Rovral WG. UN 3077 Packing Group III Environmentally hazardous substance, solid, N.O.S. (contains iprodione 75%)

Transcription

1 Rovral WG MAPP A water dispersible granule containing 750 g/kg iprodione A protectant fungicide for use on a range of horticultural and agricultural crops. The (COSHH) Control of Substances Hazardous to Health Regulations may apply to the use of this product at work. 1 kg SAFETY PRECAUTIONS Operator protection Engineering control of operator exposure must be used where reasonably practicable in addition to the following personal protective equipment: WEAR SUITABLE PROTECTIVE GLOVES AND FACE PROTECTION (FACESHIELD) when handling the product. However, engineering controls may replace personal protective equipment if a COSHH assessment shows that they provide an equal or higher standard of protection. IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY with plenty of water and seek medical advice. IF YOU FEEL UNWELL, seek medical advice immediately (show the label where possible). WHEN USING DO NOT EAT, DRINK OR SMOKE. WASH HANDS before meals and after work. Environmental protection Do not contaminate water with the product or its container. Do not clean application equipment near surface water / Avoid contamination via drains. This product qualifies for inclusion within the Local Environment Risk Assessment for Pesticides (LERAP) scheme. Before each spraying operation from a horizontal boom sprayer, or broadcast air-assisted sprayer, either a LERAP must be carried out in accordance with PSD s published guidance or the statutory buffer zone must be maintained. The results of the LERAP must be recorded and kept available for inspection for three years. DO NOT ALLOW DIRECT SPRAY from horizontal boom sprayers to fall within 5 m of the top of the bank of a static or flowing waterbody, unless a Local Environment Risk Assessment for Pesticides (LERAP) permits a narrower buffer zone, or within 1 m of the top of a ditch which is dry at the time of application. Aim spray away from water. DO NOT ALLOW DIRECT SPRAY from broadcast air-assisted sprayers for use on raspberry to fall within 15m of the top of the bank of a static or flowing waterbody, unless a Local Environmental Risk Assessment for Pesticides (LERAP) permits a narrower buffer zone, or within 5m of the top of a ditch which is dry at the time of application. Aim spray away from water. Storage and disposal KEEP AWAY FROM FOOD, DRINK AND ANIMAL FEEDING STUFFS. KEEP OUT OF REACH OF CHILDREN. KEEP IN ORIGINAL CONTAINER, tightly closed, in a safe place. EMPTY CONTAINER THOROUGHLY and dispose of safely. DO NOT RE-USE CONTAINER for any purpose. UN 3077 Packing Group III Environmentally hazardous substance, solid, N.O.S. (contains iprodione 75%) Supplied by: BASF plc Crop Protection PO Box 4, Earl Road Cheadle Hulme, CHEADLE Cheshire SK8 6QG Tel: Emergency Information: (24 hours freephone): Technical Enquiries: (office hours) This label is compliant with the CPA Voluntary Initiative Guidance = Registered trademark of BASF GB0018 ~xmam indd :17:34

