: GELEST RG 02 OLEOPHILIC REPROGRAPHIC SILICONE

Transcription

1 PP2-RG02 - GELEST RG 02 OLEOPHILIC REPROGRAPHIC SILICONE GELEST RG 02 OLEOPHILIC REPROGRAPHIC SILICONE PP2-RG02 Date of issue: 26/10/2015 Version: 1.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Physical state Product name Product code Synonyms Chemical family : Mixture : Liquid : GELEST RG 02 OLEOPHILIC REPROGRAPHIC SILICONE : PP2-RG02 : 2-COMPONENT SILICONE RTV; VINYL, METHYL MODIFIED SILICA in POLY(DIMETHYLSILOXANE), VINYLTERMINATED with (part B) HYDRIDE FUNCTIONAL CROSSLINKER : ORGANOSILOXANE 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Use of the substance/mixture : Chemical intermediate For research and industrial use only Uses advised against 1.3. Details of the supplier of the safety data sheet GELEST, INC. 11 East Steel Road Morrisville, PA USA T F (M-F): 8:00 AM - 5:30 PM EST info@gelest.com - GELEST INC. Stroofstrasse 27 Geb Frankfurt am Main Germany T +49-(0) F +49-(0) (M-F): 8:00 AM - 5:30 PM info@gelestde.com Emergency telephone number Emergency number : CHEMTREC: (USA); (International) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Not classified 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] EUH-statements : EUH210 - Safety data sheet available on request 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.1. Substance 3.2. Mixture 26/10/2015 EN (English) SDS ID: PP2-RG02 1/6

2 Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] Part A: Vinyl terminated polydimethylsiloxane (CAS No) (EC no) > 70 Not classified Part A: Vinyl, methyl modified silica (CAS No) > 30 Not classified Part B: Methylhydrosiloxane-dimethylsiloxane copolymer, trimethylsiloxane terminated Full text of H-statements: see section 16 (CAS No) (EC no) < 30 Not classified SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Remove contaminated clothing and shoes. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). If possible show this sheet; if not available show packaging or label. : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If you feel unwell, seek medical advice. : Wash with plenty of soap and water. Get medical advice/attention. : Immediately flush eyes thoroughly with water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical advice/attention. : Never give anything by mouth to an unconscious person. Get medical advice/attention Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation Symptoms/injuries after skin contact Symptoms/injuries after eye contact Symptoms/injuries after ingestion : May cause skin irritation. : May cause eye irritation Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Water spray. Water fog. Foam. Carbon dioxide. Dry chemical. : None known Special hazards arising from the substance or mixture Fire hazard : Irritating fumes and organic acid vapors may develop when material is exposed to elevated temperatures or open flame Advice for firefighters Firefighting instructions Protection during firefighting : Exercise caution when fighting any chemical fire. Use water spray or fog for cooling exposed containers. : Do not enter fire area without proper protective equipment, including respiratory protection. Avoid all eye and skin contact and do not breathe vapour and mist. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Protective equipment : Wear protective equipment as described in Section 8. Emergency procedures : Evacuate unnecessary personnel For emergency responders Protective equipment : Do not attempt to take action without suitable protective equipment. Equip cleanup crew with proper protection. For further information refer to section 8: "Exposure controls/personal protection" Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters Methods and material for containment and cleaning up For containment Methods for cleaning up : Contain any spills with dikes or absorbents to prevent migration and entry into sewers or streams. : Clean up any spills as soon as possible, using an absorbent material to collect it. Sweep or shovel spills into appropriate container for disposal. 26/10/2015 EN (English) SDS ID: PP2-RG02 2/6

3 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures 7.2. Conditions for safe storage, including any incompatibilities Storage conditions Incompatible materials Storage area 7.3. Specific end use(s) : Avoid all eye and skin contact and do not breathe vapour and mist. Use only outdoors or in a well-ventilated area. : Wash contaminated clothing before reuse. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. : Keep container tightly closed. SECTION 8: Exposure controls/personal protection 8.1. Control parameters : Alkalis. Metal salts. Oxidizing agent. Precious metals. : Store in a well-ventilated place. Store away from heat Exposure controls Appropriate engineering controls Personal protective equipment : Provide local exhaust or general room ventilation. : Avoid all unnecessary exposure. Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Hand protection Eye protection Skin and body protection Respiratory protection : Neoprene or nitrile rubber gloves. : Chemical goggles. Contact lenses should not be worn. : Wear suitable protective clothing. : Where exposure through inhalation may occur from use, respiratory protection equipment is recommended. NIOSH-certified organic vapor (black cartridge) respirator. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Clear liquid. Viscous. Molecular mass : (mixture) Colour : Translucent. Odour Odour threshold Refractive index ph Relative evaporation rate (butylacetate=1) Melting point : < -60 C Freezing point Boiling point : > 205 C Flash point : 121 C Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure : < 1 mm 20 C Relative vapour density at 20 C Relative density : 1.04 VOC content : < 3 % Solubility : Insoluble in water. Log Pow Log Kow Viscosity, kinematic : A: cst; B: cst Viscosity, dynamic 26/10/2015 EN (English) SDS ID: PP2-RG02 3/6

