SAFETY DATA SHEET. Creation Date 01-May-2012 Revision Date 26-May-2017 Revision Number 2

Transcription

1 SAFETY DATA SHEET Creation Date 01-May-2012 Revision Number 2 Product Name Cat. : Synonyms Recommended Use Uses advised against 1. Identification Lauryl methacrylate, stabilized AC ; AC ; AC ; AC ; AC Methyl-2-propenoic acid dodecyl ester Laboratory chemicals. t for food, drug, pesticide or biocidal product use Details of the supplier of the safety data sheet Company Fisher Scientific One Reagent Lane Fair Lawn, NJ Tel: (201) Acros Organics One Reagent Lane Fair Lawn, NJ Emergency Telephone Number For information US call: ACROS-01 / Europe call: Emergency Number US: / Europe: CHEMTREC Tel..US: / Europe: Hazard(s) identification Classification This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR ) Skin Corrosion/irritation Category 2 Serious Eye Damage/Eye Irritation Category 2 Specific target organ toxicity (single exposure) Category 3 Target Organs - Respiratory system. Label Elements Signal Word Warning Hazard Statements Causes skin irritation Causes serious eye irritation May cause respiratory irritation Page 1 / 7

2 Precautionary Statements Prevention Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection Avoid breathing dust/fume/gas/mist/vapors/spray Use only outdoors or in a well-ventilated area Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Call a POISON CENTER or doctor/physician if you feel unwell Skin IF ON SKIN: Wash with plenty of soap and water If skin irritation occurs: Get medical advice/attention Take off contaminated clothing and wash before reuse Eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention Storage Store in a well-ventilated place. Keep container tightly closed Store locked up Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Very toxic to aquatic life with long lasting effects 3. Composition / information on ingredients Component CAS- Weight % Lauryl methacrylate >95 4. First-aid measures Eye Contact Skin Contact Inhalation Ingestion Most important symptoms/effects tes to Physician Suitable Extinguishing Media Unsuitable Extinguishing Media Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Obtain medical attention. Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Obtain medical attention. Remove from exposure, lie down. Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Obtain medical attention. Clean mouth with water. Get medical attention.. Treat symptomatically 5. Fire-fighting measures Water spray. Carbon dioxide (CO 2). Dry chemical. Chemical foam. Flash Point 126 C / 259 F Method - Autoignition Temperature 296 C / F Page 2 / 7

3 Explosion Limits Upper Lower Sensitivity to Mechanical Impact Sensitivity to Static Discharge Specific Hazards Arising from the Chemical Containers may explode when heated. Do not allow run-off from fire fighting to enter drains or water courses. Hazardous Combustion Products Carbon monoxide (CO) Carbon dioxide (CO2) Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. NFPA Health 2 Flammability 0 Instability 0 Physical hazards N/A Personal Precautions Environmental Precautions 6. Accidental release measures Ensure adequate ventilation. Use personal protective equipment. Do not flush into surface water or sanitary sewer system. Do not allow material to contaminate ground water system. Prevent product from entering drains. Local authorities should be advised if significant spillages cannot be contained. See Section 12 for additional ecological information. Avoid release to the environment. Collect spillage. Methods for Containment and Clean Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, Up sawdust). Keep in suitable, closed containers for disposal. Do not let this chemical enter the environment. Handling Storage Exposure Guidelines 7. Handling and storage Avoid contact with skin and eyes. Do not breathe vapors or spray mist. Do not ingest. Keep in a dry, cool and well-ventilated place. Keep container tightly closed. Keep at temperatures below 25 C. 8. Exposure controls / personal protection This product does not contain any hazardous materials with occupational exposure limitsestablished by the region specific regulatory bodies. Engineering Measures Ensure adequate ventilation, especially in confined areas. Ensure that eyewash stations and safety showers are close to the workstation location. Personal Protective Equipment Eye/face Protection Skin and body protection Respiratory Protection Hygiene Measures Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR or European Standard EN166. Wear appropriate protective gloves and clothing to prevent skin exposure. protective equipment is needed under normal use conditions. Handle in accordance with good industrial hygiene and safety practice. Page 3 / 7

