(2010) Analysis of Options to Move beyond 20% Greenhouse Gas Emission Reductions and Assessing the Risk of Carbon Leakage,

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1 Documents Abdul Quader, M. a, Ahmed, S. b, Dawal, S.Z. a, Nukman, Y. c Present needs, recent progress and future trends of energy-efficient Ultra-Low Carbon Dioxide (CO2) Steelmaking (ULCOS) program (2016) Renewable and Sustainable Energy Reviews, 55, pp DOI: /j.rser a Department of Mechanical Engineering, Faculty of Engineering, University of Malaya, Kuala Lumpur, Malaysia b Department of Mechanical and Chemical Engineering, Islamic University of Technology (IUT), Dhaka, Bangladesh c Department of Engineering Design and Manufacture, University of Malaya, Faculty of Engineering, Kuala Lumpur, Malaysia Abstract The iron and steel industry is the largest energy consuming manufacturing sector, consuming 5% of the world's total energy consumption and producing 6% of the total world anthropogenic CO2 emission. Under the European Ultra Low CO2 Steelmaking (ULCOS) program, several breakthrough technologies for the drastic reduction of CO2 emissions from iron and steelmaking industry have been investigated, including (1) blast furnace with top-gas recycling (TGR-BF), (2) a new smelting reduction process (HIsarna), (3) advanced direct reduction (ULCORED) and (4) electrolysis of iron ore (ULCOWIN and ULCOLYSIS). Besides, hydrogen-based steel making and the use of biomass as reducing agent have been evaluated as supporting technology to decrease CO2 emissions. The aim of the present article is to analyze the technological developments in iron and steel industry and the progress of present experimental works developed inside the ULCOS I and II projects by collating updated information from a wide range of sources. In addition, the breakthrough technologies expected to develop or are currently being demonstrated at pilot/industrial scale for significant reduction of CO2 emissions in Europe have been identified in this paper. Economic and environmental performance of the ULCOS cutting edge technologies shows that the implementation of CCS technology in coal-based integrated steel plants might reduce 80% of CO2 emissions. However, hydrogen and biomass-based steelmaking also offers very attractive perspectives, while raising lots of major challenges. Finally, comparative assessment of the ULCOS program with others CO2 breakthrough programs around the world has also been done Elsevier Ltd. All rights reserved. Author Keywords Carbon capture and storage (CCS); CO2 breakthrough technology; CO2 emission; Iron and steel industry; ULCOS Index Keywords Blast furnaces, Carbon capture, Carbon dioxide, Emission control, Energy efficiency, Energy utilization, Environmental management, Environmental technology, Gas emissions, Iron, Iron ore reduction, Iron ores, Ore reduction, Smelting, Steelmaking; Breakthrough technology, Comparative assessment, Cutting edge technology, Economic and environmental performance, Steel-making industries, Technological development, Total energy consumption, ULCOS; Iron and steel industry References Suopajärvi, H., Pongrácz, E., Fabritius, T. Bioreducer use in Finnish blast furnace ironmaking-analysis of CO<sub>2</sub> emission reduction potential and mitigation cost (2014) Appl Energy, 124, pp (2010) Analysis of Options to Move beyond 20% Greenhouse Gas Emission Reductions and Assessing the Risk of Carbon Leakage, 1/10

2 E.E. Commission Commission Staff working document, SEC 650 Communication from the Commission to the European Parliament, the Council, the European Economic and Social Committee and the Committee of the Regions, COM(2011) 885/2 (2011) E. Roadmap 2050, Brussels: European Commission Fischedick, M., Marzinkowski, J., Winzer, P., Weigel, M. Techno-economic evaluation of innovative steel production technologies (2014) J Clean Prod, 84, pp Pardo, N., Moya, J., Vatopoulos, K. (2012) Prospective Scenarios on Energy Efficiency and CO<sub>2</sub> Emissions in the EU Iron Steel Ind., Publications Office Helle, H. (2014) Towards Sustainable Iron-and Steelmaking with Economic Optimization, Onarheim, K., Mathisen, A., Arasto, A. Barriers and opportunities for application of CCS in Nordic industry - A sectorial approach (2015) Int J Greenh Gas Control, 36, pp Hasanbeigi, A., Arens, M., Price, L. Alternative emerging ironmaking technologies for energy-efficiency and carbon dioxide emissions reduction: A technical review (2014) Renew Sustain Energy Rev, 33, pp Morfeldt, J., Nijs, W., Silveira, S. The impact of climate targets on future steel production - An analysis based on a global energy system model (2014) J Clean Prod, Patel, P., Seetharaman, S. A test of the steel industry's metal (2013) MRS Bull, 38 (9), pp Burchart-Korol, D. Life cycle assessment of steel production in Poland: A case study (2013) J Clean Prod, 54, pp (2013) Iron and Steel CCS Study (Techno-Economics Integrated Steel Mill), GHG I. IEA GHG Report 2013/04, July IEA GHG Thompson, S., Si, M. Strategic analysis of energy efficiency projects: Case study of a steel mill in 2/10

