Safety Data Sheet. Classified as hazardous

Transcription

1 Page: 1 1. Identification GHS Product Identifier Company Name Address TANKMASTER KIDDE AUSTRALIA (ABN ) Level 1/ Wellington Road Mulgrave Telephone/Fax Number Emergency phone number Recommended use the chemical and restrictions on use 2. Hazard Identification Classification the substance or mixture Victoria 3170 Australia Tel: Fire fighting foam concentrate Classified as Hazardous according to the Globally Harmonised System Classification and labelling Chemicals (GHS) including Work, Health and Safety regulations, Australia. Not classified as Dangerous Goods according to the Australian Code for the Transport Dangerous Goods by Road and Rail. (7th edition) Signal Word (s) Hazard Statement (s) Pictogram (s) Sensitization - Skin: Category 1 Warning H317 May cause an allergic skin reaction. Exclamation mark Precautionary statement Prevention Precautionary statement Response Precautionary statement Disposal Supplemental information P21 Avoid breathing mist/vapours/spray. P272 Contaminated work clothing should not be allowed out the workplace. P280 Wear protective gloves/protective clothing/eye protection/face protection. P302+P352 IF ON SKIN: Wash with plenty water. P333+P313 If skin irritation and rash occurs: Get medical advice/attention. P33 Wash contaminated clothing before reuse. P501 Dispose contents/container to an approved waste disposal plant. The information under this heading is not mandatory under WHS Regulations. It is provided as information on other GHS hazard classes and categories and/or environmental hazards that are outside the scope the WHS Regulations. GHS classification: Skin Corrosion/irritation, Category 3; Hazard statement: H Composition/information on ingredients Ingredients Name CAS Proportion Hexylene glycol <5 % Ferrous sulphate <5 % Hexahydro-1,3,5-tris(hy <1 % droxyethyl)-triazine Zinc oxide <1 % Ingredients determined not to be hazardous, including water. Balance

2 Page: 2 4. First-aid measures Inhalation Ingestion Skin Eye contact First Aid Facilities Advice to Doctor Other Information 5. Fire-fighting measures Suitable extinguishing media Unsuitable Extinguishing Media Hazards from Combustion Products Specific hazards arising from the chemical Decomposition Temp. Precautions in connection with Fire If inhaled, remove affected person from contaminated area. Keep at rest until recovered. If symptoms develop and/or persist seek medical attention. Do not induce vomiting. Wash out mouth thoroughly with water. Seek immediate medical attention. Remove all contaminated clothing immediately. Wash affected area thoroughly with soap and water. Wash contaminated clothing before reuse or discard. Seek medical attention. If in eyes, hold eyelids apart and flush the eyes continuously with running water. Remove contact lenses. Continue flushing for several minutes until all contaminants are washed out completely. If symptoms develop seek medical attention. Eye wash, safety shower and normal washroom facilities. Treat symptomatically. For advice in an emergency, contact a Poisons Information Centre (Phone Australia ) or a doctor at once. No specific measures are required as this product is a fire extinguishing medium. Under fire conditions this product may emit toxic and/or irritating fumes and gases including carbon monoxide, carbon dioxide, chlorine, oxides nitrogen, sulphur and metal. Product is an extinguishing medium. It does not burn or support combustion.. Accidental release measures Personal precautions, protective equipment and emergency procedures 7. Handling and storage Precautions for Safe Handling Conditions for safe storage, including any incompatabilities Storage Temperatures 8. Exposure controls/personal protection Occupational exposure limit values Fire fighters should wear Self-Contained Breathing Apparatus (SCBA) operated in positive pressure mode and full protective clothing to prevent exposure to vapours or fumes. Wear appropriate personal protective equipment and clothing to prevent exposure. Increase ventilation. Evacuate all unprotected personnel. If possible contain the spill. As a water based product, if spilt on electrical equipment the product will cause short-circuits. Place inert absorbent, non-combustible material onto spillage. Use clean tools to collect the material and place into suitable labelled containers for subsequent recycling or disposal. Dispose waste according to the applicable local and national regulations. If contamination sewers or waterways occurs inform the local water and waste management authorities in accordance with local regulations. Avoid inhalation vapours and mists, and skin or eye contact. Use only in a well ventilated area. Keep containers sealed when not in use. Prevent the build up mists or vapours in the work atmosphere. Maintain high standards personal hygiene by washing hands prior to eating, drinking, smoking or using toilet facilities. Store in a cool, dry, well-ventilated area, out direct sunlight. Store in suitable, labelled containers. Protect from freezing. Keep containers tightly closed. Store away from incompatible materials. Ensure that storage conditions comply with applicable local and national regulations. Below 40 C No exposure value assigned for this material by Safe Work, Australia. However, the available exposure limits for ingredients are listed below:

3 Page: 3 Biological Limit Values Appropriate engineering controls Respiratory Protection Eye Protection Hand Protection Body Protection 9. Physical and chemical properties Appearance Colour Odour Decomposition Temperature Melting Point Boiling Point Solubility in Water Specific Gravity ph Vapour Pressure Vapour Density (Air=1) Evaporation Rate Odour Threshold Safe Work, Australia Exposure Standards: Substance TWA STEL NOTICES ppm mg/m³ ppm mg/m³ Hexylene glycol Peak Limitation Zinc oxide fume Iron salts, soluble (as Fe) TWA (Time Weighted Average): The average airborne concentration a particular substance when calculated over a normal eight-hour working day, for a five-day week. STEL (Short Term Exposure Limit): The average airborne concentration over a 15 minute period which should not be exceeded at any time during a normal eight-hour workday. Peak Limitation: A ceiling concentration which should not be exceeded over a measurement period which should be as short as possible but not exceeding 15 minutes. No biological limits allocated. This substance is hazardous and should be used with a local exhaust ventilation system, drawing vapours away from workers' breathing zone. If the engineering controls are not sufficient to maintain concentrations vapours/mists below the exposure standards, suitable respiratory protection must be worn. If engineering controls are not effective in controlling airborne exposure then an approved respirator with a replaceable vapour filter should be used. Reference should be made to Australian/New Zealand Standards AS/NZS 1715, Selection, Use and Maintenance Respiratory Protective Devices; and AS/NZS 171, Respiratory Protective Devices, in order to make any necessary changes for individual circumstances. Safety glasses with side shields or chemical goggles should be worn. Final choice appropriate eye/face protection will vary according to individual circumstances. Eye protection devices should conform with Australian/New Zealand Standard AS/NZS Eye Protectors for Industrial Applications. Wear gloves impervious material such as butyl rubber. Final choice appropriate gloves will vary according to individual circumstances i.e. methods handling or according to risk assessments undertaken. Reference should be made to AS/NZS 211.1: Occupational protective gloves - Selection, use and maintenance. Suitable protective work wear, e.g. cotton overalls buttoned at neck and wrist is recommended. Chemical resistant apron is recommended where large quantities are handled. Dark brown liquid Dark brown Organic -15 C 100 C (70mmHg) Miscible in all proportions (20 C)

4 Page: 4 Viscosity Partition Coefficient: n-octanol/water Flash Point Flammability Auto-Ignition Temperature Flammable Limits - Lower Flammable Limits - Upper 30cSt (20 C) >100 C 10. Stability and reactivity Reactivity Chemical Stability Conditions to Avoid Incompatible Materials Hazardous Decomposition Products Hazardous Polymerization Not flammable 11. Toxicological Information Toxicology Information Acute Toxicity - Oral Ingestion Inhalation Skin Eye Respiratory sensitisation Skin Sensitisation Germ cell mutagenicity Carcinogenicity Reproductive Toxicity STOT-single exposure STOT-repeated exposure Aspiration Hazard 12. Ecological information Ecotoxicity Reacts with incompatible materials. Stable under normal conditions storage and handling. Heat. Protect from freezing. Strong oxidising agents. Water reactive materials. Alkali metals. Thermal decomposition may result in the release toxic and/or irritating fumes, smoke and gases including: carbon monoxide, carbon dioxide, chlorine, oxides nitrogen, sulphur and metal. Will not occur. The available toxicity data for ingredients is given below. Ferrous sulphate LD50(rat): 319mg/kg Hexylene glycol LD50(rat): 4.79g/kg Ingestion this product may irritate the gastric tract causing nausea and vomiting. May cause discomfort if swallowed. Inhalation product vapours may cause irritation the nose, throat and respiratory system. Causes mild skin irritation. Skin contact will cause redness, itching and swelling. Repeated exposure may cause skin dryness and cracking and may lead to dermatitis. May cause an allergic skin reaction. May be irritating to eyes. The symptoms may include redness, itching and tearing. Not expected to be a respiratory sensitiser. May cause an allergic skin reaction. Not considered to be a mutagenic hazard. Not considered to be a carcinogenic hazard. Not considered to be toxic to reproduction. Not expected to cause toxicity to a specific target organ. Not expected to cause toxicity to a specific target organ. Not expected to be an aspiration hazard. The available ecological data is given below.

