802 HEAVY DUTY SOLVENT DEGREASER & BRAKE CLEANER
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1 Page 1 / 11 SAFETY DATA SHEET 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product Identifier Product Name Other means of identification UN-No 1950 Synonyms No information available Recommended use of the chemical and restrictions on use Identified uses Uses advised against Equipment cleaning and maintenance Consumer use Details of the supplier of the safety data sheet Manufacturer Lubrication Engineers Inc E. Tulsa Wichita, KS USA Emergency Telephone Number CHEMTREC: (NORTH AMERICA) (INTERNATIONAL)
2 Page 2 / HAZARDS IDENTIFICATION Classification OSHA Regulatory Status Serious eye damage/eye irritation Category 2 Specific target organ toxicity (single exposure) Category 3 Flammable Aerosols Category 1 Gases Under Pressure Compressed Gas Label Elements Emergency Overview Signal Word DANGER Hazard Statements Causes serious eye irritation May cause respiratory irritation. May cause drowsiness or dizziness Extremely flammable aerosol Contains gas under pressure; may explode if heated appearance clear Physical state Aerosol Odor Hydrocarbon-like Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling. Avoid breathing dust/fume/gas/mist/vapors/spray. Use only outdoorsorinawel-ventilatedarea.keepawayfrom heat/sparks/openflames/hotsurfaces. Nosmoking.Donotsprayonan open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Wear protective gloves/protective clothing/eye protection/face protection. Keep cool. Response Call a POISON CENTER or doctor/physician if you feel unwell. Eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin None. Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. Ingestion None. Fire In case of fire: Use CO2, dry chemical, or foam for extinction. Explosion risk in case of fire. Eliminate all ignition sources if safe to do so.
3 Page 3 / 11 Spill None. Storage Store in a well-ventilated place. Keep container tightly closed. Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50 C/122 F. Protect from sunlight. Disposal Dispose of contents/container to an approved waste disposal plant. Hazards not otherwise classified (HNOC) None 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % Methyl acetate Carbon dioxide Petroleum distillates, hydrotreated light Butanol, 2-methyl-, acetate FIRST AID MEASURES First Aid Measures General Advice Eye Contact Skin Contact Inhalation Ingestion Protection of First-aiders Immediate medical attention is not required. Show this safety data sheet to the doctor in attendance. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Wash off immediately with plenty of water for at least 15 minutes. Remove and wash contaminated clothing before re-use. If symptoms develop move victim to fresh air. Immediate medical attention is not required. May cause adverse kidney effects. Drink plenty of water. Do NOT induce vomiting. Use personal protective equipment. Most important symptoms and effects, both acute and delayed Symptoms None known. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically. 5. FIRE-FIGHTING MEASURES
4 Page 4 / 11 Flash Point --20 C / -4 F Suitable Extinguishing Media Unsuitable Extinguishing Media Specific Hazards Arising from the Chemical Water spray, Carbon dioxide (CO2), Foam, Dry chemical Do not use a solid water stream as it may scatter and spread fire. Environmental Precautions. Flash back possible over considerable distance. Explosion Data Sensitivity to Mechanical Impact Not impact sensitive. Sensitivity to Static Discharge May be ignited by friction, heat, sparks or flames. Protective Equipment and Precautions for Firefighters In the event of fire and/or explosion do not breathe fumes. NFPA Health hazard 2 Flammability 4 Stability 0 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Use personal protective equipment. Avoid contact with the skin and the eyes. Avoid contact with eyes. Avoid breathing vapors or mists. Environmental Precautions Environmental Precautions Prevent entry into waterways, sewers, basements or confined areas. Beware of vapors accumulating to form explosive concentrations. Vapors can accumulate in low areas. Methods and material for containment and cleaning up Methods for Containment Methods for Cleaning up Prevent further leakage or spillage if safe to do so. Soak up with inert absorbent material. Pick up and transfer to properly labeled containers. After cleaning, flush away traces with water. Prevent product from entering drains. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Wear personal protective equipment.. Conditions for safe storage, including any incompatibilities Technical measures/storage conditions Incompatible products. Keep container tightly closed. Keep out of the reach of children. Strong acids. Strong oxidizing agents. Chlorinated compounds. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines.
