SECTION 1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING

Transcription

1 Date issued: Date revised: Revision : 2 SECTION 1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING 1.1. Product identifier Calcium chloride pellets / powder 95-98% food grade Trademark: Fudix TM CHEMICAL NAME:, CaCl2 CAS : EC : REACH registration number: Index CLP Annex VI Regulation (EC) No 1272/2008: Relevant identified uses of the substance or mixture and uses advised against Food industry uses: ph regulation in brewing industry. Fruits and vegetables processing and preservation. Meat tenderization and freezing point decreasing. Ice cream production. Jelly and jam production. Cheese and curd production for speeding the process of coagulation Details of the supplier of the safety data sheet MANUFACTURER: Zirax LLC ADDRESS: Microrayon 4, 6 Svetly Yar settlement, Volgograd region, RUSSIA Telephone: Fax: info@zirax.com 1.4. Emergency telephone number SECTION 2. HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture According to Regulation (EC) No 1272/2008 of the European Parliament: Hazard statement code: H319: Causes serious eye irritation Hazard Class and category code: Eye Irritation 2 According to Directive 67/548/EEC: Xi; R36 Irritating to eyes 2.2. Label elements According to Regulation (EC) No 1272/2008 EEC HAZARD PICTOGRAM GHS07: exclamation mark SIGNAL WORD: Warning HAZARD STATEMENT: H319: Causes serious eye irritation PRECAUTIONARY STATEMENTS: P 264: Wash hands thoroughly after handling. P 280: Wear protective glasses with splash shields or safety goggles/shield. page 1 of 34

2 P305 + P351 + P338: IF IN EYES Rinse eyes cautiously with water for 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P 313 If irritation continued get prompt qualified medical advice / attention Other hazards Calcium chloride can cause minor skin irritation. SECTION 3. COMPOSITION / INFORMATION ON INGREDIENTS 3.1. Substances Component Name CAS Number EC Concentration w/w Classification: Regulation (EC) No 1272/2008 Calcium Chloride % H319: Causes serious eye irritation Eye Irritation 2 class SECTION 4. FIRST AID MEASURES 4.1. Description of first aid measures EYES: Remove contact lenses, if present and easy to do. Rinse cautiously with water for 15 minutes. Seek medical attention. SKIN: Remove contaminated clothes; wash off any skin contaminations with soap and water. Launder contaminated clothes before re-use. INGESTION: Get prompt qualified medical attention. If conscious, give 1-2 glasses of water with absorbent carbon. INHALATION: Remove to fresh air. Keep in warm and at rest. Give oxygen or artificial aspiration if needed. If symptoms persist seek medical attention. FIRST AID MEASURES: absorbent carbon, saline purge Most important symptoms and effects, both acute and delayed EYES: Could cause irritant or burn effects to the eyes. SKIN: Could cause irritant effects to the skin. No delayed symptoms after washing contaminated skin. INGESTION: May cause nausea. May cause GI tract irritation. INHALATION: Dust may cause irritation to mucous membranes and respiratory system Indication of any immediate medical attention and special treatment needed No special antidotes. If case of ingestion wash mouth with water and give plenty water to drink. Get medical attention if needed. SECTION 5. FIRE FIGHTING MEASURES 5.1. Extinguishing media This product is a nonflammable substance. However, hazardous decomposition and combustion products may be formed in a fire situation. Cool exposed containers with water spray to prevent overheating. Extinguish fire using agent suitable for type of surrounding fire and/or chemicals. Do not use water directly on material. Heat is generated when product mixed with water Special hazards arising from the substance or mixture No special hazards Advice for firefighters Respiratory and eye protection are required for fire fighting personnel. Avoid breathing corrosive vapors. page 2 of 34

3 SECTION 6. ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Wearing the appropriate personnel protective equipment designated in Section 8, move the container to a containment area or rotate the container so that the opening is above the liquid level Environmental precautions WATER SPILL: Use appropriate containment to avoid runoff or release to sewer or waterways. LAND SPILL: Use appropriate containment to avoid runoff or release to ground Methods and material for containment and cleaning up Construct temporary dikes of dirt, sand, or any appropriate readily available material to prevent spreading of the material. Wearing the appropriate personal protective equipment designated in Section 8, close or cap valves and/or block or plug hole in leaking container and transfer to another container. Remove containers with disposal from release area Reference to other sections For addition information see section 13. SECTION 7. HANDLING AND STORAGE 7.1. Precautions for safe handling Avoid skin and eye contact and breathing dusts. Use proper protective and respiratory equipment. Not to eat, drink and smoke in work areas. Wash hands thoroughly after handling. Launder contaminated clothing before re-use. Ventilate area. Sweep or vacuum; do not create dust; place in a dry container for disposal. Clean spill area with water Conditions for safe storage, including any incompatibilities Store in a cool, dry, well-ventilated place. Keep container closed when not in use. Keep away from incompatible materials. Protect from atmospheric moisture Specific end use(s) No specific end uses. SECTION 8. EXPOSURE CONTROLS/ PERSONAL PROTECTION 8.1. Control parameters National occupational exposure limit values: maximum allowable concentration in the air of the working zone 2 mg/m, aerosol, 3 class of hazard 8.2. Exposure controls ENGINEERING CONTROLS: Where environmental controls are lacking or in enclosed spaces use a NIOSH/MSHA approved respirator for dust/fumes. Provide local exhaust ventilation system. Eye wash station and safety shower should be provided within the immediate work area for emergency use. EXPOSURE LIMITS: No occupational exposure limits established by OSHA/ACGIH/NIOSH. PERSONAL PROTECTIVE EQUIPMENT: EYES: Wear safety glasses with splash shields or safety goggles/shield. BODY: Wear appropriate protective (impervious) clothing. Leather work boots and/or leather products will dehydrate with resultant shrinkage and possible destruction. RESPIRATORY: A respirator is not indicated under normal operating conditions. Use of a NIOSH approved respirator should be based upon the presence of nuisance dust. When warranted, use a face mask particulate respirator with particulate respirator with a NIOSH N95 rating. HANDS AND FEET: Wear appropriate rubber gloves and non-leather protective boots. WORK HYGIENIC PRACTICES: Use reasonable care in handling this product. Wash hands after use and before eating. page 3 of 34

