: A-810 POLYOL SOLUTION
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- Egbert Armstrong
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1 Date of issue: 01/05/2015 Revision date: 01/05/2015 : Version: 2.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Trade name : Mixture : A-810 POLYOL SOLUTION 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture 1.3. Details of the supplier of the safety data sheet SPI Pharma 1711 Tiles Court Grand Haven, MI USA T spipharma.com : Pharmaceutical ingredient Emergency telephone number Emergency number : Chemtrec (800) ; Chemtrec (Outside USA) (24 hours; 7 days/week) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Not classified 2.2. Label elements GHS-US labelling No labelling applicable 2.3. Other hazards 2.4. Unknown acute toxicity (GHS-US) No data available SECTION 3: Composition/information on ingredients 3.1. Substance Name : A-810 POLYOL SOLUTION Name Product identifier % GHS-US classification Glycerin (CAS No) Not classified Polyhydric alcohol (primarily sorbitol) (CAS No) Not classified Water (CAS No) Not classified SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Assure fresh air breathing. Allow the victim to rest. Get medical attention. : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. Wash clothing before re-using. Obtain medical attention if irritation persists. : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention Most important symptoms and effects, both acute and delayed Symptoms/injuries Symptoms/injuries after inhalation : Not expected to present a significant hazard under anticipated conditions of normal use. : Acute exposure may cause respiratory irritation. Chronic exposure to dust may result in delayed lung injury. 05/01/2015 EN (English) Page 1
2 Symptoms/injuries after skin contact Symptoms/injuries after eye contact Symptoms/injuries after ingestion : May cause irritation to the digestive tract Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. : Do not use a heavy water stream Special hazards arising from the substance or mixture Fire hazard : Product is an aqueous solution which will not burn. Explosion hazard : None known. Reactivity : Stable under normal conditions Advice for firefighters Firefighting instructions Protective equipment for firefighters : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : If spilled, may cause the floor to be slippery For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Ventilate area Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. : Dispose of contents/container to comply with applicable local, national and international regulations. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour Conditions for safe storage, including any incompatibilities Storage conditions Incompatible products Incompatible materials 7.3. Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters : Keep only in the original container in a cool well ventilated place. Keep container closed when not in use. : Strong bases. Strong acids. Strong oxidizing agents. : Sources of ignition. Direct sunlight. USA ACGIH ACGIH TWA (mg/m³) 10 mg/m³ USA OSHA OSHA PEL (TWA) (mg/m³) 15 mg/m³ 05/01/2015 EN (English) 2/6
3 8.2. Exposure controls Appropriate engineering controls Personal protective equipment : Provide adequate ventilation to minimize dust concentrations. : Avoid all unnecessary exposure. Protective goggles. Gloves. Protective clothing. Hand protection Eye protection Skin and body protection Respiratory protection : Wear protective gloves. : Chemical goggles or safety glasses. : Wear suitable protective clothing. : Appropriate dust or mist respirator should be used if airborne particles are generated when handling this material. NIOSH mask with filter for organic gases and vapors. : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Clear Colour : Clear Odour : None Odour threshold ph : 5-7 Relative evaporation rate (butyl acetate=1) Melting point Freezing point Boiling point Flash point Auto-ignition temperature : Unknown Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Solubility : Soluble Log Pow Log Kow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 9.2. SECTION 10: Stability and reactivity Reactivity Stable under normal conditions Chemical stability Stable under normal conditions Possibility of hazardous reactions Hazardous polymerization will not occur Conditions to avoid Direct sunlight. Extremely high or low temperatures. 05/01/2015 EN (English) 3/6
4 10.5. Incompatible materials This product may react with strong oxidizing agents Hazardous decomposition products Fume. Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity LC50 inhalation rat (mg/l) LD50 oral rat Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity > 570 mg/m³ mg/kg Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Potential Adverse human health effects and symptoms Symptoms/injuries after inhalation Symptoms/injuries after skin contact Symptoms/injuries after eye contact Symptoms/injuries after ingestion : None known. : Acute exposure may cause respiratory irritation. Chronic exposure to dust may result in delayed lung injury. : May cause irritation to the digestive tract. SECTION 12: Ecological information Toxicity Persistence and degradability Bioaccumulative potential Mobility in soil Other adverse effects Effect on ozone layer Effect on the global warming : : No known ecological damage caused by this product. Aquatic Toxicity : Test & Species Conditions 05/01/2015 EN (English) 4/6
5 96 Hr LC50 Oncorhynchus mykiss 50 mg/l 24 Hr EC50 Daphnia magna >500 mg/l : Avoid release to the environment. SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information In accordance with DOT Not regulated for transport Additional information : No supplementary information available. ADR Transport by sea Air transport SECTION 15: Regulatory information US Federal regulations Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on the United States TSCA (Toxic Substances Control Act) inventory International regulations CANADA Listed on the Canadian DSL (Domestic Sustances List) WHMIS Classification Listed on the Canadian DSL (Domestic Sustances List) WHMIS Classification Uncontrolled product according to WHMIS classification criteria Uncontrolled product according to WHMIS classification criteria EU-Regulations Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances) Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances) Classification according to Regulation (EC) No. 1272/2008 [CLP] Not classified Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] Not classified 05/01/2015 EN (English) 5/6
6 National regulations Listed on the AICS (Australian Inventory of Chemical Substances) Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China) Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory Listed on the Korean ECL (Existing Chemicals List) Listed on NZIoC (New Zealand Inventory of Chemicals) Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances) Listed on the AICS (Australian Inventory of Chemical Substances) Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China) Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory Listed on the Korean ECL (Existing Chemicals List) Listed on NZIoC (New Zealand Inventory of Chemicals) Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances) US State regulations SECTION 16: Abbreviations and acronyms Date of SDS preparation : 05/01/2015 : ATE - acute toxicity estimate. CAS - Chemical Abstracts Service. HCS - Hazard Communication Standard. HMIS - Hazardous Materials Identification System. GHS - Globally Harmonised System. OSHA - Occupational Safety and Health Administration. SDS -. : None. NFPA health hazard NFPA fire hazard NFPA reactivity : 1 - Exposure under fire conditions would offer no hazard beyond that of ordinary combustible materials. : 0 - Must be preheated before ignition can occur. : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. HMIS III Rating Health Flammability Physical Personal Protection : 1 Slight Hazard - No significant risk to health : 0 Minimal Hazard : 0 Minimal Hazard : Safety glasses with side shields SDS US (GHS HazCom 2012) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 05/01/2015 EN (English) 6/6
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