MATERIAL SAFETY DATA SHEET Kaolin Qualymin, S.A. de C.V.
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1 MATERIAL SAFETY DATA SHEET Kaolin Qualymin, S.A. de C.V. MANUFACTURER'S NAME Telephone: Qualymin, S.A. de C.V. Prolongacíon Ruiz Cortines Ote. No. 140 Fracc. Villa de San Antonio Emergency Tel: Cd. Guadalupe, N.L., México, C.P RESPONSIBLE PARTY: MSDS Coordinator ISSUED: SECTION 1 - SUBSTANCE INFORMATION Substance: Hydrous Kaolin Powder - Dry Chemical Family: Aluminum Silicate Molecular Formula: AL2O3 2SiO2 2H2O Product and Tradenames: The data contained herein applies to Qualymin S.A. de C.V. Kaolin products bearing the following names: ALBOLIN SF 325 CAOLIN Q ALBOLIN TH MICRO SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS Description: A natural mineral, white, odorless powder. Concentration: SiO %, Al2O %, CaO <6%, Na2O, K2O, TiO2, <.2%, Fe2O3 <1%, SO3<2%, MgO <0.05% CAS Number: SECTION 3 - HAZARDS IDENTIFICATION Specific Chemical Identity; Common Names OSHA PEL ACGIH TLV Kaolin - Total Dust 15 mg/m 3 2 mg/m 3 Kaolin - Respirable 5 mg/m 3 Kaolin is not listed on the NTP, IARC, or OSHA lists of carcinogens. Qualymin, S.A. de C.V. recommends using personal protection equipment when handling this product.
2 Hazardous Polymerization: Under certain conditions, kaolin may catalyze the chain polymerization of styrene monomer, producing an exothermic reaction that may generate large amounts of heat and cause combustion. Kaolin should NOT be added directly to styrene monomer. NOR should styrene monomer be directly added to kaolin. This reaction does not occur when kaolin is added to polyester resin containing free styrene. If the formulation requires additional styrene monomer to be added at the end of the mix cycle, kaolin MUST be fully dispersed in the polyester resin BEFORE the incorporation of the styrene monomer. Polymerization Avoid: Do not mix with styrene monomer. Hazardous Decomposition Products: None anticipated. Incompatibility (Material to Avoid): None anticipated. Stability Data: Stable Fire and Explosion Hazard Flash Point NA Flammable Limits NA Extinguishing Method NA Special Fire Fighting Procedures NA Unusual Fire and Explosion Hazards NA NCPA: National Paint and Coatings association Hazardous Material Identification System (HMIS). Health Hazard: 1* Flammability Hazard: 0 Physical Hazard: 0 Instability 0 Reactivity 0 Personal Protection: E glasses, gloves, dust respirator SECTION 4 FIRST AID MEASURES Inhalation: There are no reported health effects associated with repeated or prolonged exposure to kaolin. Chronic exposure to kaolin dust at concentrations exceeding occupational exposure limits may cause pneumoconiosis (lung disease). Acute Exposure: Exposure to a large concentration of air-born dust of this material may cause mechanical irritation of the mucous membranes and respiratory tract. Chronic Exposure: Repeated or prolonged inhalation of air-born dust of this material may cause scarring of the lungs (pulmonary fibrosis), with shortness of breath, chronic cough, and respiratory assisted heart failure.
3 First Aid: Remove from exposure area to fresh air. If breathing has stopped, perform artificial respiration and get medical attention immediately. Keep person warm and at rest. Treat symptomatically and supportively. Skin Contact: Acute Exposure: Direct contact may cause dryness, or may cause mild irritation if an allergic predisposition exists. Chronic Exposure: Prolonged contact may cause dryness of the skin, or may cause mild irritation if an allergic predisposition exists. First Aid: Flush with water. Apply common skin moisturizers to relieve dryness. If irritation or redness develops, seek medical attention. Eye Contact: Acute Exposure: Direct contact with dust may cause mechanical irritation of the eyes. Chronic Exposure: Prolonged exposure may cause conjunctivae inflammation. First Aid: Immediately flush the contaminated eye(s) with lukewarm, gently flowing water for 15 minutes holding the eyelid(s) open. If irritation persists, obtain medical advice immediately. Ingestion: Never give anything by mouth if victim is rapidly losing consciousness or is unconscious or convulsing. Rinse mouth thoroughly with water. Do not induce vomiting. If large quantities are ingested, obtain medical advice immediately. SECTION 5 PHYSICAL DATA Specific Gravity: 2 to 3 Solubility (in water): Insoluble ph: 6 to 8 SECTION 6 STORAGE, DISPOSAL & ENVIRONMENTAL Storage: Preserve in sealed containers to prevent dispersion of dust in air. Waste Disposal: Dry material can be landfiled. Observe all federal, state, and local regulations. Responsibility to proper waste disposals with the owner of the waste. Conditions to Avoid: Prevent dispersion of dust in air.
4 Accident Spills: For large spills, shovel or sweep up (while keeping dispersion of dust in air to a minimum) and place into suitable sealed containers for reclamation of later disposal. Residue should be cleaned up using high-efficiency particulate filter vacuum. The use of water wash-down is not recommended. Wet material can cause a surface for working to become slippery. Ventilation: Provide local exhausts or process enclosure ventilation to meet published exposure limits. Respirator: Dust filter mask is recommended as minimal protection The following maximum-use concentrations and respirators are recommendations by the U.S. Department of Health and Human Service. 10mg/m³...Any dust and mist respirator 20mg/m³...Any dust and mist respirator except single-use and quarter-mask respirators. Gloves: Protective gloves are not required, but may be worn to prevent skin dryness or irritation due to skin allergy. Eye Protection: Employees should wear dust-resistant safety goggles to prevent eye contact with high concentrations of air born dust of this substance. Where there is a possibility that an employee s eyes may be exposed to bulk quantities or high concentrations of air-born dust of this substance, the employer should provide an eye wash fountain within the immediate work area for emergency use. SECTION 7 ADDITIONAL INFORMATION This product is listed on the U.S. EPA TSCA inventory as a natural occurring substance. It is not hazardous to the environment. Not regulated as a hazardous material by the Department of Transportation. ODC s: This product does not contain, nor is it manufactured with, any U.S. EPA-defined Class I or Class II ozone-depleting chemicals. Prepared by: MSDS Coordinator Disclaimer: The information and recommendations contained herein are based upon tests and information believed to be reliable and correct. However, Qualymin S.A. de C.V. does not guarantee the accuracy or completeness NOR SHALL ANY OF THIS INFORMATION CONSTITUTE A WARRANTY, WHETHER EXPRESSED OR IMPLIED, AS TO THE SAFETY OF THE GOODS, THE MERCHANTABILITY OF THE GOODS, OR THE FITNESS OF THE GOODS FOR A PARTICULAR PURPOSE. Adjustment to conform to actual conditions of usage maybe required. Qualymin assumes no responsibility for results obtained or for incidental or consequential damages, including lost profits arising from the use of these data. No warranty against infringement of any patent, copyright or trademark is made or implied. Revision date: 05/2003 End of Safety Data Sheet
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