Anaerobic Treatment with BIOPAQ. Willie Driessen 11 November 2014

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Anaerobic Treatment with BIOPAQ Willie Driessen w.driessen@paques.nl 11 November 2014 11-12-2014

Presentation 1. Introduction Paques 2. Applications 3. BIOPAQ Anaerobic technologies 4. References 11-12-2014

Who is Paques? Privately owned company Founded in 1960 Number of employees : ~350 Business Units in Netherlands, China, Brazil, India, NA Worldwide presence through network of 20 partners Innovative biological applications for wastewater and gas 11-12-2014

Paques Services Process design Engineering Manufacturing Contracting Construction Research & Development Laboratory services Pilot testing Consultancy After Sales Service 11-12-2014

11-12-2014 Lab Testing

11-12-2014 Pilot testing

Revitalizing Resources Application of microorganisms from nature in our high rate reactors 7

Paques Technologies Know how area Application Products Carbon Sulphur Nitrogen & Phosphate Metals & Chemicals Separation ANAEROBIC & AEROBIC WASTE WATER TREATMENT (BIOGAS) DESULPHURISATION NITROGEN REMOVAL PHOSPHORUS RECOVERY METALS RECOVERY SULPHIDE PRODUCTION SULPHATE REDUCTION CHEMICALS RECOVERY BIOFILTRATION AND SOLIDS REMOVAL MEMBRANE FILTRATION BIOPAQ IC BIOPAQ UASB+ BIOPAQ AFR BIOPAQ UBOX CIRCOX THIOPAQ BIODESOX ANAMMOX PHOSPAQ ASTRASAND THIOTEQ SULFATEQ BIOMETEQ IONPAQ ASTRASAND ASTRASEPARATOR

BIOPAQ Anaerobic References more than 1,000 plants in more than 60 countries in the following sectors: Pulp and Paper Beer and Beverages Food Distilleries Chemical industry 11-12-2014

References But also other sectors: Municipalities (Sewage) Pharmaceutical industry Chemical industry (organic/inorganic) Metal and Mining Municipalities 10

Integrated Effluent Treatment Plant Conditioning tank IC Reactor Aeration Aeration basins Water storage tank Secondary clarifier 11-12-2014

Combined Anaerobic-Aerobic Treatment 11-12-2014

Recovery of Resources Pure Water for cleaning Biogas to Steam boiler or CHP PRE-TREATMENT (Screening, Equalisation, Neutralisation) 11-12-2014 ADVANCED PURIFICATION (Membranes) BIOLOGICAL TREATMENT (Anaerobic/Aerobic)

Completely Stirred Tank Reactors Gas Gas BVF / Lagoon Gas Anaerobic Filters CSTR / Contact Process Gas Overview of anaerobic reactor systems Gas Sludge Bed Reactors Gas UASB Hybrid Gas Expanded Sludge Bed Reactors Gas Gas 11-12-2014 Fluïdized bed Conventional EGSB IC

Typical design parameters anaerobic reactors Volumetric Loading Rate 1 (kg COD*/m³.d) Average Reactor Volume 2 (m³/ton COD) Hydraulic Retention Time (h) CSTR lagoon 0.1 1 1800 36 100 CSTR contact process 1 5 333 24 72 UASB 5 15 100 4 36 EGSB 10 23 60 2 24 IC 15-30 44 2-24 1 COD as biodegradable 2 for approximate comparison only 18

Various BIOPAQ reactors to fit specific customer needs BIOPAQ BIOPAQ BIOPAQ BIOPAQ UASB UASB+ IC AFR

20 Granular Biomass

21 Biomass controll Granular Biomass Seeding & Harvesting

Biomass in AFR 22 up to 25 kg TSS/m3

BIOPAQ UASB Upflow Sludge Bed 3-Pase Separator Modular system design Limited reactor height

BIOPAQ UASB+ Upflow Sludge Bed 3-Phase Separator Suitable for retrofitting Building into existing assets

BIOPAQ UASB/UASB+ Brewery Zink refinery Dairy 25 Papermill Beverage

BIOPAQ IC Upflow Sludge Bed 2 Stage 3-Phase Separator (superior biomass retention) Self regulated Internal Circulation (extra enhanced mixing biomass) Small footprint 26

BIOPAQ IC Food factory Paper mill Distillery Brewery Chemical 27

BIOPAQ - AFR Digestion of Oils & Fats & Proteins Completely mixed reactor type Integrated Flotation Compact Reactor Design Floculent Biomass 28

Applications BIOPAQ AFR Industrial examples: Dairy/Ice cream Vegetable oils Food industry Food liquid transport Slaughterhouse/Rendering Influent: COD : 7-70 g/l 29

BIOPAQ AFR 30

BIOPAQ UBOX combined anaerobic-aerobic treatment Upflow Sludge Bed Combined anaerobic-aerobic treatment No odour emission Sewage and Industrial 31

BIOPAQ UBOX combined anaerobic-aerobic treatment 20,000 pe 11,000 pe 32 50,000 pe Distillery

33 BIOPAQ SIZE to accommodate for 1,000 200,000 kg/d

Applications BIOPAQ AGRO FOOD INDUSTRY AGRO-FOOD INDUSTRY BEVERAGE ALCOHOL DISTILLERY Potato Confectionery Malting Sugar cane molasses Potato Citric Starch Acid Fruit Beer Soft drink Sugar cane Sugar beet Yeast Vegetable Fruit juice molasses Pectin Dairy BEVERAGE Wine DISTILLING INDUSTRY Sugar Cannery Soft Drink Sugar Cane Sugar Cannery Beer Juice Sugar cane juice Molasses Grape wine Starch Pectin Citric acid Bakery Malting Coffee Sugar Beet Grain Molasses Fruit PULP & PAPER PULP & PAPER Recycle Paper Recycle paper Mechanical pulp Mechanical NSSC Sulphite pulp Pulping Straw Semi-Chemical Bagasse NSSC MISCELLANEOUS MISCELLANEOUS Chemical Chemical Pharmaceutical Pharmaceutical Sludge liquor Municipal sewage Landfill leachate Sludge Liquor Acid mine water Vegetable Yeast Fruit Juice Wine Chemical Pulping Municipal Sewage Fruit Cheese Wine Grain Bagasse Acid mine water Confectionery Bakery Coffee Fruit Landfill leachate 34

Experience in the Industry Fit for Purpose 35