5 Page 5 / 11 Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH STEL 500 ppm TWA: 250 ppm Methyl acetate Carbon dioxide Butanol, 2-methyl-, acetate Appropriate engineering controls STEL 250 ppm TWA: 200 ppm STEL ppm TWA: 5000 ppm STEL 100 ppm TWA: 50 ppm STEL 100 ppm TWA: 50 ppm TWA: 1000 ppm TWA: 2400 mg/m 3 (vacated) TWA: 750 ppm (vacated) TWA: 1800 mg/m 3 (vacated) STEL: 2400 mg/m 3 (vacated) STEL: 1000 ppm TWA: 200 ppm TWA: 610 mg/m 3 (vacated) TWA: 200 ppm (vacated) TWA: 610 mg/m 3 (vacated) STEL: 250 ppm (vacated) STEL: 760 mg/m 3 TWA: 5000 ppm TWA: 9000 mg/m 3 (vacated) TWA: ppm (vacated) TWA: mg/m 3 (vacated) STEL: ppm (vacated) STEL: mg/m 3 TWA: 100 ppm TWA: 525 mg/m 3 (vacated) TWA: 100 ppm (vacated) TWA: 525 mg/m 3 - IDLH: 2500 ppm TWA: 250 ppm TWA: 590 mg/m 3 IDLH: 3100 ppm TWA: 200 ppm TWA: 610 mg/m 3 STEL: 250 ppm STEL: 760 mg/m 3 IDLH: ppm TWA: 5000 ppm TWA: 9000 mg/m 3 STEL: ppm STEL: mg/m 3 IDLH: 1000 ppm TWA: 100 ppm TWA: 525 mg/m 3 Engineering Measures Showers Eyewash stations Ventilation systems. Individual protection measures, such as personal protective equipment Eye/Face Protection Skin and Body Protection Respiratory Protection Hygiene Measures Tightly fitting safety goggles. Long sleeved clothing. Protective gloves. No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required. When using, do not eat, drink or smoke. Remove and wash contaminated clothing before re-use. 9. PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Physical state appearance Odor Odor threshold Property Aerosol clear Hydrocarbon-like No information available Property ph 6-8 Melting point/freezing point No data available Boiling Point/Range no data available Flash Point --20 C / -4 F Vapor pressure No data available
6 Page 6 / 11 Vapor Density < 1 ( Air = 1 ) Specific Gravity Water solubility negligible Partition Coefficient: n-octanol/water no data available Autoignition Temperature No data available Decomposition Temperature No data available Viscosity, kinematic not applicable 10. STABILITY AND REACTIVITY reactivity No information available Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to Avoid Incompatible Materials Heat, flames and sparks. Strong acids. Strong oxidizing agents. Chlorinated compounds. Hazardous Decomposition Products Carbon monoxide, carbon dioxide and unburned hydrocarbons (smoke) 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Inhalation Eye Contact Skin Contact Ingestion Product does not present an acute toxicity hazard based on known or supplied information May cause irritation of respiratory tract. Contact with eyes may cause irritation. May cause irritation. There is no data available for this product. Component Information Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation = 5800 mg/kg ( Rat ) > mg/kg ( Rabbit ) = mg/m 3 ( Rat ) 8 h > 1600 mg/kg ( Rat ) - - Methyl acetate > 5 g/kg ( Rat ) > 5 g/kg ( Rabbit ) = ppm ( Rat ) 4 h Petroleum distillates, hydrotreated light > 5000 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) > 5.2 mg/l ( Rat ) 4 h Information on toxicological effects Symptoms Delayed and immediate effects as well as chronic effects from short and long-term exposure
7 Page 7 / 11 Sensitization Mutagenic Effects Carcinogenicity Reproductive toxicity Target Organ Effects Central nervous system (CNS), Central Vascular System (CVS), Respiratory system, Eyes, Skin. Numerical measures of toxicity - Product Information The following values are calculated based on chapter 3.1 of the GHS document. ATEmix (oral) 4392 mg/kg ATEmix (dermal) mg/kg ATEmix (inhalation-dust/mist) mg/l ATEmix (inhalation-vapor) mg/l 12. ECOLOGICAL INFORMATION Ecotoxicity Chemical Name Algae/aquatic plants Toxicity to Fish Toxicity to Microorganisms Toxicity to daphnia and other aquatic invertebrates EC50 = mg/l 15 min Methyl acetate Petroleum distillates, hydrotreated light LC ml/l Oncorhynchus mykiss 96 h LC mg/l Pimephales promelas 96 h LC50= 8300 mg/l Lepomis macrochirus 96 h EC mg/l 48 h EC mg/l 48 h - LC50= 650 mg/l Lepomis macrochirus 96 h - - EC50 > 120 mg/l 72 h LC mg/l EC50 = 6100 mg/l 30 min EC50 = mg/l 48 h Brachydanio rerio 96 h LC50 EC50 = 6000 mg/l 16 h mg/l Pimephales promelas 96 h Persistence and Degradability Bioaccumulation. Mobility The product is insoluble and floats on water. Chemical Name Methyl acetate Log Pow
8 Page 8 / 11 Other Adverse Effects No information available 13. DISPOSAL CONSIDERATIONS Waste treatment methods Waste Disposal Methods Contaminated Packaging US EPA Waste Number Should not be released into the environment. Dispose of in accordance with local regulations. Do not re-use empty containers. Empty containers should be taken to an approved waste handling site for recycling or disposal. D001 Chemical Name RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes Included in waste stream: ignitable waste F039 This product contains one or more substances that are listed with the State of California as a hazardous waste California Hazardous Waste Codes 561 Chemical Name Methyl acetate California Hazardous Waste Status Ignitable Toxic Ignitable Toxic Ignitable
9 Page 9 / TRANSPORT INFORMATION DOT UN-No 1950 Proper Shipping Name Aerosols, flammable, (each not exceeding 1 L capacity) Hazard Class 2.1 Special Provisions 49 CFR Description Compressed Gas. Emergency Response Guide 126 Number IMDG UN-No 1950 Proper Shipping Name Aerosol Hazard Class 2 Subsidiary Class 2.1 Special Provisions SP63 Description Limited quantity (LQ) 15. REGULATORY INFORMATION International Inventories TSCA DSL/NDSL NDSL EINECS ELINCS ENCS IECSC KECL PICCS AICS Not determined Not determined TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Chemical Name CAS-No Weight % SARA Threshold
10 Page 10 / Methyl acetate Carbon dioxide Petroleum distillates, hydrotreated light Butanol, 2-methyl-, acetate Values % SARA 311/312 Hazard Categories Acute Health Hazard Chronic Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard Yes No No No No Clean Water Act This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR and 40 CFR ): Chemical Name CWA - Reportable CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Quantities Substances 5000 lb X CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302): Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) 5000 lb - RQ 5000 lb final RQ RQ 2270 kg final RQ 5000 lb - RQ 5000 lb final RQ RQ 2270 kg final RQ U.S. State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations This product does not contain any substances regulated by state right-to-know regulations 16. OTHER INFORMATION Issuing Date Revision Date Reason for revision Change to composition. Disclaimer The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.
11 Page 11 / 11 SDS is available at End of Safety Data Sheet
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