3 Manitoba (2014) Renew Sustain Energy Rev, 40, pp Flues, F., Rübbelke, D., Vögele, S. An analysis of the economic determinants of energy efficiency in the european iron and steel industry (2015) J. Clean. Prod, Germeshuizen, L.M., Blom, P. A techno-economic evaluation of the use of hydrogen in a steel production process, utilizing nuclear process heat (2013) Int J Hydrogen Energy, 38 (25), pp Lin, B., Wang, X. Carbon emissions from energy intensive industry in China: Evidence from the iron & steel industry (2015) Renew Sustain Energy Rev, 47, pp Advanced Manufacturing Office (AMO). 2014, U.S. Department of Energy (U.S.DOE) Åhman, M., Nikoleris, A., Nilsson, L.J. (2012) Decarbonising Industry in Sweden-an Assessment of Possibilities and Policy Needs, Lund University Kasai, E. Recent resource and environmental issues in the steel industry (2015) Topical Themes in Energy and Resources, pp Tanaka Y, Norton M, Li Y-Y, Editors Japan: Springer Burchart-Korol, D., Pichlak, M., Kruczek, M. Innovative technologies for greenhouse gas emission reduction in steel production Metalurgija, 55 (1), pp Birat, J.-P., Borlee, J., Korthas, B., Stel, J., Van Der Meijer, K., Günther, C., Halin, M., Treadgold, Ch. ULCOS program: A progress report in the Spring of 2008, SCANMET III. (2008) Proceedings of the 3rd International Conference on Process Development in Iron and Steelmaking, Luleå, Sweden Birat, J.-P. The sustainability of Steel: Iron as a backbone of urban and societal metabolism (2008) Proceedings of the International Steel Technologies Symposium, Taiwan Quader, M.A. 3/10

4 A comprehensive review on energy efficient CO<sub>2</sub> breakthrough technologies for sustainable green iron and steel manufacturing (2015) Renew Sustain Energy Rev, 50, pp Association, W.S. World steel in figures 2011 (2011) World Steel Assoc, 2. Fallot, A. Biomass sustainability, availability and productivity (2009) Revue de Métallurgie, 106 (10), pp Birat, J.-P. CCS and the steel industry Proceedings of the International Conference on CCS Regulation for the EU and China 2009, Maizière-Lès-Metz Birat, J. (2010) Steel Sectoral Report - Contribution to the UNIDO Roadmap on CCS1-fifth Draft Global Technology Roadmap for CCS in Ind, United Nations Ind. Dev. Organization, Vienna, Austria Birat, J.-P. Addressing the climate change challenge: ULCOS breakthrough program (2009) Proceeding of the 157th ISIJ Meeting on International Organized Sessions, Environmental and Energy Technology/high Temperature Processes, Tokyo, Japan CAMP-ISIJ Birat, J.-P. The «co<sub>2</sub> tool»: Emissions and energy consumption of existing and breakthrough routes in a future studies framework (2009) La Revue de Métallurgie - CIT, pp E. ULCOS-Perspectives, Commission [cited September] Structure and Financing, ULCOS [cited September] Birat, J. ULCOS program: An update in 2012 (2012) Proceedings of 4th International Conference on Process Development in Iron and Steelmaking (SCANMET IV), Luleå, Sweden Porzio, G.F. Reducing the energy consumption and CO<sub>2</sub> emissions of energy intensive industries through decision support systems-an example of application to 4/10