4 SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties (a) Appearance: White pellets / powder (b) Odour: Odourless (c) Odour threshold: Not applicable (d) ph: Neutral or slightly alkaline (e) Melting point/freezing point: 772 o C (1,422 Fº) (f) Initial boiling point and boiling range; >1627 C (g) Flash point: Not applicable (h) Evaporation rate: Not applicable (i) Flammability (solid, gas): Not Flammable (j) Upper/lower flammability or explosive limits: Not applicable (k) Vapour pressure: Not applicable (l) Vapour density: Not applicable (m) Relative density: Min 700 kg/m 3 (50 lb/ft³) (n) Solubility(ies): Soluble in alcohol, acetic acid and acetone (o) Partition coefficient: n-octanol/water: inorganic substance, not applicable (p) Auto-ignition temperature: Not applicable (q) Decomposition temperature: Not applicable (r) Viscosity: Not applicable for a solid product (s) Explosive properties: the substance is non-explosive (t) Oxidising properties: the substance is non-explosive 9.2. Other information MOLECULAR WEGHT: 111 SECTION 10. STABILITY AND REACTIVITY Reactivity Reacts exothermically with water, acids and alkali Chemical stability Product is stable under normal / recommended storage and handling conditions Possibility of hazardous reactions Will not occur Conditions to avoid To avoid contact of material with incompatible materials Incompatible materials Incompatible with organic materials, acids, alkali, non- ferrous and ferrous metals Hazardous decomposition products Does not occur under normal temperatures and pressures. SECTION 11. TOXICOLOGICAL INFORMATION Information on toxicological effects Acute toxicity of product is low. The value of DL 50 mg/kg study with animals: oral, rat 1940 oral, mouse 1384 oral, rabbit LOCAL EFFECTS: Eye, mucous membrane and skin irritant. page 4 of 34

5 HEALTH EFFECTS: Moderately toxic by ingestion, slightly toxic by dermal absorption. CARCINOGENICITY: Not Listed by NTP. Not listed by IARC. Not listed by OSHA. MUTAGENICITY: Not Available REPRODUCTIVE TOXICITY REPRODUCTIVE EFFECTS: testing does not appear necessary as will not reach the foetus or the male and female reproductive organs when exposed orally, dermally orby inhalation, as it does not become available systemically. TERATOGENIC EFFECTS: Not Available SENSITIZATION: Not Available SECTION 12. ECOLOGICAL INFORMATION Toxicity Calcium chloride is not classified as hazardous for the environment. Calcium and chloride are normally occurring ions that don t have long term negative effect. Overview of short-term effects on fish Method Results Remarks Reference Pimephales promelas freshwater static Method: other: EPA/600/4-90/027, EPA/600/6-91/003 Lepomis macrochirus freshwater static Method: other: Doudroff et al., (1951) Lepomis macrochirus freshwater static Method: other Gambusia affinis freshwater static Method: other: not mentioned LC50 (96 h): 4630 mg/l LC50 (48 h): > 6560 mg/l LC50 (24 h): > 6660 mg/l 2 (reliable with restrictions) key study experimental result Test material (EC name): (96 h): mg/l 2 (reliable with restrictions) supporting study experimental result Test material (EC name): LC50 (96 h): mg/l LC50 (96 h): mg/l Overview of short-term effects on aquatic invertebrates 2 (reliable with restrictions) supporting study Test material (EC name): 2 (reliable with restrictions) supporting study experimental result Test material (EC name): Mount, D.R., Gulley, D.D., Hockett, J.R., Garrison, T.D. and Evans, J.M. (1997a) Cairns, J., Jr. and Scheier, A. (1959) Trama, F.B. (1954) Method Results Remarks Reference Daphnia magna freshwater static OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) Ceriodaphnia dubia freshwater static Method: other: EPA/600/4-90/027, EPA/600/6-91/003 LC50 (48 h): 2400 mg/l based on: mobility LC50 (48 h): 1830 mg/l based on: mobility 1 (reliable without restriction) key study experimental result Test material (EC name): 2 (reliable with restrictions) supporting study experimental result Test material (EC name): Wallen, I.E., Greer, W.C. and Lasater, R. (1957) de Groot, W.A. and Groeneveld, A.H.C. (1998) Mount, D.R., Gulley, D.D., Hockett, J.R., Garrison, T.D. and Evans, J.M. (1997b) other aquatic worm: Tubifex EC50 (96 h): 780 mg/l 2 (reliable with restrictions) Khangarot, B.S. page 5 of 34

6 tubifex freshwater semi-static Method: other based on: mobility EC50 (48 h): 1830 mg/l based on: mobility EC50 (24 h): 2260 mg/l based on: mobility other aquatic crustacea: Cyclops LC50 (48 h): mg/l abyssorum prealpinus based on: mortality freshwater static Method: other: not mentioned other aquatic crustacea: Eudiaptomus padanus padanus freshwater static Method: other: not mentioned other aquatic crustacea: Daphnia hyalina freshwater static Method: other: not mentioned Caenorhabditis elegans freshwater static Method: other other aquatic crustacea: Nitocra spinipes freshwater static Method: other: not mentioned Daphnia magna freshwater static Method: other: not mentioned Daphnia magna static Method: other: EPA/600/4-90/027, EPA/600/6-91/003 Daphnia magna static Method: other LC50 (48 h): mg/l based on: mortality LC50 (48 h): 8300 mg/l based on: mortality LC50 (24 h): mg/l based on: mortality LC50 (96 h): 1600 mg/l based on: mortality LC50 (48 h): 1285 mg/l based on: mortality LC50 (48 h): 2770 mg/l based on: mobility (48 h): 1062 mg/l based on: mobility supporting study experimental result Test material (EC name): 2 (reliable with restrictions) supporting study experimental result Test material (EC name): 2 (reliable with restrictions) supporting study experimental result Test material (EC name): 2 (reliable with restrictions) supporting study experimental result Test material (EC name): 2 (reliable with restrictions) supporting study experimental result Test material (EC name): 2 (reliable with restrictions) supporting study experimental result Test material (EC name): 2 (reliable with restrictions) supporting study experimental result Test material (EC name): 2 (reliable with restrictions) supporting study experimental result Test material (EC name): 2 (reliable with restrictions) supporting study experimental result Test material (EC name): (1991) Baudouin, M.F. and Scoppa, P. (1974a) Baudouin, M.F. and Scoppa, P. (1974b) Baudouin, M.F. and Scoppa, P. (1974a) Tatara, C.P., Newman, M.C., McCloskey, J.T. and Williams, P.L. (1997) Bengtsson, B.-E. (1978) Biesinger, K.E. and Christensen, G.M. (1972) Mount, D.R., Gulley, D.D., Hockett, J.R., Garrison, T.D. and Evans, J.M. Khangarot, B.S. and Ray, P.K. (1989) Overview of long-term effects on aquatic invertebrates Method Results Remarks Reference Daphnia magna Method: other: not mentioned EC50 (21 d): 610 mg/l based on: reproductive impairment EC16 (21 d): 320 mg/l 2 (reliable with restrictions) key study experimental result Test material (EC name): Biesinger, K.E. and Christensen, G.M. (1972) page 6 of 34