2 HARMFUL DANGEROUS FOR THE ENVIRONMENT Rovral WG A water dispersible granule containing 750 g/kg iprodione IRRITATING TO EYES LIMITED EVIDENCE OF A CARCINOGENIC EFFECT VERY TOXIC TO AQUATIC ORGANISMS, MAY CAUSE LONG TERM ADVERSE EFFECTS IN THE AQUATIC ENVIRONMENT WEAR SUITABLE PROTECTIVE CLOTHING AND GLOVES KEEP OUT OF THE REACH OF CHILDREN IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF WATER AND SEEK MEDICAL ADVICE IF SWALLOWED, SEEK MEDICAL ADVICE IMMEDIATELY AND SHOW THIS CONTAINER OR LABEL DO NOT BREATHE SPRAY USE ONLY IN WELL VENTILATED AREAS THIS MATERIAL AND ITS CONTAINER MUST BE DISPOSED OF IN A SAFE WAY USE APPROPRIATE CONTAINMENT TO AVOID ENVIRONMENTAL CONTAMINATION To avoid risks to man and the environment, comply with the instructions for use This product is approved under the Plant Protection Products Regulations IMPORTANT INFORMATION FOR USE ONLY AS AN AGRICULTURAL/HORTICULTURAL FUNGICIDE, as directed below: CROPS MAXIMUM INDIVIDUAL MAXIMUM NUMBER OF LATEST TIME OF DOSE TREATMENTS PER CROP APPLICATION Winter and spring oilseed rape 0.67 kg/ha 1 7 weeks before harvest Brussels sprout and cauliflower 0.67 kg/ha 3 14 days before harvest Bulb onions 0.67 kg/ha 4 21 days before harvest Salad onions 0.67 kg/ha 4 7 days before harvest Tomato (protected) 67g per 100 litres water 5 2 days before harvest Lettuce (protected) 33g per 100 litres water* 3 14 days before harvest Lettuce (outdoor) 33g per 100 litres water* 3 21 days before harvest Strawberry (outdoor and protected) 1 kg/ha 4 2 days before harvest Raspberry (outdoor) 1 kg/ha 4 7 days before harvest Brassica seed production crops** 0.67 kg/ha 3 14 days before harvest Ornamental pot plants 67 g per 100 litres water 5 Not applicable Other specific restriction: Cherry tomatoes must not be treated * Lettuce (outdoor and protected): Do not exceed a volume of 1000 litres per hectare. ** Crops intended for sowing: cabbage, cauliflower, broccoli, mustard, fodder rape, turnip, swede, kohl rabi, stubble turnip and Chinese cabbage. Treated crop must not be used for human or animal consumption. Use on raspberry must only be applied via broadcast air-assisted sprayers with the relevant buffer zone as detailed in the Environmental protection section. The following minimum intervals between applications must be observed: Strawberry 10 days Raspberry 10 days Tomato (protected) 14 days Brassica seed production crops 21 days Lettuce 14 days READ THE LABEL BEFORE USE. USING THIS PRODUCT IN A MANNER THAT IS INCONSISTENT WITH THE LABEL MAY BE AN OFFENCE. FOLLOW THE CODE OF PRACTICE FOR USING PLANT PROTECTION PRODUCTS. ~xmam indd :17:34

3 DIRECTIONS FOR USE IMPORTANT: This information is approved as part of the Product Label. All instructions within this section must be read carefully in order to obtain safe and successful use of this product. Rovral WG is a protectant fungicide for use on a range of horticultural and agricultural crops. 1. Restrictions/Warnings Consult processors before using on crops intended for processing. Avoid spray drift onto neighbouring crops, especially oats. 2. Disease Control Rovral WG is protectant and contact fungicide for the control of Botrytis cinerea in protected tomatoes, lettuce and strawberries, ornamental pot plants, raspberries, oilseed rape, salad and bulb onions (including B. squamosa), and control of Alternaria brassicae and Alternaria brassicicola, in brassica seed production crops, oilseed rape, Brussels sprout and cauliflower. 2.1 Resistance Strains of several diseases including Botrytis cinerea resistant to dicarboximide fungicides are known in various crops in the UK. Where strains of fungi resistant to dicarboximide fungicides (such as iprodione) occur, Rovral WG may not be effective. In order to minimise the risk of resistance development, Rovral WG should be used in accordance with FRAC resistance management advice for dicarboximide fungicides: Recommendations for use of Dicarboximides Rovral WG contains a dicarboximide fungicide To reduce the risk of resistant strains adversely affecting control - Avoid the use of consecutive applications of dicarboximide fungicides whether applied alone or in tank mix. - Restrict applications to those times when Botrytis infection pressure is high. - Maintain regular prolonged times when dicarboximides are not used. Where resistance is suspected, use Rovral WG in mixture with other fungicides with a different mode of action effective against the same diseases. ~xmam indd :17:35

4 3. Crop specific information 3.1 Tomatoes (Protected) Time and rate of Application For the control of Botrytis cinerea, apply Rovral WG at a rate of 67 g per 100 litres of water and apply to run off. Apply Rovral WG from when the second truss is in flower; repeat at 14 day intervals or when conditions favour the spread of Botrytis (such as at trimming or de leafing). The programme described above helps to reduce the levels of inoculum within the house and hence assists in preventing ghost spotting. A maximum of 5 applications may be made. A minimum spray interval of 14 days must be observed. 3.2 Lettuce (Protected and Outdoor) Botrytis cinerea Time and rate of Application For the control of Botrytis cinerea, apply Rovral WG at a rate of 33 g per 100 litres of water. Do not exceed a volume of 1000 litres per hectare (equivalent to a maximum of 0.33 Kg/ha). As a guide for protected lettuce, newly planted lettuce with three leaves require 5 litres of spray to 22,000 plants. At a later stage of growth, e.g. up to six to eight leaves, 5 litres should treat about 5000 plants. The final spray, before cutting, will require 5 litres of spray to approximately 1100 plants.for outdoor and protected lettuce a maximum of 3 applications may be made. A minimum spray interval of 14 days must be observed between treatments. 3.3 Ornamental Pot Plants Time and rate of Application For the control of Botrytis cinerea, apply Rovral WG at a rate of 67 g per 100 litres of water. Apply at the onset of disease, then repeat at 21 day intervals as necessary. Apply to the point of run off, ensuring good coverage of the plants. Good tolerance to Rovral WG has been shown by the following pot plant species: ~xmam indd :17:35

