Technologies to Mitigate Climate Change

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IOM Roundtable on Environmental Health, San Francisco September 11, 2007 Stanford University Global Climate & Energy Project Technologies to Mitigate Climate Change Lynn Orr Stanford University

The Punchlines The challenge is huge (nothing less than changing the world s energy systems), There is plenty we can do now to start the process, The transitions will be decades long, A sustained effort will be needed across a wide-ranging portfolio of energy resources and transformations So, let s get to work.

World Primary Energy Supply The world is heavily dependent now on fossil fuels ~ 80% Time scales for changing the fraction of fossil fuel resources used are long decades, at least Significant effort needed to make new technology options cost-effective

The Need for Technology Concentrations of CO 2 will rise above current values (380 ppm), even under the most optimistic scenarios. Stabilization will require that emissions peak and then decline. Peak timing depends on the stabilized concentration. Improvements in in efficiency, introduction of of renewables, nuclear power, all all help. New technology will be be needed for for the really deep reductions.

So what do we do? Look for energy efficiency at every turn there is plenty of room for efficiency improvement with technologies we have today, especially in the US (lots of near-term opportunities in buildings, lighting, vehicles, etc). But growth in demand, particularly in the developing world will require that new technologies be brought on line if greenhouse gases emissions are to be reduced at the same time. Engage in a vigorous research effort to lay foundations for future energy technologies. Use a portfolio approach: guessing now the shape of the energy mix and markets 30-50 years in the future is doomed to failure.

US energy use and CO 2 emissions are currently projected to increase by 2030 Quads Mt CO 2 While renewables are projected to grow, coal grows more Most coal is used for electric power generation Petroleum use for transportation also grows In a carbon-constrained world, this will have to change Source: EIA Energy Outlook 2007

How do we change this? One transition pathway (EPRI) Changes to the US electric generation system by 2030 to achieve a 45% reduction in CO 2 from EIA 2007 predicted emissions for 2030: Efficiency: reduce load growth from 1.5%/yr to 1.1%/yr Renewables: increase from 30 GWe to 70 GWe Nuclear Generation: increase from 12. GWe 64 GWe Advanced Coal Generation: increase new plant efficiency to 46% by 2020, 49% by 2030, upgrade 150 GWe of old plants Carbon Capture and Storage: widely deployed after 2020 Plug-In Hybrids: 5% of base load in 2030 Distributed energy generation: 5% of baseload in 2030 Source: EPRI, The Power to Reduce CO 2 Emissions, 2007

What resources can we use? Exergy flow of planet Earth (TW)

PV Land Area Requirements to Supply US Energy Use Solar resource is huge cost is the primary issue About 1.5% of US land area would be required to generate our current total energy use 4000 km 2 to offset 1 Gt CO 2 /yr Intermittency better grid and/or storage?

Wind Wind is close to competitive now with no subsidy A 1MW wind turbine can offset ~2500 t CO 2 /yr, 400,000 turbines for 1 Gt CO 2 /yr bigger machines are now available Intermittency will require more grid capacity to connect wind resource to users

Nuclear Power Nuclear power no CO 2 emissions (except for the concrete and steel in the plant). Significant capital cost barriers Waste storage new fuel cycles can reduce but not eliminate need for waste storage Concerns about nuclear proliferation limit fuel reprocessing at present

Cost of Electricity with a Carbon Tax 0.25 0.2 Levelized Cost Comparison for Electric Power Generation With $100 per Ton Tax on Carbon (2006 Fuel Prices) Carbon Tax Fuel-2006 Variable O&M Fixed O&M Charges Capital Charges 0.15 $/KWHr (2006$s ) 0.1 0.05 0 Nuclear Coal Gas CC Gas CT Solar PV Solar Thermal Generation Technology Wind Source: J. Weyant, Energy Modeling Forum, Stanford University

Biofuels Biofuels possible significant contribution if we can use cellulose/lignin to make ethanol or another liquid fuel Ethanol from corn ~30% better than gasoline on CO 2 emissions (if credit given for byproducts). Gasification options can convert biomass to fuels Biodiesel will remain small if produced from seed oils (palm oil, jatropha may change this)