7 based on: reproductive impairment LC50 (21 d): 920 mg/l based on: mortality Overview of effects on algae and aquatic plants Method Results Remarks Reference Selenastrum capricornutum EC50 (72 h): 2900 mg/l (new name: Pseudokirchneriella based on: biomass subcapitata) (algae) EC50 (72 h): > 4000 mg/l OECD Guideline 201 (Alga, based on: growth rate Growth Inhibition Test) EC50 (72 h): mg/l based on: growth rate EC20 (72 h): 1000 mg/l based on: biomass 1 (reliable without restriction) key study experimental result Test material (EC name): de Groot, W.A. (1998) Persistence and degradability Test not available as product is inorganic Bioaccumulative potential Product is not biodegrade or accumulate Mobility in soil In accordance with REACH Annex XI, the study does not need to be conducted as in water; is dissociated into calcium and chloride ions and chloride ions will not adsorb on particulate matter. The calcium ion may bind to particulate matter or may form stable inorganic salts with sulphate and carbonate ions, but calcium is naturally present in soil. Therefore, exposure of the soil compartment is unlikely Results of PBT and vpvb assessment According to Annex XIII of the REACH Regulation 1907/2006/EC inorganic substances do not need to be subjected to a PBT assessment Other adverse effects None identified. SECTION 13. DISPOSAL CONSIDERATIONS Waste treatment methods Observe federal, state, and local regulations when disposing of this substance. DISPOSAL METHOD: Dispose of waste at an appropriate waste disposal facility according to current applicable laws and regulations. FOR LARGE SPILLS: Contain material according to section 6. PRODUCT DISPOSAL: Dispose of at a supervised incineration facility or an appropriate waste disposal facility according to current applicable laws and regulations and product characteristics at time of disposal. EMPTY CONTAINER: Rinse drums with a suitable solvent and steam to remove vapors before disposal or reuse in accordance with applicable regulations SECTION 14. TRANSPORT INFORMATION UN number Not applicable UN proper shipping name Not regulated Transport hazard class(es) Not applicable page 7 of 34

8 14.4. Packing group Not applicable Environmental hazards Not applicable Special precautions for user Not applicable Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15. REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture General principles of protection EH Chemical safety assessment A chemical safety assessment has been performed for according to REACH. SECTION 16. OTHER INFORMATION To the best of our knowledge, this Safety Data Sheet conforms to the requirements of: - Regulation (EC) 1907/2006 of the European Parliament and of the Council of 18 December Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December Commission Regulation (RU) 453/2010 of List of relevant R phrases, hazard statement, safety phrases and precautionary statement: According to Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008: HAZARD STATEMENT: H319: Causes serious eye irritation PRECAUTIONARY STATEMENTS: P 264: Wash hands thoroughly after handling. P 280: Wear protective glasses with splash shields or safety goggles/shield. P305 + P351 + P338: IF IN EYES Rinse eyes cautiously with water for 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P 313 If irritation continued get prompt qualified medical advice / attention. According to Directive 67/548/EEC: Xi Irritant R36 Irritating to eyes S-phrases: (S2) - keep out of the reach of children S22 - do not breathe dust S24 - avoid contact with skin Individuals handling this product should be informed of the recommended safety precautions and should have access to this information. It is the users' responsibility to satisfy themselves as to the suitability and completeness of such information for their own particular use. We do not accept liability for any loss or damage that may occur from the use of this information nor do we offer warranty against patent infringement. ZIRAX LLC reserves the right to refuse shipment of this product to any customer who fails to demonstrate the ability to consistently handle and use it safely and in compliance with all applicable laws, rules and regulations. Such demonstration may require on-site inspection of any or all storage, processing, packaging and other handling systems that come in contact with it. page 8 of 34

9 ANNEX 1 The overview of exposure scenarios of Calcium Chloride Life Cycle Stage(s) covered by the IU Short description of Identified Use Product Category (PC) Manufacture Formulation End Use Industrial Professional Consumer Service Life (for article) Sector of use (SU) Process Category (Proc) Article Category (AC) Environmental Release Category (ERC) ES1: Production of Not applicable X SU8 (SU3) PROC1, PROC2, PROC3, PROC4, PROC6, PROC8a, PROC8b, PROC9, PROC15, PROC26 Not applicable ERC1 ES2: Use of calcium chloride as chemical intermediate Not applicable X SU8, SU9, SU14 (SU1, SU3, SU4, SU5, SU6b) PROC1, PROC2, PROC3, PROC4, PROC6, PROC8a, PROC8b, PROC9, PROC15, PROC22a, PROC22b, PROC22c, PROC23a, PROC23b, PROC23c, PROC26 1, PROC27a 2, PROC27b 3 Not applicable ERC6a 1 No specific assessment has been performed with ECTOC TRA for this PROC, but activities for PROC 26 (handling of solid inorganic substances at abient temperature) are covered within this scenario. 2 No specific assessment has been performed with ECTOC TRA for this PROC, but activities for PROC27a (Production of metal powders (hot processes)) are covered within this scenario by PROC22 and PROC23. 3 No specific assessment has been performed with ECTOC TRA for this PROC, but activities for PROC 27b (Production of metal powders (wet processes)) are covered within this scenario. page 9 of 34