5 Aralia sieboldii Azalea spp. Begonia rex (cv Fireglow) Chrysanthemum (all year round cultivars) Cineraria (Senecio sp.) Croton (Codiaeum sp. cv Bravo) Cyclamen spp. Dracaena sp. (cv Redege) Ficus robusta Fuchsia spp. Hedera minor Hedera major Impatiens parviflora Kalanchoe spp. Neanthe bella Pelargonium sp. Philodendron scandens Pilea cadierei (cv Nana) Poinsettia (Euphorbia pulcharrima) Senecio macroglossus variegatus Sinningia spp. (Gloxinia) Tolerance of other species should be checked before making large scale applications. 3.4 Strawberries (Protected and Outdoor) Time and rate of Application For the control of Botrytis cinerea, apply 1.0 kg of Rovral WG in 2000 litres of water per hectare. Lower volume rates may not be sufficient to give good coverage on dense crops. Ensure thorough blossom coverage from above and from the sides. Directed nozzles and a ruffler bar will help achieve this. The first application should be made at the white bud stage with subsequent treatments at day intervals during the flowering period, up to a maximum of four applications per year. ~xmam indd :17:35

6 3.5 Raspberries Time and rate of Application For the control of Botrytis cinerea, apply 1.0 kg of Rovral WG in 1000 litres of water per hectare. A minimum of three sprays over the flowering period is recommended, starting at early flowering and repeating at 14 day intervals. A maximum of 4 sprays may be made per year. A minimum spray interval of 10 days must be observed between treatments. 3.6 Brassica Seed Production Crops (crops intended for sowing): cabbage, cauliflower, broccoli, mustard, fodder rape, turnip, swede, kohl rabi, stubble turnip and Chinese cabbage (not oilseed rape) Time and rate of Application For the control of Alternaria brassicae and A.brassicicola, spray at the end of flowering at a rate of 0.67 kg Rovral WG in 600 to 1000 litres of water per hectare. A total of 3 applications may be made. A minimum spray interval of 21 days must be observed between treatments. Treated crop must not be used for human or animal consumption 3.7 Winter and spring oilseed rape. Time and rate of Application Apply Rovral WG at a rate of 0.67 kg per hectare. A maximum of 1 spray may be made to each crop. Rovral WG should be applied in litres per hectare of water as a fine spray (BCPC category), except where drift is a hazard when a medium spray should be used. Use the higher volume if the crop is very dense. Dark leaf spot and pod spot: Alternaria spp Protectant applications Apply 0.67 kg per hectare Rovral WG between mid flower, i.e. when 20 pods that are 2.5 cm in length have formed on the main raceme, and the end of flowering. ~xmam indd :17:35

7 Disease onset applications Treat with 0.67 kg per hectare Rovral WG when black pin head spots first appear on the pods. Pod infections are most likely to occur on those crops where Alternaria spp spots can be detected on the uppermost leaves (bracts). Grey mould: Botrytis cinerea When applying a protectant spray of Rovral WG at 0.67 kg per hectare at mid flower for the control of Alternaria spp., application will also control grey mould. Application at the end of flowering will be unsatisfactory. 3.8 Brussel sprouts and cauliflower Time and rate of Application For the control of Alternaria brassicae and A. brassicicola, apply Rovral WG at 0.67 kg per hectare. A maximum of 3 applications of Rovral WG may be made. A programme of applications may be required. The first treatment should be applied at the onset of disease on the foliage. Apply in at least litres per hectare of water ensuring good coverage of the plants. A minimum spray interval of 21 days must be observed between treatments. 3.9 Salad and bulb onions Time and rate of Application For the control of leaf spot (Botrytis squamosa) and collar rot (Botrytis cinerea) apply Rovral WG at a rate of 0.67 kg per hectare. A programme of applications is required. Apply in litres per hectare of water ensuring good coverage of the foliage. Salad Onions Over wintered: Treat at monthly intervals starting at the crook stage. A maximum of 4 applications may be made. Spring and summer sown: Treat at 14 day intervals starting at the crook stage. A maximum of 4 applications may be made. ~xmam indd :17:35