5 the steel industry (2013) Appl Energy, 112, pp Birat, J. ULCOS: The European steel industry's effort to find breakthrough technologies to cut its CO<sub>2</sub> emissions significantly (2006) Proceedings of the EU/Asia Workshop on Clean Production and Nanotechnologies, Seoul, South Korea Siitonen, S., Tuomaala, M., Ahtila, P. Variables affecting energy efficiency and CO<sub>2</sub> emissions in the steel industry (2010) Energy Policy, 38 (5), pp Afanga, K., Olivier, M., Fabrice, P. Assessment of top gas recycling blast furnace: A technology to reduce CO<sub>2</sub> emissions in the steelmaking industry (2012) Proceedings of the Carbon Management Technology Conference, Hattink, M. Developments of the ULCOS Low CO<sub>2</sub> Blast Furnace Process at the LKAB Experimental BF in Luleå, Danloy, G. ULCOS-pilot testing of the low-co<sub>2</sub> blast furnace process at the experimental BF in Luleå (2009) Revue de Métallurgie, 106 (1), pp (2014) Top Gas Recycling, [cited /08] Wyns, T. (2012) The Low Carbon Future of the European Steel Sector, CENTER FOR CLEAN AIR POLICY EUROPE European Parliament Guangqing, Z., Hirsch, A. The trial of the top gas recycling blast furnace at LKAB s' EBF and scale-up (2009) La Revue de Metallurgie, pp Van Der Stel, J. Developments of the ULCOS low CO<sub>2</sub> blast furnace process at the LKAB experimental BF in Luleå (2011) Proceedings of the 1st International Conference on Energy Efficiency and CO<sub>2</sub> Reduction in the Steel Industry, Düsseldorf Van Der Stel, J., Sert, D., Hirsch Ing., A., Eklund, N., Sundqvist Ökvist, L. 5/10

6 (2012) TOP Gas Recycle Blast Furnace Developments for Low CO<sub>2</sub> Ironmaking, [cited September] Van Der Stel, J. (2014) ULCOS Top Gas Recycling Blast Furnace Process (ULCOS TGRBF): Final Report, Publications Office (2014) HIsarna Smelter Technology, ULCOS [cited August] Assefa, G. ORWARE: An aid to environmental technology chain assessment (2005) J Clean Prod, 13 (3), pp (2014) ULCORED, ULCOS [cited August] Fu, J.X. Carbon reduction programs and key technologies in global steel industry (2014) J Iron Steel Res, Int, 21 (3), pp Staal. B, M. (2004) ULCOS=Ultra Low CO<sub>2</sub> Steelmaking, [cited July] Abbasi, M. A feasibility study for synthesis gas production by considering carbon dioxide capturing in an industrial-scale methanol synthesis plant (2015) Arab J Sci Eng, 40 (5), pp Yanmaz, M., Kaya, D. Ultra-low carbon diox DE (CO<sub>2</sub>) steelmaking (2012) Eng Sci Technol Int J, 15, p. 2. Hsu, C.K. Reduction of energy consumption and pollution emissions for industrial furnace using hydrogen-rich tail gas (2014) Int J Hydrogen Energy, 39 (18), pp Chen, W.H. An evaluation of hydrogen production from the perspective of using blast furnace gas and coke oven gas as feedstocks (2011) Int J Hydrogen Energy, 36 (18), pp Chen, W.H. Hydrogen production from steam reforming of coke oven gas and its utility for 6/10

7 indirect reduction of iron oxides in blast furnace (2012) Int J Hydrogen Energy, 37 (16), pp Yan, X.L. Study of a nuclear energy supplied steelmaking system for near-term application (2012) Energy, 39 (1), pp Kasahara, S., Inagaki, Y., Ogawa, M. Flow sheet model evaluation of nuclear hydrogen steelmaking processes with VHTR-IS (very high temperature reactor and iodine-sulfur process) (2012) ISIJ Int, 52 (8), pp Ranzani Da Costa, A., Wagner, D., Patisson, F. Modelling a new, low CO<sub>2</sub> emissions, hydrogen steelmaking process (2013) J Clean Prod, 46, pp Ranzani Da Costa, A. Modélisation d'un four à cuve de réduction directe du minerai de fer par l'hydrogène pur (2009) Revue de Métallurgie, 106 (10), pp Nogami, H., Yagi, J.I., Sampaio, R.S. Exergy analysis of charcoal charging operation of blast furnace (2004) ISIJ Int, 44 (10), pp Alakangas, E. (2005) Properties of Wood Fuels Used in Finland, Technical Research Centre of Finland, VTT Processes. Project Report Pro2/P2030/05 (Project C5SU00800) Suopajärvi, H., Pongrácz, E., Fabritius, T. The potential of using biomass-based reducing agents in the blast furnace: A review of thermochemical conversion technologies and assessments related to sustainability (2013) Renew Sustain Energy Rev, 25, pp Srivastava, U., Kawatra, S.K., Eisele, T.C. Production of pig iron by utilizing biomass as a reducing agent (2013) Int J Miner Process, 119, pp Carbon Capture and Storage (CCS), ULCOS [cited October] Hooey, L. Techno-economic study of an integrated steelworks equipped with oxygen blast furnace and CO<sub>2</sub> Capture (2013) Energy Proced, 37, pp Rootzén, J., Johnsson, F. 7/10