10 Life Cycle Stage(s) covered by the IU Short description of Identified Use Product Category (PC) Manufacture Formulation End Use Industrial Professional Consumer Service Life (for article) Sector of use (SU) Process Category (Proc) Article Category (AC) Environmental Release Category (ERC) ES3: Formulation and/or distribution of Calcium Chloride Not applicable X SU19 (SU1, SU2a, SU2b,SU3, SU4, SU5, SU6b, SU8, SU11, SU12, SU13, SU14, SU15, SU19, SU20, SU0- C23.5/ C23.6) PROC1, PROC2, PROC3, PROC5, PROC6, PROC8a, PROC8b, PROC9, PROC14, PROC15 PROC26 1, PROC27a 2, PROC27b 3 Not applicable ERC2 ES4: Use of calcium chloride as processing aid Not applicable X SU3 (SU1, SU2a, SU2b, SU4, SU5, SU6b, SU8, SU9, SU10, SU11, SU12, SU13, SU14, SU15, SU16, SU17) PROC1, PROC2, PROC3, PROC4, PROC6, PROC7, PROC8a, PROC8b, PROC9, PROC10, PROC13, PROC15, PROC22a, PROC22b, PROC22c, PROC23a, PROC23b, PROC23c, PROC26 1, PROC27a 2, PROC27b 3 Not applicable ERC4 ES5: Industrial outdoor use of end use Not applicable X SU3(SU1, SU2a, SU2b) PROC1, PROC2, PROC5, PROC7, PROC8a, PROC8b, Not applicable ERC4 page 10 of 34

11 Life Cycle Stage(s) covered by the IU Short description of Identified Use Product Category (PC) Manufacture Formulation End Use Industrial Professional Consumer Service Life (for article) Sector of use (SU) Process Category (Proc) Article Category (AC) Environmental Release Category (ERC) PROC9, PROC13, PROC19, PROC26 1, ES6: Professional indoor use of Not applicable X SU22 (SU1, SU10, SU19, SU20, SU0- C23.5/ C23.6) PROC1, PROC2, PROC3, PROC4, PROC5, PROC8a, PROC8b, PROC9 PROC10, PROC11, PROC15, PROC19, PROC20, PROC26 1, Not applicable ERC8a, ERC8d ES7: Professional outdoor use of Not applicable X SU22 (SU1, SU5, SU10, SU13, SU19, SU20, SU0- C23.5/ C23.6) PROC1, PROC2, PROC5, PROC8a, PROC8b, PROC9, PROC10 PROC11, PROC13, PROC19, PROC20 PROC26 1 Not applicable ERC8d ES8: Handling of (aqueous) calcium chloride X X SU3,SU22 (SU1, SU2a,SU4,SU5,S U6b,SU8,SU9, SU10, SU11,SU12,SU1 3, SU14,SU15 SU19, SU20, PROC1, PROC2, PROC3, PROC4, PROC5, PROC6, PROC7, PROC8a, PROC8b, PROC9, PROC10, PROC11, PROC13, PROC14, PROC15 Not applicable ERC1, ERC6a, ERC2, ERC4, ERC8a, ERC8d page 11 of 34

12 Life Cycle Stage(s) covered by the IU Short description of Identified Use Product Category (PC) Manufacture Formulation End Use Industrial Professional Consumer Service Life (for article) Sector of use (SU) Process Category (Proc) Article Category (AC) Environmental Release Category (ERC) SU0- C23.5/ C23.6) ES9: Handling of calcium chloride with low dustiness X X SU3,SU22 (SU1, SU2a,SU4,SU5,S U6b,SU8,SU9, SU10, SU11,SU12,SU1 3, SU14,SU15 SU19, SU20, SU0- C23.5/ C23.6) PROC1, PROC2, PROC3, PROC4, PROC5, PROC6, PROC7, PROC8a, PROC8b, PROC9, PROC10, PROC11, PROC13, PROC14, PROC15, PROC22a, PROC22b, PROC22c, PROC23a, PROC23b, PROC23c Not applicable ERC1, ERC6a, ERC2, ERC4, ERC8a, ERC8d ES10: Use of calcium chloride by consumers PC2, PC5, PC35, PC37, PC4, PC12, PC 27,PC16, PC0- UCN code K35100 X SU21 Not applicable Not applicable ERC8a, ERC8d page 12 of 34

13 9.1. Production of Exposure scenario Production (ES1) SAFETY DATA SHEET Section 1 Exposure Scenario Title Title Production of ; CAS: Use Descriptor Processes, tasks, activities covered Section 2 Field for additional statements to explain scenario if required. Section 2.1 Product characteristics Physical form of product Concentration of substance in product Frequency and duration of use Human factors not influenced by risk management Other Operational Conditions affecting worker exposure Contributing Scenarios Sector of Use: Industrial SU8, (SU3) Process Categories: PROC1, PROC2, PROC3, PROC4, PROC6, PROC8a, PROC8b, PROC9, PROC15,PROC26 Environmental Release Categories: ERC1 Manufacturing of Calcium Chloride, includes recycling/ recovery, material transfers, storage, maintenance and loading (including marine vessel/barge, road/rail car and bulk container), sampling and associated laboratory activities. Operational conditions and risk management measures Control of worker exposure Solid, medium dustiness [OC2] Covers percentage substance in the product up to 100 % (unless stated differently) [G13]. Not applicable Covers daily exposures up to 8 hours (unless stated differently) [G2] Not applicable Assumes use at not more than 20 C above ambient temperature, unless stated differently [G15].; Assumes a good basic standard of occupational hygiene is implemented [G1]. Risk Management Measures Note: list RMM standard phrases according to the control hierarchy indicated in the ECHA template: 1. Technical measures to prevent release, 2. Technical measures to prevent dispersion, 3. Organisational measures, 4. Personal protection. Justification General measures (irritants) [G19]. General exposures [CS1]. With sample collection [CS56]. General exposures [CS1]. Continuous process [CS54]. ; Avoid all skin contact with product, clean up contamination/spills as soon as they occur. Wear gloves (tested to EN374) if hand contamination likely, wash off any skin contamination immediately. Provide basic employee training to prevent / minimise exposures and to report any skin problems that may develop [E3].Use suitable eye protection [PPE26]. Provide a good standard of general ventilation. Natural ventilation is from doors, windows etc. Controlled ventilation means air is supplied or removed by a powered fan. [E1]. Provide a good standard of general ventilation. Natural ventilation is from doors, windows etc. Controlled ventilation means air is supplied or removed by a powered fan. [E1]. measured data, see (PROC1) measured data, see (PROC2) page 13 of 34