8 Bulb Onions Over wintered: Treat at monthly intervals from the crook stage until January. Further treatments at monthly intervals starting in March may be necessary to control late season infections. A maximum of 4 applications may be made. 4. Mixing and Spraying Apply as a FINE-MEDIUM spray, as defined by BCPC. Half fill the tank with clean water and start the agitation. Add the required amount of Rovral WG to the spray tank while re-circulating. Add the remainder of the water and continue agitation until spraying is complete. When tank mixes are to be used, each product should be added separately. On emptying the container, rinse container thoroughly by using an integrated pressure rinsing device or manually rinsing three times. Add washings to sprayer at time of filling and dispose of container safely. 5. Trademark Acknowledgements Rovral WG is a trademark of BASF. ~xmam indd :17:35

9 The following does not form part of the product label under the Plant Protection Products Regulations 2005 With many products there is a general risk of resistance developing to the active ingredients. For this reason a change in activity cannot be ruled out. It is generally impossible to predict with certainty how resistance may develop because there are so many crop and use connected ways of influencing this. We therefore have to exclude liability for damage or loss attributable to any such resistance that may develop. To help minimise any loss in activity the BASF recommended rate should in all events be adhered to. Numerous, particularly regional or regionally attributable, factors can influence the activity of the product. Examples include weather and soil conditions, crop plant varieties, crop rotation, treatment times, application amounts, admixture with other products, appearance of organisms resistant to active ingredients and spraying techniques. Under particular conditions a change in activity or damage to plants cannot be ruled out. The manufacturer or supplier is therefore unable to accept any liability in such circumstances. All goods supplied by us are of high grade and we believe them to be suitable, but as we cannot exercise control over their mixing or use or the weather conditions during and after application, which may affect the performance of the material, all conditions and warranties, statutory or otherwise, as to the quality or fitness for any purpose of our goods are excluded and no responsibility will be accepted by us for any damage or injury whatsoever arising from their storage, handling, application or use; but nothing should be deemed to exclude or restrict any liability upon us which cannot be excluded or restricted under the provisions of the Unfair Contract Terms Act 1977 or any similar applicable law. ~xmam indd :17:35

10 Section 6 of the Health and Safety at Work Act Additional Product Safety Information The product label provides information on a specific pesticidal use of the product; do not use otherwise, unless you have assessed any potential hazard involved, the safety measures required and that the particular use has off-label approval or is otherwise permitted under the of Plant Protection Products Regulations. The information on this label is based on the best available information including data from test results. 1. SUBSTANCE/PREPARATION AND COMPANY NAME Product Name: ROVRAL WG MAPP Number: Use: Company: Agricultural/Horticultural Fungicide BASF plc PO Box 4, Earl Road Cheadle Hulme Cheadle Cheshire SK8 6QG Tel: Fax: Emergency Information: (24 Hours freephone) 2. COMPOSITION/INFORMATION ON INGREDIENTS Formulation: A water dispersible granule containing 750 g/kg iprodione Hazardous ingredients EC No. % w/w Symbol R Phrases Iprodione Xn, N R40, R50/53 sodium Xn R22, R36/37, diisopropylnaphthalene R20 sulphonate sodium alkylnaphthalene Xi R36/38 sulphonate, formaldehyde condensate ~xmam indd :17:35

