This SDS adheres to the standards and regulatory requirements of Malaysia and may not meet the regulatory requirements in other countries. 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product information Trade name : Company : Du Pont Malaysia Sdn Bhd 6th Floor, Bangunan Samudra, No. 1, Jalan Kontraktor U1/14, Seksyen U1, HICOM-Glenmarie Industrial Park, 40150 Shah Alam, Selangor Darul Ehsan Malaysia Telephone : +60 3 5569 3006 Telefax : +60 3 5569-3008 Emergency telephone : +60 3 5569-3013 2. COMPOSITION/INFORMATION ON INGREDIENTS Synonyms : B12527036 Prevathon 50SC Rynaxypyr 50SC DPX-E2Y45 50SC Components Chemical Name CAS-No. Concentration Chlorantraniliprole 500008-45-7 5 % Inert Ingredients 95 % 3. HAZARDS IDENTIFICATION Risks Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Safety data Use appropriate container to avoid environmental contamination. This material and its container must be disposed of as hazardous waste. 4. FIRST AID MEASURES General advice Inhalation Skin contact : Never give anything by mouth to an unconscious person. Have the product container or label with you when calling a poison control center or doctor, or going for treatment. : Move to fresh air. Call a poison control centre or doctor for treatment advice. : Take off all contaminated clothing immediately. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control centre or doctor for treatment advice. 1/6
Eye contact Ingestion : Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. If eye irritation persists, consult a specialist. : Consult a physician if necessary. Have person sip a glass of water if able to swallow. DO NOT induce vomiting unless directed to do so by a physician or poison control center. Never give anything by mouth to an unconscious person. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Special protective equipment for fire-fighters Further information : Water spray, Dry chemical, Foam, Carbon dioxide (CO2) : In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment. : Evacuate personnel and keep upwind of fire. If area is heavily exposed to fire and if conditions permit, let fire burn itself out since water may increase the area contaminated. Do not allow run-off from fire fighting to enter drains or water courses. Cool containers / tanks with water spray. Control Runoff. (on small fires) Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. 6. ACCIDENTAL RELEASE MEASURES Personal precautions Environmental precautions Methods for cleaning up Additional advice : Review sections 5 and 7 before proceeding with clean-up. Use personal protective equipment. : Prevent material from entering sewers, waterways, or low areas. : Soak up with sawdust, sand, oil dry or other absorbent material. Dispose of in an approved container. If liquid has been spilt in large quantities clean up promptly by scoop or vacuum. : Refer to the product label for instructions. 7. HANDLING AND STORAGE Handling Advice on safe handling : Provide appropriate exhaust ventilation at places where dust is formed. Wear personal protective equipment. Storage Requirements for storage areas and containers : Do not contaminate water, other pesticides, fertilizer, food or feed in storage. Store in a cool, dry place. Observe label precautions. Store product in original container only in a location inaccessible to children and pets. 2/6
8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components Values Control parameters Basis Chlorantraniliprole (Total dust.) Chlorantraniliprole (Respirable dust.) AEL * 10 mg/m3 DuPont AEL (2007) AEL * 5 mg/m3 DuPont AEL (2007) Engineering measures Use sufficient ventilation to keep employee exposure below recommended limits. Personal protective equipment Respiratory protection : In the case of dust or aerosol formation use respirator with an approved filter. Hand protection : Material: Chemical-resistant gloves Eye protection Skin and body protection Hygiene measures Protective measures : Goggles, face shield, or safety glasses. : Wear protective clothing such as gloves, apron, boots, or coveralls, as appropriate. : Avoid contact with skin, eyes and clothing. Avoid breathing dust. Wash thoroughly after handling. Wash hands thoroughly with soap and water after handling and before eating, drinking, chewing gum or using tobacco. : End users of this product should follow label instructions for personal protection when using this product. 9. PHYSICAL AND CHEMICAL PROPERTIES Form Colour Odour : semi-viscous liquid : white : mild, alcoholic ph : 6.2 Flash point : > 100 C Density Viscosity, dynamic : 1.036 g/cm3 (20 C) : 570 mpa.s 3/6
10. STABILITY AND REACTIVITY Materials to avoid Hazardous decomposition products Hazardous reactions : None reasonably foreseeable. : Carbon dioxide (CO2), nitrogen oxides (NOx) : Hazardous polymerisation does not occur. Stable under normal conditions. 11. TOXICOLOGICAL INFORMATION Acute oral toxicity Acute inhalation toxicity Acute dermal toxicity Skin irritation : LD50/rat : > 5,000 mg/kg : LC50/4 h/rat : > 2.1 mg/l : LD50/rat : > 5,000 mg/kg : rabbit Result: No skin irritation Eye irritation : rabbit Result: No eye irritation Sensitisation : guinea pig Classification: Did not cause sensitization on laboratory animals. Mutagenicity assessment : Tests on bacterial or mammalian cell cultures did not show mutagenic effects. Did not show mutagenic effects in animal experiments. Carcinogenicity assessment Toxicity to reproduction assessment : Did not show carcinogenic effects in animal experiments. : Animal testing did not show any effects on fertility. 12. ECOLOGICAL INFORMATION Ecotoxicity effects Toxicity to fish : LC50/96 h/oncorhynchus mykiss (rainbow trout): 13.8 mg/l EC50/96 h/lepomis macrochirus (Bluegill sunfish): 15.1 mg/l Toxicity to algae Aquatic toxicity : EC50/72 h/pseudokirchneriella subcapitata (green algae): > 2 mg/l : EC50/48 h/daphnia magna (Water flea): 0.0116 mg/l 4/6
Further information on ecology Additional ecological information : No data is available on the product itself. See product label for additional application instructions relating to environmental precautions. 13. DISPOSAL CONSIDERATIONS Product : In accordance with local and national regulations. Do not contaminate ponds, waterways or ditches with chemical or used container. 14. TRANSPORT INFORMATION IMDG UN-Number : 3082 Proper shipping name : Environmentally hazardous substance, liquid, n.o.s. (Chlorantraniliprole) Class : 9 Packaging group : III Labelling No. : 9 Marine pollutant : yes (Chlorantraniliprole) Further information : Not regulated as a hazardous material by IATA. 15. REGULATORY INFORMATION National regulatory information Pesticides Act 1974 (Act 149) (amended 2004). Symbol(s) : N Dangerous for the environment R-phrase(s) : R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S-phrase(s) : S57 Use appropriate container to avoid environmental contamination. S60 This material and its container must be disposed of as hazardous waste. 16. OTHER INFORMATION Sources of key data used to compile the Safety Data Sheet: Department: Du Pont Malaysia Sdn Bhd 5/6
6th Floor, Bangunan Samudra, No. 1, Jalan Kontraktor U1/14, Seksyen U1, HICOM-Glenmarie Industrial Park, 40150 Shah Alam, Selangor Darul Ehsan Malaysia Further information: Take notice of the directions of use on the label., DuPont's registered trademark Significant change from previous version is denoted with a double bar. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The above information relates only to the specific material(s) designated herein and may not be valid for such material(s) used in combination with any other materials or in any process or if the material is altered or processed, unless specified in the text. 6/6