14 With sample collection [CS56]. General exposures [CS1]. Use in contained batch processes [CS37]. General exposures (open systems) [CS16]. Batch process [CS55]. With sample collection [CS56]. ; Filling / preparation of equipment from drums or containers. [CS45]. Calendering (including Banburys) [CS64] Process sampling [CS2]. Dedicated facility [CS81] Laboratory activities [CS36]. Process sampling [CS2]. Nondedicated facility [CS82] Drum/batch transfers [CS8]. Transport [CS58]. bulk open loading and unloading [CS503]Nondedicated facility [CS82] bulk closed loading and unloading [CS501]Dedicated facility [CS81] Equipment cleaning and maintenance [CS39]. Nondedicated facility [CS82] Storage [CS67].General exposures (closed systems) [CS15]. Storage [CS67].With sample collection [CS56]. Provide a good standard of general ventilation. Natural ventilation is from doors, windows etc. Controlled ventilation means air is supplied or removed by a powered fan. [E1]. Provide a good standard of general ventilation. Natural ventilation is from doors, windows etc. Controlled ventilation means air is supplied or removed by a powered fan. [E1]. Provide a good standard of general ventilation. Natural ventilation is from doors, windows etc. Controlled ventilation means air is supplied or removed by a powered fan. [E1]. Provide a good standard of general ventilation. Natural ventilation is from doors, windows etc. Controlled ventilation means air is supplied or removed by a powered fan. [E1]. Provide a good standard of general ventilation. Natural ventilation is from doors, windows etc. Controlled ventilation means air is supplied or removed by a powered fan. [E1]. Provide a good standard of general ventilation. Natural ventilation is from doors, windows etc. Controlled ventilation means air is supplied or removed by a powered fan. [E1]. Provide a good standard of general ventilation. Natural ventilation is from doors, windows etc. Controlled ventilation means air is supplied or removed by a powered fan. [E1]. Provide a good standard of general ventilation. Natural ventilation is from doors, windows etc. Controlled ventilation means air is supplied or removed by a powered fan. [E1]. Provide a good standard of general ventilation. Natural ventilation is from doors, windows etc. Controlled ventilation means air is supplied or removed by a powered fan. [E1]. Provide a good standard of general ventilation. Natural ventilation is from doors, windows etc. Controlled ventilation means air is supplied or removed by a powered fan. [E1]. Provide a good standard of general ventilation. Natural ventilation is from doors, windows etc. Controlled ventilation means air is supplied or removed by a powered fan. [E1]. Provide a good standard of general ventilation. Natural ventilation is from doors, windows etc. Controlled ventilation means air is supplied or removed by a powered fan. [E1]. measured data, see (PROC3) measured data, see (PROC4) measured data, see (PROC6) measured data, see (PROC8b) measured data, see (PROC8a) measured data, see (PROC9) measured data, see (PROC15) measured data, see (PROC8a) measured data, see (PROC8b) measured data, see (PROC8a) measured data, see (PROC1) measured data, see (PROC2) page 14 of 34

15 9.2. Use of as chemical intermediate Exposure scenario Use as an intermediate (ES2) Section 1 Title Use Descriptor Exposure Scenario Title Use of Calcium Chloride as chemical intermediate; CAS: Sector of Use: Industrial SU8, SU9, SU14 (SU1, SU3, SU4, SU5, SU6b) Processes, tasks, activities covered Section 2 Field for additional statements to explain scenario if required. Section 2.1 Product characteristics Physical form of product Concentration of substance in product Frequency and duration of use Human factors not influenced by risk management Other Operational Conditions affecting worker exposure Contributing Scenarios Process Categories: PROC1, PROC2, PROC3, PROC4, PROC6, PROC8a, PROC8b, PROC9, PROC15, PROC22a, PROC22b, PROC22c, PROC23a, PROC23b, PROC23c Environmental Release Categories: ERC 6a Use of Calcium Chloride as chemical intermediate. Use as an intermediate. Includes recycling/ recovery, material transfers, storage, maintenance and loading (including marine vessel/barge, road/rail car and bulk container), sampling and associated laboratory activities. Operational conditions and risk management measures Control of worker exposure Solid, medium dustiness [OC2] Covers percentage substance in the product up to 100 % (unless stated differently) [G13]. Not applicable Covers daily exposures up to 8 hours (unless stated differently) [G2] Not applicable Assumes use at not more than 20 C above ambient temperature, unless stated differently [G15].; Assumes a good basic standard of occupational hygiene is implemented [G1]. Risk Management Measures Note: list RMM standard phrases according to the control hierarchy indicated in the ECHA template: 1. Technical measures to prevent release, 2. Technical measures to prevent dispersion, 3. Organisational measures, 4. Personal protection. General measures (irritants) [G19]. General exposures [CS1]. With sample collection [CS56]. General exposures [CS1]. Continuous process [CS54]. With sample collection [CS56]. Avoid all skin contact with product, clean up contamination/spills as soon as they occur. Wear gloves (tested to EN374) if hand contamination likely, wash off any skin contamination immediately. Provide basic employee training to prevent / minimise exposures and to report any skin problems that may develop [E3].Use suitable eye protection [PPE26]. page 15 of 34

