SAFETY DATA SHEET. AquaNet NORTH SEA Ultra 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
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1 Revision date: 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product identifier Chemical name Product type Declaration no PRN Replace MSDS of Version number Relevant identified uses of the substance or mixture and uses advised against Uses of the chemical Uses advised against 1.3 Details of the supplier of the safety data sheet Manufacturer Responsible Author 1.4 Emergency telephone number 2. HAZARD IDENTIFICATION Anti-fouling products (Product type 21) Impregnation agent for floating net cages and ropes. This product is not recommended for other uses than those specified above. Steen-Hansen AS Ulsmågveien 24 N-5224 NESTTUN Norway Telephone: Fax: post@steen-hansen.no Steen-Hansen AS/Britt Hope Merete H. Selle Poison Information Centre: Classification of the substance or mixture Classification according to 1272/2008EC Classification according to 67/548/EEC and 1999/45/EC 2.2 Label elements Pictogram Aquatic Chronic 1; H410: Very toxic to aquatic environment. N; R50/53 Xn; R22 Signal word Hazard statement(s) Warning H410 Very toxic to aquatic life with long lasting effects. H400 Very toxic to aquatic life. H302 Harmful if swallowed. Precautionary statements General P102 Keep out of reach of children. Prevention P261 P273 Avoid release to the environment. Response P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P391 Collect spillage. Disposal P501 Dispose of contents/container to disposal facilities for hazardous waste. Page 1 (6)
2 2.3 Other hazards 3. COMPOSITION/INFORMATION ON INGREDIENTS 3.2 Mixtures Classification according to regulation Ingredients Identification 67/548/EEC, 1999/45/EC 1272/2008 (CLP) Copper (I) oxide Ec/Nlp nr: Cas nr: Index nr: X Xn; R22 N; R50/53 Acute Tox 4; H302 Aquatic Acute 1; H400 Aquatic Chronic 1; H410 Weight% Explanation Ingredients comments Xn=Harmful. N=Dangerous for the environment. Aquatic Acute 1: Very toxic to aquatic environment. Aquatic Chronic 1: Very toxic to aquatic environment. R-phrases with full text is found in section 16. All concentrations are listed as weight percent. The classification applies to each substance, not the product. 4. FIRST AID MEASURES 4.1 Description of first aid measures Inhalation Skin contact Eye contact Ingestion Medical information Health control 4.2 Most important symptoms and effects, both acute and delayed 4.3 Indication of any immediate medical attention and special treatment needed Provide fresh air and rest. Seek medical attention if breathing is difficult. Remove contaminated clothes. Wash with water. Seek medical attention with continued skin irritation. Flush eyes for a long time with plenty of water; Seek medical attention if pain persists. Drink plenty of water or milk. If more then a insignificant amount is swallowed, seek medical attention. Symptomatic treatment. General health check. Frequent and/or repeated contact with the skin may cause redness, irritation or ulceration to the skin. Remove the patient from the polluted area. Never give an unconscious person anything to drink. Show this safety data sheet to the doctor in attendance. 5. FIRE-FIGHTING MEASURES 5.1 Extinguishing media Suitable extinguishing media Extinguishing media which shall not be used 5.2 Special hazards arising from the substance or mixture 5.3 Advice for firefighters Extinguish surrounding fires with suitable extinguisher. Avoid using directed water jets during extinguishing work. Non flammable according to regulations for flammable products. Use of breathing protection equipment is recommended. Remove containers from scene of fire if this is possible without risk. Avoid using directed water jets during extinguishing work. 6. ACCIDENTAL RELEASE MEASURES 6.1 Personal precautions, protective equipment and emergency procedures 6.2 Environmental precautions 6.3 Methods and material for containment and cleaning up Containers with collected materials should be labeled carefully with the correct content. Wear protective clothing as described in Section 8.2 of the material safety data sheet. Keep persons and animals away from contaminated area. If possible, stop liquid flow. Absorb with suitable material, and deliver to nearest refuse disposal terminal. Page 2 (6)
3 6.4 Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 12 for information on ecology. See section 13 for waste disposal. The recommendations for emissions to water and land is based on the most likely spill scenario for this product. However, geographic conditions, wind, temperature, (the water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. Therefore, local experts should be consulted. Note: Local regulations may regulate or restrict certain activities. 7. HANDLING AND STORAGE 7.1 Precautions for safe handling Do not eat or drink while working with this product. Opened packages must be closed and kept in upright position to prevent leakage. Read and follow the diractions for use. Avoid waste when pouring into another container. Waste and residue are to be delivered to an approved waste depot in accordance with international and national guidelines. 7.2 Conditions for safe storage, including any incompatibilities Special precautions 7.3 Specific end use(s) Other information Keep container tightly closed. Store in a frost-free place. Temperature 5-35 C. Avoid direct sunlight. None known. Product residues and rinsing water must not be emptied in drains or in the nature. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 Control parameters 8.2 Exposure controls Exposure controls Provide sufficient general and local exhaust ventilation. Provide use of recommended safety equipment. Eyewash facilities should be available at the work place. Avoid innhalation of spraymist/dust. Avoid spill, skin and eye-contact. Respiration protection Eye protection Hand protection Skin protection Industrial hygiene: Wash hands before eating,drinking, smoking or using the toilet. Remove filthy clothes immidietaly/wash them thoroghly before re-using them. If the working area is properly ventilated, this is not necessary. Eye protection shall be in accordance to EN 166 standard. Use gloves. Don`t use gloves of PVA if the product are water-based. Working clothes and if necessary plastic apron. Protective equipment must be controlled and cleaned regularly. 9. PHYSICAL AND CHEMICAL PROPERTIES 9.1 Information on basic physical and chemical properties Form Colour Odour Smell limit Liquid. Reddish. No characteristic ph - conc. 8,8 Melting point Boiling point Flash point - Relative evaporation rate Flammability (solid, gas) Explosion limits Vapour pressure Vapour density Specific gravity Solubility Solubility water 1,33 g/cm3 ± 2,5 % Water Unlimited Page 3 (6)