4 Explosive properties Oxidising properties Explosive limits 9.2. Other information SECTION 10: Stability and reactivity Reactivity Chemical stability Stable in sealed containers stored under a dry inert atmosphere Possibility of hazardous reactions B-part is reactive with metal salts and precious metals Conditions to avoid Heat. Open flame. Sparks Incompatible materials Alkalis. Metal salts. Oxidizing agent. Precious metals Hazardous decomposition products Formaldehyde. Organic acid vapors. Silicon dioxide. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Part A: Vinyl terminated polydimethylsiloxane ( ) LD50 oral rat LD50 dermal rabbit Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity > 16 ml/kg > 16 ml/kg Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Symptoms/injuries after inhalation Symptoms/injuries after skin contact Symptoms/injuries after eye contact Symptoms/injuries after ingestion : May cause skin irritation. : May cause eye irritation. SECTION 12: Ecological information Toxicity Persistence and degradability Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects 26/10/2015 EN (English) SDS ID: PP2-RG02 4/6

5 SECTION 13: Disposal considerations Waste treatment methods Sewage disposal recommendations : Do not dispose of waste into sewer. Waste disposal recommendations : Incinerate. Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information UN number Not regulated for transport UN proper shipping name Transport hazard class(es) Packing group Environmental hazards Other information : No supplementary information available Special precautions for user Overland transport Transport by sea Air transport Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances National regulations Water hazard class (WGK) : 3 - severe hazard to waters Part A: Vinyl terminated polydimethylsiloxane ( ) Listed on the AICS (Australian Inventory of Chemical Substances) Listed on the Canadian DSL (Domestic Substances List) Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China) Listed on the Korean ECL (Existing Chemicals List) Listed on NZIoC (New Zealand Inventory of Chemicals) Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances) Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on INSQ (Mexican national Inventory of Chemical Substances) Part A: Vinyl, methyl modified silica ( ) Listed on the AICS (Australian Inventory of Chemical Substances) Listed on the Canadian DSL (Domestic Substances List) Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China) Listed on the Korean ECL (Existing Chemicals List) Listed on NZIoC (New Zealand Inventory of Chemicals) Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances) Listed on the United States TSCA (Toxic Substances Control Act) inventory 26/10/2015 EN (English) SDS ID: PP2-RG02 5/6

6 Part B: Methylhydrosiloxane-dimethylsiloxane copolymer, trimethylsiloxane terminated ( ) Listed on the AICS (Australian Inventory of Chemical Substances) Listed on the Canadian DSL (Domestic Substances List) Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China) Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory Listed on the Korean ECL (Existing Chemicals List) Listed on NZIoC (New Zealand Inventory of Chemicals) Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances) Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on INSQ (Mexican national Inventory of Chemical Substances) Chemical safety assessment SECTION 16: Other information Abbreviations and acronyms : Abbreviations: ND: Not Determined, No Data; NA: Not Applicable; LD: Lethal Dose; LC: Lethal Concentration; ATE: Acute Toxicity Estimates; H: hour; : C unless otherwise stated; mm: millimeters Hg, torr; PEL: permissible exposure level; TWA: time weighted average; TLV: threshold limit value; TG: Test Guideline; NIOSH: National Institute for Occupational Safety and Health; IARC: International Agency for Research on Cancer; NTP: National Toxicology Program; HMIS: Hazardous Material Information System; CAS No.: Chemcial Abstract Service Registration Number; EC No.: European Commission Registration Number; EC Index No.: European Commission Index Number; OECD: The Organisation for Economic Co-operation and Development. Full text of H- and EUH-statements: EUH210 Safety data sheet available on request Prepared by safety and environmental affairs. SDS EU (REACH Annex II) - Custom according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830 The information contained in this document has been gathered from reference materials and/or Gelest, Inc. test data and is to the best knowledge and belief of Gelest, Inc. accurate and reliable. Such information is offered solely for your consideration, investigation and verification. It is not suggested or guaranteed that the hazard precautions or procedures described are the only ones which exist. Gelest, Inc. makes no warranties, express or implied, with respect to the use of such information and assumes no responsibility therefore. Information on this safety data sheet is not intended to constitute a basis for product specifications Gelest Inc. Morrisville, PA /10/2015 EN (English) SDS ID: PP2-RG02 6/6