16 General exposures [CS1]. Use in contained batch processes [CS37]. General exposures (open systems) [CS16]. Batch process [CS55]. With sample collection [CS56]. Filling / preparation of equipment from drums or containers. [CS45]. SAFETY DATA SHEET Provide a good standard of general ventilation (not less than 3 to 5 air Wear a respirator conforming to EN140 with Type A/P2 filter or better Calendering (including Banburys) [CS64] Provide a good standard of general ventilation (not less than 3 to 5 air Wear a respirator conforming to EN140 with Type A/P2 filter or better Process sampling [CS2]. Dedicated Provide a good standard of general ventilation (not less than 3 to 5 facility [CS81] air Wear a respirator conforming to EN140 with Type A/P2 filter or better Process sampling [CS2]. Non-dedicated facility [CS82]. Avoid carrying out operation for more than 1 hour [OC11] Drum/batch transfers [CS8]. Transport [CS58]. Laboratory activities [CS36]. Bulk open loading and unloading [CS503]. Non-dedicated facility [CS82] bulk closed loading and unloading [CS501]Dedicated facility [CS81] Equipment cleaning and maintenance [CS39]. Non-dedicated facility [CS82]. General exposures (closed systems) [CS15]. Elevated temperature [CS111]. Process temperature melting point Calcium Chloride General exposures (closed systems) [CS15]. Elevated temperature [CS111]. Process temperature > melting point Calcium Chloride Material transfers [CS3]. (open systems) [CS108]. Batch processes at elevated temperatures [CS136]. Process temperature melting point Calcium Chloride Material transfers [CS3]. (open systems) [CS108]. Batch processes at elevated temperatures [CS136]. Process temperature > melting point Calcium Chloride Provide a good standard of general ventilation (not less than 3 to 5 air changes per hour) [E11., or: Wear a respirator conforming to EN140 with Type A/P2 filter or better Provide a good standard of general ventilation (not less than 3 to 5 air Wear a respirator conforming to EN140 with Type A/P2 filter or better Provide a good standard of general ventilation (not less than 3 to 5 air changes per hour) [E11]., or: Wear a respirator conforming to EN140 with Type A/P2 filter or better Drain or remove substance from equipment prior to break-in or maintenance [E81], or: Wear a respirator conforming to EN140 with Type A/P2 filter or better Provide extract ventilation to points where emissions occur [E54], or: Wear a respirator conforming to EN140 with Type A/P2 filter or better Provide a good standard of controlled ventilation (10 to 15 air changes per hour) [E40]., or: Wear a respirator conforming to EN140 with Type A/P2 filter or better page 16 of 34

17 Storage [CS67]. General exposures (closed systems) [CS15]. Storage [CS67]. With sample collection [CS56] Formulation and/or distribution of Exposure scenario Formulation and/or distribution (ES3) Section 1 Title Use Descriptor Processes, tasks, activities covered Section 2 Field for additional statements to explain scenario if required. Section 2.1 Product characteristics Physical form of product Concentration of substance in product Frequency and duration of use Human factors not influenced by risk management Other Operational Conditions affecting worker exposure Contributing Scenarios General measures (irritants) [G19]. Exposure Scenario Title Formulation and/or distribution of Calcium Chloride; CAS: Sector of Use: Industrial SU10 (SU1, SU2, SU3, SU4, SU5, SU6b, SU8, SU11, SU12, SU13, SU14, SU15, SU19, SU20, SU0- C23.5/ C23.6) Process Categories: PROC1, PROC2, PROC3, PROC5, PROC 6, PROC8a, PROC8b, PROC9, PROC14, PROC15 Environmental Release Categories: ERC2 Formulation and distribution, packing and re-packing (including drums and small packs) of the Calcium Chloride and its mixtures in batch or continuous operations, including storage, materials transfers, mixing, large and small scale packing, loading (including marine vessel/barge, rail/road car and IBC loading), maintenance and associated laboratory activities. e.g. production of adsorbents, cosmetics, metals, fertilizers, plant protection, cement, haemodialysis solution and general distributor activities with Calcium Chloride Operational conditions and risk management measures Control of worker exposure Solid, medium dustiness [OC2] Covers percentage substance in the product up to 100 % (unless stated differently) [G13]. Not applicable Covers daily exposures up to 8 hours (unless stated differently) [G2] Not applicable Assumes use at not more than 20 C above ambient temperature, unless stated differently [G15]. Assumes a good basic standard of occupational hygiene is implemented [G1]. Risk Management Measures Note: list RMM standard phrases according to the control hierarchy indicated in the ECHA template: 1. Technical measures to prevent release, 2. Technical measures to prevent dispersion, 3. Organisational measures, 4. Personal protection. Avoid all skin contact with product, clean up contamination/spills as soon as they occur. Wear gloves (tested to EN374) if hand contamination likely, wash off any skin contamination immediately. page 17 of 34

18 General exposures [CS1]. Continuous process [CS54]. General exposures [CS1]. Continuous process [CS54]. With sample collection [CS56]. General exposures [CS1]. Use in contained batch processes [CS37]. Mixing operations (open systems) [CS30]. Calendering (including Banburys) [CS64] Bulk open loading and unloading [CS503]. Non-dedicated facility [CS82] Bulk closed loading and unloading [CS501]. Dedicated facility [CS81] Drum/batch transfers [CS8]. Transport [CS58]. Tabletting, compression, extrusion or pelletisation [CS506]. Laboratory activities [CS36]. Process sampling [CS2]. Dedicated facility [CS81] Process sampling [CS2]. Non-dedicated facility [CS82]. Equipment cleaning and maintenance [CS39]. Non-dedicated facility [CS82]. Storage [CS67]. General exposures (closed systems) [CS15]. Storage [CS67]. General exposures (closed systems) [CS15]. With sample collection [CS56]. Provide basic employee training to prevent / minimise exposures and to report any skin problems that may develop [E3]. Use suitable eye protection [PPE26]. changes per hour) [E11]. or: Wear a respirator conforming to EN140 with Type A/P2 filter or better Avoid carrying out operation for more than 1 hour [OC11]. Drain or remove substance from equipment prior to break-in or maintenance [E81], or: page 18 of 34