4 9. Physical and chemical properties Physical State Liquid Appearance Light yellow Odor sweet Odor Threshold ph Melting Point/Range C / F Boiling Point/Range Flash Point 126 C / 259 F Evaporation Rate Flammability (solid,gas) Flammability or explosive limits Upper Lower Vapor Pressure Vapor Density Specific Gravity Solubility Partition coefficient; n-octanol/water Autoignition Temperature 296 C / F Decomposition Temperature Viscosity Molecular Formula C16 H30 O2 Molecular Weight Stability and reactivity Reactive Hazard Stability Conditions to Avoid Incompatible Materials ne known, based on information available Stable under normal conditions. Temperatures above 25 C. Incompatible products. Strong oxidizing agents, Strong acids, Strong bases, Peroxides Hazardous Decomposition Products Carbon monoxide (CO), Carbon dioxide (CO2) Hazardous Polymerization Hazardous Reactions Acute Toxicity Hazardous polymerization may occur. ne under normal processing. 11. Toxicological information Product Information Component Information Component LD50 Oral LD50 Dermal LC50 Inhalation Lauryl methacrylate > 5 g/kg t listed t listed Toxicologically Synergistic Products Delayed and immediate effects as well as chronic effects from short and long-term exposure Irritation Sensitization Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Component CAS- IARC NTP ACGIH OSHA Mexico Page 4 / 7

5 Lauryl methacrylate t listed t listed t listed t listed t listed Mutagenic Effects t mutagenic in AMES Test Reproductive Effects Developmental Effects Teratogenicity STOT - single exposure STOT - repeated exposure Aspiration hazard Symptoms / effects,both acute and delayed Endocrine Disruptor Information Other Adverse Effects... Respiratory system ne known See actual entry in RTECS for complete information. 12. Ecological information Ecotoxicity Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. The product contains following substances which are hazardous for the environment. Persistence and Degradability Bioaccumulation/ Accumulation Mobility Waste Disposal Methods Insoluble in water. Is not likely mobile in the environment due its low water solubility. 13. Disposal considerations Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. Chemical waste generators must also consult local, regional, and national hazardous waste regulations to ensure complete and accurate classification. 14. Transport information DOT t regulated TDG t regulated IATA UN Proper Shipping Name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. Hazard Class 9 Packing Group III IMDG/IMO UN Proper Shipping Name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. Hazard Class 9 Packing Group III International Inventories 15. Regulatory information Component TSCA DSL NDSL EINECS ELINCS NLP PICCS ENCS AICS IECSC KECL Lauryl methacrylate X X X X X X X Legend: X - Listed Page 5 / 7

6 E - Indicates a substance that is the subject of a Section 5(e) Consent order under TSCA. F - Indicates a substance that is the subject of a Section 5(f) Rule under TSCA. N - Indicates a polymeric substance containing no free-radical initiator in its inventory name but is considered to cover the designated polymer made with any free-radical initiator regardless of the amount used. P - Indicates a commenced PMN substance R - Indicates a substance that is the subject of a Section 6 risk management rule under TSCA. S - Indicates a substance that is identified in a proposed or final Significant New Use Rule T - Indicates a substance that is the subject of a Section 4 test rule under TSCA. XU - Indicates a substance exempt from reporting under the Inventory Update Rule, i.e. Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40 CFR 710(B). Y1 - Indicates an exempt polymer that has a number-average molecular weight of 1,000 or greater. Y2 - Indicates an exempt polymer that is a polyester and is made only from reactants included in a specified list of low concern reactants that comprises one of the eligibility criteria for the exemption rule. U.S. Federal Regulations TSCA 12(b) SARA 313 SARA 311/312 Hazard Categories Acute Health Hazard Chronic Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard Yes CWA (Clean Water Act) Clean Air Act OSHA Occupational Safety and Health Administration CERCLA California Proposition 65 U.S. State Right-to-Know Regulations This product does not contain any Proposition 65 chemicals U.S. Department of Transportation Reportable Quantity (RQ): DOT Marine Pollutant DOT Severe Marine Pollutant N N N U.S. Department of Homeland Security This product does not contain any DHS chemicals. Other International Regulations Mexico - Grade Prepared By Creation Date Revision Date 16. Other information Regulatory Affairs Thermo Fisher Scientific EMSDS.RA@thermofisher.com 01-May May-2017 Page 6 / 7

7 Print Date Revision Summary 26-May-2017 This document has been updated to comply with the US OSHA HazCom 2012 Standard replacing the current legislation under 29 CFR to align with the Globally Harmonized System of Classification and Labeling of Chemicals (GHS). Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of SDS Page 7 / 7