8 Exploring the limits for CO<sub>2</sub> emission abatement in the EU power and industry sectors - Awaiting a breakthrough (2013) Energy Policy, 59, pp Saima, W.H., Mogi, Y., Haraoka, T. Development of PSA system for the recovery of carbon dioxide and carbon monoxide from blast furnace gas in steel works (2013) Energy Proced, 37, pp Romano, M.C. Application of advanced technologies for CO<sub>2</sub> capture from industrial sources (2013) Energy Proced, 37, pp Goff, F., Lackner, K. Carbon dioxide sequestering using ultramafic rocks (1998) Environ Geosci, 5 (3), pp Rawlins, C.H. Sequestration of CO<sub>2</sub> from steelmaking offgas by carbonate formation with slag (2006) Assoc Iron Steel Technol AIST, Croezen, H., Korteland, M. (2010) Technological Developments in Europe: A Long-term View of CO<sub>2</sub> Efficient Manufacturing in the European Region: Report, CE Delft Meijer, K. (2008) ULCOS, Ultra Low CO<sub>2</sub> Steelmaking, Presentation given at 25 September Link, J. IRMA - Flowsheet model-examples of application ijmuiden: Corus research development & technology (2008) Proceedings of the 4th ULCOS Seminar, Birat, J. Carbon dioxide (CO2) capture and storage technology in the iron and steel industry (2010) Developments and Innovation in Carbon Dioxide (CO2) Capture and Storage Technology, 1, pp Association, W. (2012) Sustainable Steel: At the Core of A Green Economy, Brussels Belgium Naito, M., Matsuzaki, S., Yonezawa, K., Saito, K. Possibility of hydrogen reduction in iron-making process (COURSE 50 program in 8/10

9 Japan) (2009) Proceedings of the 157th ISIJ Meeting, International Organized Sessions, Environmental and Energy Technology/high Temperature Processes, Tokyo, Japan CAMP-ISIJ Tonomura, S. Outline of Course 50 (2013) Energy Proced, 37, pp Birat, J., Maizière-Lès-Metz, D. (2010) Steel sectoral report. Contribution to the UNIDO roadmap on CCS1-fifth draft JP, Birat, Arcelor Mittal Global R and D, Maizières-lès-Metz, France Kim, H. The influence of electrolyte basicity on the performance of an iridium anode for the electrolysis of molten iron oxide (2011) J Electrochem Soc, 158, pp. E101-E105. Pinegar, H.K., Moats, M.S., Sohn, H.Y. Process simulation and economic feasibility analysis for a hydrogen-based novel suspension ironmaking technology (2011) Steel Res Int, 82 (8), pp Steel Industry Developing Technical Solutions to Climate Change by Reducing Steel Making Emissions and Energy Intensity 2015, Institute, A.I.a.S. [cited /05/2015] Birat, J. (2007) Mitigation of Greenhouse Gas Emissions in the Steel Sector, with A Focus on Biomass Issues III Conférencia Regional Sobre Mudanças Globais: Am. Do Sul, Saõ Paulo, pp Correspondence Address Abdul Quader M.; Department of Mechanical Engineering, Faculty of Engineering, University of MalayaMalaysia; maquader.me@gmail.com Publisher: Elsevier Ltd ISSN: CODEN: RSERF Language of Original Document: English Abbreviated Source Title: Renewable Sustainable Energy Rev Document Type: Review Source: Scopus About Scopus What is Scopus Content coverage About Elsevier About Elsevier Terms and Conditions Privacy Policy Customer Service Help and Contact Live chat 9/10

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