19 9.4. Use of as processing aid Exposure scenario Use of as processing aid (ES4) Section 1 Exposure Scenario Title Title Use of Calcium Chloride as processing aid; CAS: Use Descriptor Processes, tasks, activities covered Section 2 Field for additional statements to explain scenario if required. Section 2.1 Product characteristics Physical form of product Concentration of substance in product Frequency and duration of use Sector of Use: Industrial SU3 (SU1, SU2a, SU2b, SU4, SU5, SU6b, SU8, SU9, SU10, SU11, SU12, SU13, SU14, SU15, SU16, SU17) Process Categories: PROC1, PROC2, PROC3, PROC4, PROC6, PROC7, PROC8a, PROC8b, PROC9, PROC10, PROC13, PROC15, PROC22a, PROC22b PROC22c, PROC23a, PROC23b, PROC23c Environmental Release Categories: ERC 4 Use of Calcium Chloride as processing aid. Use as a process chemical or extraction agent. Includes recycling/ recovery, material transfers, storage, maintenance and loading (including marine vessel/barge, road/rail car and bulk container), sampling and associated laboratory activities. E.g. functions as adsorbent, coagulant, emulsion breaker, alginates, extraction agent, completion fluid, heat transfer fluid, water treatment chemical or use within the paper industry for example as antistatic Operational conditions and risk management measures Control of worker exposure Solid, medium dustiness [OC2]. Covers percentage substance in the product up to 100 % (unless stated differently) [G13]. Not applicable Covers daily exposures up to 8 hours (unless stated differently) [G2] Human factors not influenced by risk management Other Operational Conditions affecting worker exposure Contributing Scenarios General measures (irritants) [G19]. General exposures [CS1]. Continuous process [CS54]. Not applicable Assumes use at not more than 20 C above ambient temperature, unless stated differently [G15].; Assumes a good basic standard of occupational hygiene is implemented [G1]. Risk Management Measures Note: list RMM standard phrases according to the control hierarchy indicated in the ECHA template: 1. Technical measures to prevent release, 2. Technical measures to prevent dispersion, 3. Organisational measures, 4. Personal protection. Avoid all skin contact with product, clean up contamination/spills as soon as they occur. Wear gloves (tested to EN374) if hand contamination likely, wash off any skin contamination immediately. Provide basic employee training to prevent / minimise exposures and to report any skin problems that may develop [E3]. Use suitable eye protection [PPE26]. page 19 of 34

20 General exposures [CS1]. Continuous process [CS54]. With sample collection [CS56]. General exposures [CS1]. Use in contained batch processes [CS37]. General exposures (open systems) [CS16]. Batch process [CS55]. With sample collection [CS56]. Filling / preparation of equipment from drums or containers. [CS45]. Calendering (including Banburys) [CS64] Spraying [CS10]. Bulk open loading and unloading [CS503]. Non-dedicated facility [CS82] Bulk closed loading and unloading [CS501]. Dedicated facility [CS81] Drum/batch transfers [CS8]. Transport [CS58]. Rolling, Brushing [CS51]. Dipping, immersion and pouring [CS4]. Laboratory activities [CS36]. Equipment cleaning and maintenance [CS39]. Non-dedicated facility [CS82] Process sampling [CS2]. Dedicated facility [CS81] Process sampling [CS2]. Non-dedicated facility [CS82] General exposures (closed systems) [CS15]. Elevated temperature [CS111]. Process temperature melting point Calcium Chloride Minimise exposure by partial enclosure of the operation or equipment and provide extract ventilation at openings [E60]. or: Drain or remove substance from equipment prior to break-in or maintenance [E81], or: Avoid carrying out operation for more than 4 hours [OC12]. page 20 of 34

21 General exposures (closed systems) [CS15]. Elevated temperature [CS111]. Process temperature > melting point Calcium Chloride Material transfers [CS3]. (open systems) [CS108]. Batch processes at elevated temperatures [CS136]. Process temperature melting point Calcium Chloride Material transfers [CS3]. (open systems) [CS108]. Batch processes at elevated temperatures [CS136]. Process temperature > melting point Calcium Chloride Storage [CS67]. General exposures (closed systems) [CS15]. Provide a good standard of controlled ventilation (10 to 15 air changes per hour) [E40], or: Provide a good standard of controlled ventilation (10 to 15 air changes per hour) [E40], or: 9.5. Industrial outdoor use of - end use Exposure scenario Industrial outdoor use (ES5) Section 1 Exposure Scenario Title Title ES5: Industrial outdoor use of Calcium Chloride; CAS: Use Descriptor Sector of Use: Industrial SU3 (SU1, SU2) Process Categories: PROC1, PROC2, PROC5, PROC7, PROC8a, PROC8b, PROC9, PROC13, PROC19 Environmental Release Categories: ERC4 Processes, tasks, activities covered Section 2 Field for additional statements to explain scenario if required. Section 2.1 Product characteristics Physical form of product Concentration of substance in product Frequency and duration of use Human factors not influenced by risk management Industrial outdoor use of Calcium Chloride. Covers the end use of Calcium chloride either pure or in formulation by spreading, spraying and pouring. Including storage, materials transfers, mixing, loading and maintenance. E.g. the use of dust suppression - and de-icingmixtures. Operational conditions and risk management measures Control of worker exposure Solid, medium dustiness [OC2]. Covers percentage substance in the product up to 100 % (unless stated differently) [G13]. Not applicable Covers daily exposures up to 8 hours (unless stated differently) [G2] Not applicable page 21 of 34

22 Other Operational Conditions affecting worker exposure Contributing Scenarios Assumes use at not more than 20 C above ambient temperature, unless stated differently [G15]. Assumes a good basic standard of occupational hygiene is implemented [G1]. Outdoor [OC9]. Risk Management Measures Note: list RMM standard phrases according to the control hierarchy indicated in the ECHA template: 1. Technical measures to prevent release, 2. Technical measures to prevent dispersion, 3. Organisational measures, 4. Personal protection. General measures (irritants) [G19]. Mixing operations (open systems) [CS30]. Bulk open loading and unloading [CS503]. Non-dedicated facility [CS82] Bulk closed loading and unloading [CS501]. Dedicated facility [CS81] Drum/batch transfers [CS8]. Transport [CS58]. Spraying [CS10]. Spraying [CS10]. Spreading Large surfaces [CS46]. Mixing operations (open systems) [CS30]. Manual [CS34]. Spreading Manual [CS34]. Equipment cleaning and maintenance [CS39]. Non-dedicated facility [CS82] Storage [CS67]. General exposures (closed systems) [CS15]. Storage [CS67]. General exposures (closed systems) [CS15]. With sample collection [CS56]. Section 2.2 Product characteristics Avoid all skin contact with product, clean up contamination/spills as soon as they occur. Wear gloves (tested to EN374) if hand contamination likely, wash off any skin contamination immediately. Provide basic employee training to prevent / minimise exposures and to report any skin problems that may develop [E3]. Use suitable eye protection [PPE26]. Minimise exposure by partial enclosure of the operation or equipment and provide extract ventilation at openings [E60]. or: Avoid carrying out operation for more than 1 hour [OC11], or: Control of environmental exposure Substance is a unique structure [PrC1]. Inorganic substance. page 22 of 34