4 Partition coefficient n-octanol/water Auto-ignition temp. Decomposition temperature Viscosity s DIN cup 4 20 C Explosive properties Oxidising properties 9.2 Other information 10. STABILITY AND REACTIVITY 10.1 Reactivity 10.2 Chemical stability Stable under normal conditions Possibility of hazardous No hazardous reactions know. reactions 10.4 Conditions to avoid Store in a dry and well ventilated area, away from heat source and direct sunlight. Temperature 5-35 C Incompatible materials Not known Hazardous decomposition products 11. TOXICOLOGICAL INFORMATION None when the product is handled according to regulations Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/ irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity STOT-single exposure Aspiration hazard Under normal use, no health effects are anticipated. Dangerous when swallowed. Contains copper oxide. Frequent or prolonged contact may remove natural oils and dry out the skin, and cause discomfort and dermatitis. Splashes in the eye can cause a burning sensation. Direct contact with the eyes will cause discomfort, normally this is temporary. None of the substances listed in section 3 is classified as allergenic. None of the substances listed in section 3 is classified as mutagenic. None of the substances listed in section 3 is classified as carcinogenic. None of the substances listed in section 3 is classified as reproduction toxic. Not known. Spraymist may cause irritation to respiratory tract. Health hazard is directly related to use and safety measures. 12. ECOLOGICAL INFORMATION 12.1 Toxicity Toxic for aquatic organisms. May cause long-term adverse effects in the aquatic environment. No eco-toxic effect known. For ingredient copper (I) oxide EC ppb LC mg/l (Daphnia) 12.2 Persistence and degradability 12.3 Bioaccumulative potential Bio-accumulation: Not known Mobility in soil 12.5 Results of PBT and vpvb No available data. assessment 12.6 Other adverse effects No available information. 13. DISPOSAL CONSIDERATIONS 13.1 Waste treatment methods Disposal group EAL Packings The product is not biologically degradable in terms of OECD criteria, but is nonetheless naturally degradable over time. The product is miscible with water in all proportions and can be transported far if spilled to water. Avoid release to the environment. Refer to special instructions/safety data sheets. The product must not be discharged in the sewer water stream or ground water. Packaging with product residual should be treated eqivalent to product. Clean packaging material Page 4 (6)
5 should be subjected to waste management schemes (recovery recycling, reuse) according to local legislation. Destruct according to legislation, contact local authorities. 14. TRANSPORT INFORMATION 14.1 UN number UN proper shipping name Item name IMDG proper shipping name 14.3 Transport hazard class(es) Label 9 ADR/RID class 9 ADR/RID classification code 9 ADR/RID danger number 90 IMDG class 9 IMDG marine pollutant IMDG EmS 14.4 Packing group III Paint related material (>25% kobberoksyd i vannløsning) Paint related material (>25% kobberoksyd i vannløsning) P F-A, S-F 14.5 Environmental hazards The product must not be discharged in the sewer water stream or ground water Special precautions for user 14.7 Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code 15. REGULATORY INFORMATION Tunnel restriction code 3 (E) Safety, health and environmental regulations/ legislation specific for the substance or mixture 15.2 Chemical safety assessment Commission Regulation (EU) No 453/2010 Annex II (Appendix II - "II"). European Parliament and Council Regulation (EC) 1272/2008. Transport of hazardous goods: ADR, RID, IMDG, IATA (2011). Regulations regarding OAR values. Administrative norms for pollution of the atmosphere (Arbeidstilsynet, 2008). ECHA (European Chemicals Agency) C&L Inventory database. Ex-ECB databasen ( COMMISSION REGULATION (EU) No 944/2013 of 2 October 2013 (ATP5). Norwegian Waste Regulations (miljøverndepartementet) - FOR No. 930: Regulations relating to the recycling of waste. The information in this safety data sheet should not be regarded as the user's own risk assessment. It is always the user's responsibility to take all necessary steps in order to meet the requirements of the local rules and regulations. Classification of this product is given on the basis of the available information from the vendor. 16. OTHER INFORMATION Relevant hazard- and risk phrases given in section 3 H302 Harmful if swallowed. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. R-22 Harmful if swallowed. R-50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Key literature references and Material safety data sheet from the supplier. sources for data First released Printed date The above information is believed to be correct but not necessarily all inclusive and shall be used only as a guide. The data are based on the current state of our knowledge, and are intended to describe the product with regard to the requirements of safety. The data should not be taken to imply any guarantee of a particular or general specification. It is the responsibility of the user of the product to ensure to his satisfaction that the product is suitable for the intended purpose and method of use. Page 5 (6)
6 We do not accept responsibility for any harm caused by the use of this information. For more information go to our web-site SAFETY DATA SHEET conforming to commission regulation 67/548/EEC, 1999/45/EC and (EU) No 453/2010 of 20. May Page 6 (6)
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