11 3. HAZARDS IDENTIFICATION HARMFUL DANGEROUS FOR THE ENVIRONMENT IRRITATING TO EYES (R36) LIMITED EVIDENCE OF A CARCINOGENIC EFFECT (R40) VERY TOXIC TO AQUATIC ORGANISMS, MAY CAUSE LONG TERM ADVERSE EFFECTS IN THE AQUATIC ENVIRONMENT (R50/53) 4. FIRST AID MEASURES General advice: If a person thinks that they have been exposed to this product and feels unwell, call a doctor or take them to a hospital. Remove all contaminated clothing. Keep them at REST away from source of contamination. DO NOT ALLOW smoking or eating. First aider should avoid becoming contaminated and wear protective clothing if necessary. Eye contact: Immediately irrigate affected eyes for at least 15 minutes under flowing water, with eyelids open. Skin contact: Immediately remove contaminated clothing and footwear and flush skin with plenty of water. Wash affected area thoroughly with soap and water as soon as possible. Ingestion: DO NOT INDUCE VOMITING. Wash out mouth with clean water. Seek medical attention immediately. Inhalation: Keep person calm, remove to fresh air. Unconsciousness: If danger of loss of consciousness, place person in recovery position. Apply artificial ventilation if necessary, but care must be taken to avoid contamination of the first aider. ~xmam indd :17:35

12 GUIDE TO PHYSICIAN general advice Active ingredient group: Iprodione - dicarboximide Symptoms of accidental There is no documentation of overexposure: pathological effects in humans. Any unusual symptoms which occur after exposure (by any mode of entry) should be recorded and reported to BASF at Cheadle. (i) Treatment should be symptomatic and supportive based on judgement of physician. (ii) If the product has been swallowed, gastric lavage with proper laryngeal control may be necessary. For ingestion of small quantities activated charcoal as an absorbent in a dosage of 30 grams in 100 ml of water may be considered. (iii) Maintenance of ventilation and oxygen therapy to be used as required. (iv) If symptomatic therapy is indicated for control of restlessness, anxiety or convulsions, then Diazepam is recommended as the drug of choice. 5. FIRE FIGHTING MEASURES Suitable extinguishing media: Water spray, foam, water fog, dry chemical, or carbon dioxide. Possible harmful fumes in a fire: Carbon monoxide, hydrogen chloride, carbon dioxide, nitrogen oxides, organochloric compounds can be released. Avoid breathing smoke and fumes. Protective equipment: Use self-contained breathing apparatus and protective clothing. Further information: Call the Fire Brigade at once to deal with all fires involving pesticides unless the fire is small and immediately controllable. Spray unopened containers with a mist spray to keep cool. If without risk, remove intact containers from exposure to fire. Contain fire-fighting water, bunding if ~xmam indd :17:35

13 necessary with sand or earth. Do not allow contamination of public drains or surface or ground waters. Dispose of fire debris and contaminated water as advised in the DEFRA publication Code of practice for using plant protection products. 6. ACCIDENTAL RELEASE MEASURES If spilled: Wear prescribed protective clothing. Clear spillage immediately. Contain spillage, sweep up and collect contaminated material and place in a marked container for disposal. Thoroughly wash area of spillage. Dispose of contaminated materials as advised in the DEFRA publication Code of practice for using plant protection products. Wash thoroughly immediately after handling spillages, or at once if contaminated. Personal protective equipment: See Section 8. Environmental precautions: Do not allow contamination of public drains or surface or ground waters. Inform local water plc if spillage enters drains and the Environment Agency (England & Wales), the Scottish Environmental Protection Agency (Scotland), or the Environment and Heritage Service (Northern Ireland) if it enters surface or ground waters. Keep people and animals away. 7. HANDLING AND STORAGE Handling: No special measures are necessary. Avoid contact with skin and eyes. When using do not eat, drink or smoke. Protection against fire and explosion: Dust can form an explosive mixture with air. Avoid dust formation. Avoid deposition of dust. Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should be kept handy ~xmam indd :17:35

14 Storage: Keep dry and frostproof in a suitable pesticide store. Store separately from food, drink and animal feed. Protect from temperatures above: 40 C 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION (i) PRECAUTIONS (from product label) Operator protection Engineering control of operator exposure must be used where reasonably practicable in addition to the following personal protective equipment: WEAR SUITABLE PROTECTIVE GLOVES AND FACE PROTECTION (FACESHIELD) when handling the product. However, engineering controls may replace personal protective equipment if a COSHH assessment shows that they provide an equal or higher standard of protection. IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY with plenty of water and seek medical advice. IF YOU FEEL UNWELL, seek medical advice immediately (show the label where possible). WHEN USING DO NOT EAT, DRINK OR SMOKE. WASH HANDS before meals and after work. Environmental protection Do not contaminate water with the product or its container. Do not clean application equipment near surface water / Avoid contamination via drains. This product qualifies for inclusion within the Local Environment Risk Assessment for Pesticides (LERAP) scheme. Before each spraying operation from a horizontal boom sprayer, or broadcast airassisted sprayer, either a LERAP must be carried out in accordance with PSD s published guidance or the statutory buffer zone must be maintained. The results of the LERAP must be recorded and kept available for inspection for three years ~xmam indd :17:35