23 Operational conditions Contributing scenario SAFETY DATA SHEET Annual tonnage of road salt 1.5 tonnes/km Fraction of CaCl2 in road salt 0.06 Annual tonnage of CaCl tonnes/km Frequency and duration of use Type of release Dispersive use [FD3]. Emission Days (days/year) [FD4]: 25 Environmental factors not influenced by risk management Spreading width (m): 10 Other Operational Conditions of Use in open systems. use affecting environmental exposure Release fraction to air from process 0 (initial release prior to RMM) [OOC4]: Release fraction to wastewater from process (release after RMMs are applied): Release fraction to soil from process (initial release prior to RMM) [OOC6]: Conditions and measures related to municipal sewage treatment plant Other environmental control measures additional to above Outdoor use [OOC1]. De-icing agent, application as a mixture of 70% NaCl and 30% of a 20% solution of CaCl2 0 1 Not applicable as there is no release to wastewater [STP1]. Avoid spilling salt directly onto plants. Contributing scenario De-icing agent, application as liquid CaCl2 brine (max. 35% solution) Annual tonnage of road salt 0.8 tonnes/km Fraction of CaCl2 in road salt 0.35 Annual tonnage of CaCl tonnes/km Frequency and duration of use Type of release Dispersive use [FD3]. Emission Days (days/year) [FD4]: 25 Environmental factors not influenced by risk management Spreading width (m): 10 Other Operational Conditions of Use in open systems. use affecting environmental exposure Release fraction to air from process 0 (initial release prior to RMM) [OOC4]: Release fraction to wastewater from process (release after RMMs are applied): Release fraction to soil from process (initial release prior to RMM) [OOC6]: Conditions and measures related to municipal sewage treatment 0 1 Not applicable as there is no release to wastewater [STP1]. page 23 of 34

24 plant Other environmental control measures additional to above Avoid spilling salt directly onto plants. Contributing scenario De-icing agent, application as solid CaCl2 (up to 100%) Annual tonnage of road salt 0.25 tonnes/km Fraction of CaCl2 in road salt 1 Annual tonnage of CaCl tonnes/km Frequency and duration of use Type of release Dispersive use [FD3]. Emission Days (days/year) [FD4]: 25 Environmental factors not influenced by risk management Spreading width (m): 10 Other Operational Conditions of Use in open systems. use affecting environmental exposure Release fraction to air from process 0 (initial release prior to RMM) [OOC4]: Release fraction to wastewater from process (release after RMMs are applied): Release fraction to soil from process (initial release prior to RMM) [OOC6]: Conditions and measures related to municipal sewage treatment plant Other environmental control measures additional to above 0 1 Not applicable as there is no release to wastewater [STP1]. Avoid spilling salt directly onto plants. Contributing scenario Dust suppressor, application as solid CaCl2 (up to 80%) Annual tonnage of road salt 3 tonnes/km Fraction of CaCl2 in road salt 0.8 Annual tonnage of CaCl2 2.4 tonnes/km Frequency and duration of use Type of release Dispersive use [FD3]. Emission Days (days/year) [FD4]: 3 Environmental factors not influenced by risk management Spreading width (m): 10 Other Operational Conditions of Use in open systems. use affecting environmental exposure Release fraction to air from process 0 (initial release prior to RMM) [OOC4]: Release fraction to wastewater from process (release after RMMs are applied): Release fraction to soil from process (initial release prior to RMM) [OOC6]: 0 1 page 24 of 34

25 Conditions and measures related to municipal sewage treatment plant Other environmental control measures additional to above SAFETY DATA SHEET Not applicable as there is no release to wastewater [STP1]. Avoid spilling salt directly onto plants. Contributing scenario Dust suppressor, application as CaCl2 solution (up to 37%) Annual tonnage of road salt 3 tonnes/km Fraction of CaCl2 in road salt 0.37 Annual tonnage of CaCl tonnes/km Frequency and duration of use Type of release Dispersive use [FD3]. Emission Days (days/year) [FD4]: 3 Environmental factors not influenced by risk management Spreading width (m): 10 Other Operational Conditions of Use in open systems. use affecting environmental exposure Release fraction to air from process 0 (initial release prior to RMM) [OOC4]: Release fraction to wastewater from process (release after RMMs are applied): Release fraction to soil from process (initial release prior to RMM) [OOC6]: Conditions and measures related to municipal sewage treatment plant Other environmental control measures additional to above 0 1 Not applicable as there is no release to wastewater [STP1]. Avoid spilling salt directly onto plants Professional (indoor) use of Exposure scenario Professional indoor use (ES6) Section 1 Exposure Scenario Title Title ES6: Professional use of Calcium Chloride; CAS: Use Descriptor Processes, tasks, activities covered Section 2 Field for additional statements to explain scenario if required. Sector of Use: professional SU22 (SU1, SU10, SU19, SU20, SU0- C23.5/ C23.6) Process Categories: PROC1, PROC2, PROC 3, PROC4, PROC5, PROC8a, PROC8b, PROC9, PROC10, PROC11, PROC15, PROC19, PROC20 Environmental Release Categories: ERC 8a, 8d Professional use of CaCl2. Covers the end use of Calcium chloride either pure or in formulation including pouring/unloading from drums or containers; and exposures during mixing/diluting in the preparatory phase and by spraying, brushing, dipping, wiping automated and by hand. E.g. the use of, washing and cleaning products or use as heat transfer fluid. Operational conditions and risk management measures page 25 of 34