessel/flight No, and date 11 Port/place of loading: port Riga m/v Conmar Island 12 Port/place of discharge: 13 Destination Karachi, Pakistan Port Qasim 14 Shipping marks Number and kind of packages; description of goods Gross mass (kg) Net mass (kg) 10 wooden pallets: 40 x 145 Kg drums 6650 Kg 5800 Kg UN 1993 Flammable liquids, N.O.S. (Naphta) class 3, PG III, (-4 C c.c.) 15 Container identification No/vehicle registration No. ECMU2064212 CONTAINER/VEHICLE 16 Seal number s F1774535 PACKING CERTIFICATE I hereby declare that the goods described above have been packed/loaded into the container/vehicle identified above in accordance with applicable provisions MUST BE COMPLETED AND SIGNED FOR ALL CONTAINER/VEHICLE LOADS BY PERSON RESPONSIBLE FOR PACKING/LOAD 20 Name of company: Nordichem Europe, SIA Name/status of declarant: Mareks Andersons Packer Place and date Riga, 10/11/2016 Signature of declarant 17 Container/vehicle size and type 20 DC 18Tare (kg) 21 RECEIVING ORGANISATION RECEIPT mass 850 Kg 19 Total gross mass (including tare) (kg) 6650 Kg Receiving the above number of packages/containers/trailers in apparent good order and conditions, unless stated hereon: RECEIVING ORGANISATION REMARKS: Haulier s name Vehicle reg.no. Signature and date 22 Name of company(of SHIPPER PREPARING THIS NOTE): Nordichem Europe, SIA Name/status of declarant Magnus Petersons Executive Assistent Place and date Rigaa, 10/11/2016 Signature of declarant 16

Chapter 6 Segregation General segregation provisions Segregation is the process of separating two or more substances or articles which are considered mutually incompatible when their packing or stowage together may result in undue hazard in case of leakage or spillage, or any other accident. General Segregation table for Dangerous Goods Tab. No 1 Class 1.1 1.2 1.5 1.3 1.6 1. 4 2. 1 2. 2 2. 3 3 4.1 4.2 4.3 5.1 5.2 6.1 6.2 7 8 9 1.1,1.2,1.5 * * * 4 2 2 4 4 4 4 4 4 2 4 2 4 X 1.3,1.6 * * * 4 2 2 4 3 3 4 4 4 2 4 2 2 X 1.4 * * * 2 1 1 2 2 2 2 2 2 X 4 2 2 X 2.1 4 4 2 X X X 2 1 2 2 2 2 X 4 2 1 X 2.2 2 2 1 X X X 1 X 1 X X 1 X 2 1 X X 2.3 2 2 1 X X X 2 X 2 X X 2 X 2 1 X X 3 4 4 2 2 1 2 X X 2 2 2 2 X 3 2 X X 4.1 4 3 2 1 X X X X 1 X 1 2 X 3 2 1 X 4.2 4 3 2 2 1 2 2 1 X 1 2 2 1 3 2 1 X 4.3 4 4 2 2 X X 2 X 1 X 2 2 X 2 2 1 X 5.1 4 4 2 2 X X 2 1 2 2 X 2 1 3 1 2 X 5.2 4 4 2 2 1 2 2 2 2 2 2 X 1 3 2 2 X 6.1 2 2 X X X X X X 1 X 1 1 X 1 X X X 6.2 4 4 4 4 2 2 3 3 3 2 3 3 1 X 3 3 X 7 2 2 2 2 1 1 2 2 2 2 1 2 X 3 X 2 X 8 4 2 2 1 X X X 1 1 1 2 2 X 3 2 X X 9 X X X X X X X X X X X X X X X X X 1- away from --- at least 3m horizontally; 2- separated from --- at least 6m horizontally; 3- separated by a complete compartment or hold from --- at least 12 m horizontally; 4- separated longitudinally by an intervening complete compartment or hold from.--- at least 24 m horizontally; * - see 7.2.7.1 of this chapter for the segregation provisions between class 1 substances or articles 17

Segregation table for Dangerous goods in port areas Tab. No 2. Classes 2.1 2.2 2.3 3 4.1 4.2 4.3 5.1 5.2 6.1 8 9 Flammable gases 2.1 0 0 0 s a s 0 s s 0 a 0 Non-toxic, non-flammable gases 2.2 0 0 0 a 0 a 0 0 a 0 0 0 Toxic gases 2.3 0 0 0 s 0 s 0 0 s 0 0 0 Flammable liquids 3 s a s 0 0 s a s s 0 0 0 Flammable solids, self-reactive substances and desensitized explosives 4.1 a 0 0 0 0 a 0 a s 0 a 0 Spontaneously combustible substances 4.2 s a s s a 0 a s s a a 0 Substances which, in contact with water, emit 0 0 0 a 0 a 0 s s 0 a 0 flammable gases 4.3 Oxidizing substances 5.1 s 0 0 s a s s 0 s a s 0 Organic peroxides 5.2 s a s s s s s s 0 a s 0 Toxic substances (liquid and solids) 6.1 0 0 0 0 0 a 0 a a 0 0 0 Corrosives (liquid and solids) 8 a 0 0 0 a a a s s 0 0 0 Miscellaneous dangerous substances and articles 9 0 0 0 0 0 0 0 0 0 0 0 0 Note for segregation table Cargoes of classes 1 (except division 1.4S), 6.2 and 7 should normally be allowed into the port area for direct shipment for delivery only. These classes have not been included in the table. However, if, through unforeseen circumstances, these cargoes have to be temporarily kept, it should be designated areas. Segregation requirements of the individual class as stipulated in the IMDG Code should be considered by the port authority when establishing specific requirements. Segregation advice for the temporary keeping of dangerous goods in port areas I. Packages/IBC/ trailers/open containers/flat racks or platform containers: 0 = no segregation necessary unless required by the individual schedules; a= away from minimum 3m separated required; s= separated from - in open areas, minimum 6 m separation, in sheds or warehouses, minimum 12m separation unless by an approved fire wall; II. Closed containers/portable tanks/closed road vehicles: 0 = no segregation necessary; 18

a = away from - no segregation necessary; s = separated from - in open areas, longitudinally and laterally, minimum 3m separation required, in sheds or warehouses longitudinally and laterally, minimum 6m separation required unless separated by an approved fire wall; III. Open road vehicles/railway freight wagons/open top containers: 0 = no segregation necessary unless required by the individual schedules; a = away from minimum 3m separated required; s= separated from - in open areas, minimum 6 m separation, in sheds or warehouses, minimum 12m separation unless by an approved fire wall; An example: Packages * UN1364 Cotton Waste,oily, 4.2 and UN2067 Ammonium nitrate based fertilized, 5.1. Segregation level - s - separated from - in open areas, minimum 6 m separation, in sheds or warehouses, minimum 12m separation unless by an approved fire wall; **Closed containers for 4.2 and 5.1. Segregation level - s - in open areas, longitudinally and laterally, minimum 3m separation required, in sheds or warehouses longitudinally and laterally, minimum 6m separation required unless separated by an approved fire wall; *** Open top containers for 4.2 and 5.1 Segregation level s - minimum 6m separated require. Please study carefully and complete the final test 19