5 Page: 5 Persistence and degradability Mobility Bioaccumulative Potential Other Adverse Effects Environmental Protection Acute Toxicity - Fish 13. Disposal considerations Disposal Considerations 14. Transport information Transport Information IMDG Marine pollutant 15. Regulatory information Regulatory Information Poisons Schedule AICS (Australia) 1. Other Information Date preparation or last revision SDS Literature References The product is biodegradable. COD: 0.5 gg-1 The product is water soluble and may spread in water systems. The product is not expected to bioaccumulate. Prevent this material entering waterways, drains and sewers. LC50 (Rainbow trout, donaldson trout, Oncorhynhus mykiss): >10,000 ppm/24h LC50 (Rainbow trout, donaldson trout, Oncorhynhus mykiss): >10,000 ppm/3h LC50 (Rainbow trout, donaldson trout, Oncorhynhus mykiss): >10,000 ppm/48h LC50 (Rainbow trout, donaldson trout, Oncorhynhus mykiss): >10,000 ppm/h LC50 (Rainbow trout, donaldson trout, Oncorhynhus mykiss): 5,400 ppm/72h LC50 (Rainbow trout, donaldson trout, Oncorhynhus mykiss): 4,200 ppm/9h Dispose waste according to applicable local and national regulations. Road and Rail Transport: Not classified as Dangerous Goods according to the Australian Code for the Transport Dangerous Goods by Road and Rail (ADG Code) (7th edition). Marine Transport (IMO/IMDG): Not classified as Dangerous Goods by the criteria the International Maritime Dangerous Goods Code (IMDG Code) for transport by sea. Air Transport (ICAO/IATA): Not classified as Dangerous Goods by the criteria the International Air Transport Association (IATA) Dangerous Goods Regulations for transport by air. No Classified as Hazardous according to the Globally Harmonised System Classification and labelling Chemicals (GHS) including Work, Health and Safety regulations, Australia. Not classified as a Scheduled Poison according to the Standard for the Uniform Scheduling Medicines and Poisons (SUSMP). Not Scheduled The listed chemicals are included in Australian Inventory Chemical Substances (AICS) or otherwise notified under NICNAS. SDS reviewed: September 2014 Supersedes: February 2010 Preparation Safety Data Sheets for Hazardous Chemicals Code Practice. Standard for the Uniform Scheduling Medicines and Poisons. Australian Code for the Transport Dangerous Goods by Road & Rail. Model Work Health and Safety Regulations, Schedule 10: Prohibited carcinogens, restricted carcinogens and restricted hazardous chemicals. Workplace exposure standards for airborne contaminants, Safe work Australia. American Conference Industrial Hygienists (ACGIH). Globally Harmonised System classification and labelling chemicals....end Of MSDS... Copyright ACOHS Pty Ltd

6 Page: Copyright in the source code the HTML, PDF, XML, XFO and any other electronic files rendered by an Infosafe system for Infosafe MSDS displayed is the intellectual property Acohs Pty Ltd. Copyright in the layout, presentation and appearance each Infosafe MSDS displayed is the intellectual property Acohs Pty Ltd. The compilation MSDS's displayed is the intellectual property Acohs Pty Ltd. Copying any MSDS displayed is permitted for personal use only and otherwise is not permitted. In particular the MSDS's displayed cannot be copied for the purpose sale or licence or for inclusion as part a collection MSDS without the express written consent Acohs Pty Ltd.