Alcohol Fuels from Biomass Assessment of Production Technologies

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Northern California Rice Field Alcohol Fuels from Biomass Assessment of Production Technologies Pacific Coast Clean Energy Forum Portland, Oregon November 28 & 29, 2007

Introduction Who was behind it? Purpose of Study Cellulose-to-Bioalcohols technologies examined Study approach Findings, conclusions, and path forward

Purpose of Study Review and evaluate candidate technologies for producing ethanol and other alcohols from cellulosic biomass feedstocks, describing development progress to date and future prospects for these technologies. Review and summarize relevant past bioalcohol production technology projects studied or proposed in California. Identify opportunities for new projects involving applications of candidate bioalcohol production technologies using California s cellulosic biomass resources. Identify remaining regulatory, economic and institutional obstacles to bioalcohol project development and describe state and federal government roles in addressing these challenges.

Potential Biofuels and Bioenery Pathways Biomass Resource Transportation, Preparation and Handling Technology Platform Forest & Agricultural Residues Thermochemical Municipal Solid Waste Biochemical Energy Crops Direct Combustion Fuels/ Products Bio-Diesel Bio-Alcohols Chemicals Drugs Materials Electricity & Heat

Technologies Examined Thermochemical Processes Pyrolysis/Steam Reforming no air or oxygen Gasification with air or oxygen High Temperature Gasification >3500 F with air or oxygen Thermal Pyrolysis no oxygen or air Thermal Oxidation combustion at or near stochiometry Integrated Thermochemical Conversion/Oxidation) 13 Developers Examined

Thermochemical Technology B io m a s s C o n v e r s io n B io m a s s P r o c e s s in g E nergy C o n v e r s io n S te a m S te a m T u r b in e C o m b u stio n G r in d in g M ix in g S c r e e n in g T herm oc h e m ic a l Syngas Syngas F uel P r o d u c tio n B io a l c o h o l s T ra n sp o rt E n g in e / G e n e ra to r E nergy P ro d u ctio n E nergy U se H e a tin g, C o o lin g B u ild in g s, P rocesses E l e c t r i c i ty T o G r id H e a tin g, C o o lin g B u ild in g s, P rocesses E l e c t r i c i ty T o G r id F u el U se R e fin in g, B le n d in g & D istr ib u tio n 5E A ssessm en t 1. 2. 3. 4. 5. E v a l u a t io n (T e c h n ic a l ) E n ergy E n v ir o n m e n t E c o n o m ic s S o c i o - P o l i t ic a l E ffe c tiv e n e ss

Technologies Examined Biochemical Processes Acid Hydrolysis/Fermentation Enzymatic Hydrolysis/Fermentation Other Biological Processes 25 Developers Examined

Biochemical Technology Credit: Celunol Corp.

5E Assessment E1 Technology Evaluation E2 Energy Efficiency E3 Environmental Impacts E4 Economic Viability E5 Socio-political Effectiveness

Comparison of Thermochemical and Biochemical Systems A) Thermochemical Conversion Mixed Alcohols & Electricity B) Biochemical Conversion Ethanol & Electricity 500 2,205 Ethanol Fuel (gallons/dt) 80 59 N/A Electricity (kwh/dt) 550 205 1400 Total Net Energy Efficiency (E2) 50% 33% 28% see report see report see report 66 205 60 14.9 107.0 16.4 Electricity Production Cost ($/kwh) $0.071 N/A $0.071 Alcohol Production Cost ($/gallon) $1.12 $2.24 N/A Plant Size DT/day C) Thermochemical Conversion Electricity Only 500 Products (E1) Plant Emissions (E3) Economics (E4) Capital Cost, $M Operating Cost, $M/yr N/A: Not applicable; E1, E2 and E4 values are given with +15% uncertainty

Opportunities and Challenges U.S. Biomass Potential the Billon Ton Study CA Biomass Potential 33 million tons Technical Challenges Environmental and Regulatory Challenges Economic and Institutional Challenges Market-Related Challenges

Government Roles and Initiatives California Government Energy Commission s Public Interest Energy Program (PIER) Governor s Executive Order S-06-06 Bioenergy Action Plan Bioenergy Interagency Working Group AB 32 Global Warming Solutions Act Federal Government U.S. DOE Biomass Research and Development Initiative U.S. Dept. of Agriculture U.S. Defense Advanced Research Projects Agency

Federal Funding Efforts - 2007 11/5 - Ground Broken for First Commercial Cellulosic Biomass Plant in the U.S. 8/27 - DOE offers up to $33.8 Million to Support Cellulosic Biofuel Processes 10/1 - DOE Invests $30 Million to Launch Bioenergy Research Centers 9/26 - DOE and USDA Offer $18 Million for Biomass Research 5/1 - DOE Offers $200 Million for Small-Scale Cellulosic Biorefineries 6/26 - DOE Awards $375 Million for Three Bioenergy Research Centers

Conclusions and Recommendations Thermochemical technology with the highest probability of near-term commercial success is an integrated pyrolysis/steam reforming process possibly as low as $1.12/gallon production cost Biochemical technology hydrolysis and fermentation was estimated to be approximately $2.24/gallon production cost at present time Projected improvements could lower this cost to below $1.50/gallon

Conclusions and Recommendations (cont d) Ethanol and bioalcohols from cellulosic biomass has several promising technologies Still need for significant research, development, demonstration, and deployment Demonstration and commercial scale plants need to be built, validated, and improved Government still needed to implement regulations, provide increased RDD&D support and grant incentives to promote tech advancement However, government should not mandate the type(s) of technology they believe to be the future winners, but support all promising technologies

Questions/Comments? Frederick Tornatore Partner/Senior Vice President TSS Consultants 2724 Kilgore Road Rancho Cordova, CA 95670 916.638.8811 x104 Cell: 916.601.0531 fatoxic@tssconsultants.com www.tssconsultants.com