Green Chemical Products
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1 Green Chemical Products Presented by: Shawn Lu Date Here: Jun Weatherford. All rights reserved. 1
2 Content Definition of Green Drilling Fluids Drilling Waste Management GreenWERCS MicroTox Examples 2014 Weatherford. All rights reserved. 2
3 GREEN vs. GREENER? 1. Prevention It s better to prevent waste than to treat or clean up waste afterwards. 2. Atom Economy Design synthetic methods to maximize the incorporation of all materials used in the process into the final product. 3. Less Hazardous Chemical Syntheses Design synthetic methods to use and generate substances that minimize toxicity to human health and the environment. 4. Designing Safer Chemicals Design chemical products to affect their desired function while minimizing their toxicity. 5. Safer Solvents and Auxiliaries Minimize the use of auxiliary substances wherever possible make them innocuous when used. 6. Design for Energy Efficiency Minimize the energy requirements of chemical processes and conduct synthetic methods at ambient temperature and pressure if possible. 7. Use of Renewable Feedstocks Use renewable raw material or feedstock rather whenever practicable. 8. Reduce Derivatives Minimize or avoid unnecessary derivatization if possible, which requires additional reagents and generate waste. 9. Catalysis Catalytic reagents are superior to stoichiometric reagents. 10. Design for Degradation Design chemical products so they break down into innocuous products that do not persist in the environment. 11. Real-time Analysis for Pollution Prevention Develop analytical methodologies needed to allow for real-time, in-process monitoring and control prior to the formation of hazardous substances. 12.Inherently Safer Chemistry for Accident Prevention Choose substances and the form of a substance used in a chemical process to minimize the potential for chemical accidents, including releases, explosions, and fires Weatherford. All rights reserved. 3
4 Cradle to the Grave The full life circle of chemicals needs to be considered. Chemicals Environment Applications Hydrocarbon recovery 2014 Weatherford. All rights reserved. 4
5 Drilling Waste Management The optimization of cost, performance vs. environmental profile is important. Performance Green? Cost Performance Green? Cost 2014 Weatherford. All rights reserved. 5
6 Weatherford Drilling Fluid Systems Aqueous (WBM) WEL-DRILL KCL PHPA WEL-DRILL CPG Cloud Point Glycol WEL-DRILL HP High Performance Water Based Mud WEL-DRILL Plus High Temperature High Pressure WEL-DRILL S Silicate Systems WEL-DRILL MMO Mixed Metal Oxide WEL-DRILL F Formate Systems WEL-DRILL RDF Reservoir Drilling Fluid WEL-DRILL C Cationic systems 2014 Weatherford. All rights reserved. 6 6
7 Weatherford Drilling Fluid Systems Non Aqueous (OBM) WEL-VERT Invert emulsion for use in wide range of base fluids WEL-VERT D Optimized diesel based system WEL-VERT FR Flat Rheology System WEL-VERT Plus High Temperature High Pressure WEL-VERT RDF Reservoir Drilling Fluid 2014 Weatherford. All rights reserved. 7 7
8 Weatherford Drilling Fluid - Air and Foam Systems Water Based: DuraFoam Economical non recyclable KleanFoam Recyclable (successfully used in over 200 wells TransFoam EnviroFoam Recyclable, unique ph control Completely biodegradable Oil Foam Based: OleoFoam EF OleoFoam HT OleoFoam C HF 100 base Crude, Diesel or Synthetic Condensate Base 2014 Weatherford. All rights reserved. 8 8
9 Weatherford Solids Control and Drilling Waste Management Full range of Solids Control and Drilling Waste Services Solids control systems: Shakers, Centrifuges, Mud Cleaners, hydrocyclones etc. Drilling waste management solutions Transport, treatment and disposal Filtration services DE and Cartridge Fluid system design and manufacture Total Site Management Designs Management 2014 Weatherford. All rights reserved. 9 9