15 DO NOT ALLOW DIRECT SPRAY from horizontal boom sprayers to fall within 5 m of the top of the bank of a static or flowing waterbody, unless a Local Environment Risk Assessment for Pesticides (LERAP) permits a narrower buffer zone, or within 1m of the top of a ditch which is dry at the time of application. Aim spray away from water. DO NOT ALLOW DIRECT SPRAY from broadcast airassisted sprayers for use on raspberry to fall within 15m of the top of the bank of a static or flowing waterbody, unless a Local Environmental Risk Assessment for Pesticides (LERAP) permits a narrower buffer zone, or within 5m of the top of a ditch which is dry at the time of application. Aim spray away from water. Storage and disposal KEEP AWAY FROM FOOD, DRINK AND ANIMAL FEEDINGS STUFFS. KEEP OUT OF REACH OF CHILDREN. KEEP IN ORIGINAL CONTAINER, tightly closed, in a safe place. EMPTY CONTAINER THOROUGHLY and dispose of safely. DO NOT RE-USE CONTAINER for any purpose. (ii) PERSONAL PROTECTIVE EQUIPMENT In tests with a range of pesticide products, protective gloves made of nitrile rubber at least 0.5 mm thick and 300 mm long have been found to be the most suitable. Gloves made of viton, butyl rubber, neoprene and PVC can also offer good protection. Gloves must protect the whole hand and wrist and should be thoroughly washed after each operation. Face shields should conform to BS EN 166. The wearing of other personal protective equipment may be required to supplement the items listed above. These are described in the DEFRA publication Code of practice for using plant protection products. Decontaminate all personal protective equipment after use. When this is not possible dispose of as hazardous waste. ~xmam indd :17:36

16 (iii) OCCUPATIONAL EXPOSURE LIMITS (OESs) Hazardous ingredients Long term Short term exposure limit exposure limit Not applicable 9. PHYSICAL AND CHEMICAL PROPERTIES Form: Water dispersible granule Colour: Beige Odour: Odourless Flash point: Not applicable Flammability: Not highly flammable Self-ignition temperature Not self-igniting Minimum ignition energy mj Bulk density: 640 kg/m 3 Solubility in water: Dispersible ph: 9.8 (10 g/l, 24 C) 10. STABILITY AND REACTIVITY Hazardous reactions: None provided product is correctly handled. Substances to avoid: None known Hazardous decomposition products: None if stored and handled correctly. 11. TOXICOLOGICAL INFORMATION Acute toxicity: Ingestion: LD50 oral (rat): > 2000 mg/kg Skin contact: LD50 dermal (rat): > 2000 mg/kg Inhalation: LD50 inhalation (rat) 4 hr: > 5.16 mg/l Eye contact: Irritating to eyes Sensitising potential: No sensitising effect ~xmam indd :17:36

17 12. ECOLOGICAL INFORMATION Ecotoxic effects: Rainbow trout (Oncorhynchus mykiss) LC50 96 h: Daphnia EC/LC50 (48 h): Algae EC/LC50 (0-72 h): 35 mg/l 0.4 mg/l 9.1 mg/l 13. DISPOSAL CONSIDERATIONS Leaking containers: Damaged or leaking containers must be dealt with as soon as noticed by sealing them in impermeable containers. Disposal of used containers: Follow the directions given in the DEFRA publication Code of practice for using plant protection products. Disposal of diluted pesticide: Advice for the disposal or re-use of diluted pesticide is given in the DEFRA publication Code of practice for using plant protection products. 14. TRANSPORT INFORMATION UN Number : 3077 Packing Group : III ROAD/RAIL ADR/RID Class : 9 Description of goods : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (contains IPRODIONE 75%) SEA 9 IMDG Class : Description of goods : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (contains IPRODIONE 75%) ~xmam indd :17:36