Oceans Tides: small intermittent resource (0.2-18m gravity head), probably only makes sense for a modest number of locations. OTEC: small gradient in temperature, large equipment, low efficiency, high cost. Waves: small gravity head so small resource, hard to capture in tough operating environment. http://www.rise.org.au/info/tech/tidal/index.html Ocean systems are likely to be a small contributor to overall energy use. http://www.nrel.gov/otec/electricity.html

Hybrid Vehicles Hybrid cars ~30-40% reduction in fuel use vs conventional vehicle of same weight (replace 360,000 cars to offset 1 MMt CO 2 /yr) Plug-in hybrids can help (with better batteries) but require significant improvement in grid carbon

More Alternatives Hydrogen issues include how to make the hydrogen, how to store it, cost of fuel cells. Hydroelectric power untapped US resource is modest Geothermal energy modest resource but useful in the right places (Iceland, Hawaii, ) The real challenge is to avoid using much more coal or heavy oils and tar sands, particularly in the US, China, and India.

Relative Carbon Emissions of Alternative Hydrocarbon Fuels Coal to Liquids Gas to Liquids Tar Sand & Heavy Oil Enhanced Oil Recovery Combustion Emissions Min Mfg Emissions Max Mfg Emissions Conventional Oil 0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.6 1.8 2 Production of alternative liquid fuels from coal, tar sands, or oil shales increases GHG emissions significantly Volumes of CO 2 storage required to mitigate the upstream emissions will be very large if coal and oil shales are used to offset a significant fraction of conventional hydrocarbon use. Source: Farrell & Brandt, Env. Res. Let. 1, 2006

Research for the Longer Term One Example: The Global Climate and Energy Project.. Goals Goals Fundamental, Fundamental, precommercial precommercialresearch research Novel Novel technology technology options options for for energy energy conversion conversion and and utilization utilization Impact Impact in in the the 10-50 10-50 year year timeframe timeframe Strategy Step-out Step-out research: research: revisit revisit the the fundamentals fundamentals and and explore explore new new approaches approaches High High risk risk // high high reward reward Budget Budget $225M $225M commitment commitment Participants Industrial Industrial sponsors sponsors Academic Academic institutions institutions --Stanford Stanford and and an an increasing increasing number number of of other other universities universities worldwide worldwide

Research Examples - Solar Area Solar electricity Solar hydrogen Organic photovoltaics High efficiency thin-film concepts Photoelectrochemical water splitting Silicon-based quantum structures Efficient photon collection

Research Examples - Bio Area Biomass Bio-hydrogen Bio-electricity Genetic engineering of cellulose accumulation Direct current extraction from the chloroplast of photosynthetic cells Hydrogenase enzyme Genetic evolution of biological systems (bacteria) to produce hydrogen

Advanced combustion Research Examples - Carbon Mitigation Areas CO 2 separation CO 2 sequestration High-efficiency IC engines with theoretical efficiency limits of ~ 60% Novel nanostructured polymeric and inorganic membrane materials Study of the long-term stability and seal integrity of geologic structures (aquifers, oil and gas reservoirs) Cardo polyimide hollow fiber membrane 100µm Membrane reactors combining NG reforming and C capture Hydrotalcite membrane Integrated coal thermal conversion process in supercritical conditions using aquifer brine as a solvent and storage medium

Oil and gas reservoirs: enhanced oil and gas recovery. Deep formations that contain salt water. Coal beds (adsorbed CO 2 replaces adsorbed CH 4 ). What could be done with CO 2 from oxidation reactions? Options for Geologic Storage of CO 2

Conclusions Changing the world s energy systems to reduce GHG emissions is a big challenge, but it can by met by a sustained effort on many fronts. There is way too much coal in the world avoiding relying on it, or capturing and storing the CO 2 from it, is essential if we are to control atmospheric concentrations of CO 2. There is no single, simple solution to this challenge. There is much to do, but there is much that can be done, on a variety of time scales: Much better energy efficiency now Adding more renewable and low GHG technologies available now to the energy mix Research on a wide-ranging portfolio of energy resources and conversion methods for applications in the long term