10 Weatherford Engineered Fluids Management SM Engineered Fluids Management SM (EFM SM ) is a holistic based engineering approach to providing drilling fluid and waste management services. EFM SM solutions utilize tried and trusted project management, environmental management, and site management techniques to combine fluids, engineering, solids control and waste management services to provide a seamless value adding service which delivers improved environmental performance Weatherford. All rights reserved. 10
11 GreenWERCS A scoring system based on the potential impact on human health and the environment. Have a unique/systematic scale to evaluate/compare all the products in a standard/customized framework Weatherford. All rights reserved. 11
12 GreenWERCS - Criteria Persistent, bioaccumulative and toxic substances (PBTs) Carcinogens, mutagens or reproductive toxicants (CMRs) Probable endocrine disrupters Potential hazardous waste Standard and user defined criteria Weatherford. All rights reserved. 12
13 Standard criteria Weatherford. All rights reserved. 13
14 Weatherford Green Analyzer NA/EU 2014 Weatherford. All rights reserved. 14
15 Scores of Weatherford Drilling Fluid Additives 2014 Weatherford. All rights reserved. 15
16 Drilling Fluid Products Generic Analysis The red component in DF will determine the overall profile. O/SBM WBM - RDF Diesel Base oil Organic clay inhibitors Emulsifiers/wetting agent Rheology modifiers Scavengers Brines Lubricants Fluid loss additives Weighting agent Viscosifiers Synthetic polymers Weighting agent Viscosifiers Biopolymer Starches 2014 Weatherford. All rights reserved. 16
17 Drilling Waste Management Drilling Cuttings In addition to drilling fluid additives, there are additional residual on drilling cuttings. O/SBM WBM - RDF PAH aromatics Base oil content PAH aromatics Scavengers - reacted products 2014 Weatherford. All rights reserved. 17
18 Microtox Toxicity Test The Microtox toxicity test system is the industry standard for rapid toxicity screening and analysis. Microtox rapid toxicity detection is an in vitro test system that uses bioluminescent bacteria for the detection of toxicity in water and is used as a screening system to detect the relative toxicity of a sample. 18 The simplicity of the test is that a measurable activity of the living luminescent bacteria is the production of light. If the bacteria s metabolism slows or the bacteria die, the quantity of light lessens or ceases. This phenomena allows us to measure a 50% effective concentration (EC50) of a sample, which is a 50% reduction in bioluminescence Weatherford. All rights reserved. 18
19 Microtox Toxicity Test Test EC20 EC50 PASS/FAIL MTX Threshold ClayGuard MTX - 68 L/m3 Third Party Lab Results from 10/12/ L/m3 68 L/m3 N/A 23% 85% PASS Test EC20 EC50 PASS/FAIL MTX - Threshold ClayGuard 16.4L/m L/m3 N/A Test EC20 EC50 PASS/FAIL MTX - Threshold CC L/m L/m3 N/A 2014 Weatherford. All rights reserved. 19
20 Drilling Waste Management Drilling Cuttings Good practice plus green additive will minimize the overall environmental impact of DWM process. Separation Disposal/treatment Go Green Green? Weatherford. All rights reserved. 20
21 Weatherford systems 1 High Performance Water Based Drilling Fluids Green additives Excellent lubrication ROP enhancement Shale Inhibition 2014 Weatherford. All rights reserved. 21
22 Weatherford systems 2. SafeBrine Physical Properties Property Observation Comment Density Up to 23.6 ppg ppg Commercially available Solubility in water Easy to dilute Reasonable weigh-up cut-back window Color Colorless Turbidity 1.44 NTU ppg brine Corrosivity Mild to skin Quite easy to handle Toxicity PLONOR Listed 6/12/2014 Weatherford International Weatherford. All rights reserved. 22
23 Goal: Greener life circle Chemicals Environment Applications Hydrocarbon recovery Weatherford. All rights reserved. 23
24 THANK YOU QUESTIONS 2014 Weatherford. All rights reserved. 24
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