18 AIR 9 ICAO/IATA Class : Description of goods : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (contains IPRODIONE 75%) Pack sizes : 1 kg No. per outer : 10 This product is subject to The Carriage of Dangerous Goods and Use of Transportable Pressure Equipment Regulations 2004 and their amendments. 15. REGULATORY INFORMATION This product is approved under the Plant Protection Products Regulations This product has been classified in accordance with The Chemicals (Hazard Information and Packaging for Supply) (Amendment) Regulations 2005 (CHIP 3.1). This product may be subject to the Control of Major Accident Hazards Regulations (COMAH) if certain threshold quantities are exceeded. Hazard classification(s) See Section 3 R-phrase(s) See Section 3 S-phrase(s) S2 Keep out of the reach of children S23 Do not breathe spray S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice S36/37 Wear suitable protective clothing and gloves S46 If swallowed, seek medical advice immediately and show this container or label S51 Use only in well ventilated areas S57 Use appropriate containment to avoid environmental contamination S35 This material and its container must be disposed of in a safe way ~xmam indd :17:36

19 The Control of Substances Hazardous to Health Regulations (COSHH) may apply to the use of this product at work. 16. OTHER INFORMATION For further medical advice Doctors should contact the National Poisons Information Service. In an emergency further information can be obtained from the National Chemical Emergency Centre (24 hours). Xn Harmful Xi Irritant N Dangerous for the environment R40 Limited evidence of carcinogenic effect R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R22 Harmful if swallowed. R36/37 Irritating to eyes and respiratory system. R20 Harmful by inhalation. R36/38 Irritating to eyes and skin. The information contained herein is based on the present state of our knowledge and does not therefore guarantee certain properties. Recipients of our product must take responsibility for observing existing laws and regulations. ~xmam indd :17:36

20 Rovral WG MAPP A water dispersible granule containing 750 g/kg iprodione A protectant fungicide for use on a range of horticultural and agricultural crops. The (COSHH) Control of Substances Hazardous to Health Regulations may apply to the use of this product at work. 1 kg SAFETY PRECAUTIONS Operator protection Engineering control of operator exposure must be used where reasonably practicable in addition to the following personal protective equipment: WEAR SUITABLE PROTECTIVE GLOVES AND FACE PROTECTION (FACESHIELD) when handling the product. However, engineering controls may replace personal protective equipment if a COSHH assessment shows that they provide an equal or higher standard of protection. IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY with plenty of water and seek medical advice. IF YOU FEEL UNWELL, seek medical advice immediately (show the label where possible). WHEN USING DO NOT EAT, DRINK OR SMOKE. WASH HANDS before meals and after work. Environmental protection Do not contaminate water with the product or its container. Do not clean application equipment near surface water / Avoid contamination via drains. This product qualifies for inclusion within the Local Environment Risk Assessment for Pesticides (LERAP) scheme. Before each spraying operation from a horizontal boom sprayer, or broadcast air-assisted sprayer, either a LERAP must be carried out in accordance with PSD s published guidance or the statutory buffer zone must be maintained. The results of the LERAP must be recorded and kept available for inspection for three years. DO NOT ALLOW DIRECT SPRAY from horizontal boom sprayers to fall within 5 m of the top of the bank of a static or flowing waterbody, unless a Local Environment Risk Assessment for Pesticides (LERAP) permits a narrower buffer zone, or within 1 m of the top of a ditch which is dry at the time of application. Aim spray away from water. DO NOT ALLOW DIRECT SPRAY from broadcast air-assisted sprayers for use on raspberry to fall within 15m of the top of the bank of a static or flowing waterbody, unless a Local Environmental Risk Assessment for Pesticides (LERAP) permits a narrower buffer zone, or within 5m of the top of a ditch which is dry at the time of application. Aim spray away from water. Storage and disposal KEEP AWAY FROM FOOD, DRINK AND ANIMAL FEEDING STUFFS. KEEP OUT OF REACH OF CHILDREN. KEEP IN ORIGINAL CONTAINER, tightly closed, in a safe place. EMPTY CONTAINER THOROUGHLY and dispose of safely. DO NOT RE-USE CONTAINER for any purpose. UN 3077 Packing Group III Environmentally hazardous substance, solid, N.O.S. (contains iprodione 75%) Supplied by: BASF plc Crop Protection PO Box 4, Earl Road Cheadle Hulme, CHEADLE Cheshire SK8 6QG Tel: Emergency Information: (24 hours freephone): Technical Enquiries: (office hours) This label is compliant with the CPA Voluntary Initiative Guidance = Registered trademark of BASF GB0018 ~xmam indd :17:36