T01235 IN LINE REFILL TABLET BLUE 12/CS Version 1.0 Revision Date 05/30/2015 Print Date 06/05/2015

Transcription

1 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Material name : Material number : Manufacturer or supplier's details Company : Zep Inc. Address : 1310 Seaboard Industrial Blvd., NW Atlanta, GA Telephone : Emergency telephone numbers For SDS Information : Compliance Services For a Medical Emergency : Toll Free - All Calls Recorded For a Transportation Emergency : CHEMTREC: All Calls Recorded. In the District of Columbia SECTION 2. HAZARDS IDENTIFICATION Emergency Overview Appearance Colour Odour solid blue pleasant GHS Classification Serious eye damage : Category 1 Skin irritation : Category 2 GHS Label element Hazard pictograms : Signal word Hazard statements Precautionary statements : Danger : H318 Causes serious eye damage. H315 Causes skin irritation. : Prevention: P280 Wear protective gloves/ eye protection/ face protection. P264 Wash.? thoroughly after handling. Response: P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P332 + P313 If skin irritation occurs: Get medical advice/ attention. P302 + P352 IF ON SKIN: Wash with plenty of water/.?. 1 / 9

2 Storage: P405 Store locked up. Disposal: P501 Dispose of contents/container in accordance with local regulation. Potential Health Effects Carcinogenicity: IARC ACGIH OSHA NTP No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH. No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous components Chemical Name CAS-No. Concentration [%] Amides, coco, N-(hydroxyethyl) >= 10 - <= 25 Fatty acids, tallow, sodium salts >= 10 - <= 25 Fatty acids, coco, sodium salts >= 10 - <= 25 sodium dodecylbenzenesulfonate >= 10 - <= 25 (1-Hydroxyethylidene)bis-phosphonic Acid tetrasodium salt >= <= 10 SECTION 4. FIRST AID MEASURES General advice If inhaled In case of skin contact In case of eye contact If swallowed : Move out of dangerous area. Show this safety data sheet to the doctor in attendance. Do not leave the victim unattended. : Move to fresh air. If symptoms persist, call a physician. : If skin irritation persists, call a physician. Immediately flush skin with large amounts of water. : Protect unharmed eye. Remove contact lenses. Flush eyes with water as a precaution. If eye irritation persists, consult a specialist. : Drink plenty of water. Rinse mouth with water. 2 / 9

3 Do not induce vomiting. Drink water. Call physician immediately. SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media Unsuitable extinguishing media Specific hazards during firefighting : Carbon dioxide (CO2) Water spray Alcohol-resistant foam : none : Do not allow run-off from fire fighting to enter drains or water courses. Hazardous combustion products Specific extinguishing methods Further information Special protective equipment for firefighters : Carbon dioxide (CO2) Carbon monoxide : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. : Collect contaminated fire extinguishing water separately. This must not be discharged into drains. : Use personal protective equipment. Wear self-contained breathing apparatus for firefighting if necessary. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and materials for containment and cleaning up : Material can create slippery conditions. Use personal protective equipment. : Do not allow uncontrolled discharge of product into the environment. : Suitable material for picking up SECTION 7. HANDLING AND STORAGE Advice on safe handling Conditions for safe storage Materials to avoid : Use only with adequate ventilation. Avoid contact with skin and eyes. : Keep containers tightly closed in a dry, cool and wellventilated place. : Do not store near acids. 3 / 9

4 SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Contains no substances with occupational exposure limit values. Personal protective equipment Respiratory protection : In case of insufficient ventilation, wear suitable respiratory equipment. Hand protection Remarks Eye protection Skin and body protection Hygiene measures : The suitability for a specific workplace should be discussed with the producers of the protective gloves. : Safety glasses : Choose body protection according to the amount and concentration of the dangerous substance at the work place. impervious clothing : Keep away from food and drink. When using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday. Avoid contact with the skin and the eyes. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : solid Colour : blue Odour : pleasant Odour Threshold : ph : not applicable Melting point/freezing point : not determined Boiling point : not determined Flash point : not applicable Evaporation rate : not applicable Upper explosion limit : not determined Lower explosion limit : not determined Vapour pressure : not applicable Density : not determined Solubility(ies) Water solubility : soluble Partition coefficient: n- : 4 / 9

5 octanol/water Auto-ignition temperature Thermal decomposition Viscosity Viscosity, kinematic : not determined : : SECTION 10. STABILITY AND REACTIVITY Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products : Stable : Stable under normal conditions. : No decomposition if stored and applied as directed. : Heat. : Acids Alkali metals : Carbon oxides Nitrogen oxides (NOx) Sulphur oxides SECTION 11. TOXICOLOGICAL INFORMATION Acute toxicity Components: sodium dodecylbenzenesulfonate: Acute oral toxicity : LD50 Oral rat: 438 mg/kg Skin corrosion/irritation Product: Remarks: Irritating to skin. Serious eye damage/eye irritation Product: Remarks: May cause irreversible eye damage. Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity 5 / 9

6 Reproductive toxicity Amides, coco, N-(hydroxyethyl): Fatty acids, tallow, sodium salts: Fatty acids, coco, sodium salts: sodium dodecylbenzenesulfonate: (1-Hydroxyethylidene)bis-phosphonic Acid tetrasodium salt: STOT - single exposure STOT - repeated exposure Aspiration toxicity SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Persistence and degradability Bioaccumulative potential Product: Partition coefficient: n- octanol/water Mobility in soil Other adverse effects : Remarks: SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues Contaminated packaging : Dispose of in accordance with local regulations. : Do not re-use empty containers. Dispose of as unused product. Empty containers can be landfilled, when in accordance with the local regulations. 6 / 9

7 SECTION 14. TRANSPORT INFORMATION Transportation Regulation: 49 CFR (USA): Transportation Regulation: IMDG (Vessel): Transportation Regulation: IATA (Cargo Air): Transportation Regulation: IATA (Passenger Air): Transportation Regulation: TDG (Canada): SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity This material does not contain any components with a CERCLA RQ. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards : Acute Health Hazard SARA 302 SARA 313 : SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. : SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. California Prop 65 This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. The components of this product are reported in the following inventories: TSCA DSL NDSL AICS On the inventory, or in compliance with the inventory 7 / 9

8 Instability SAFETY DATA SHEET NZIoC PICCS IECSC Inventory Acronym and Validity Area Legend: AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TSCA (USA) SECTION 16. OTHER INFORMATION Further information NFPA: Flammability HMIS III: Health HEALTH FLAMMABILITY 2 0 PHYSICAL HAZARD 0 Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic OSHA GHS Label Information: Hazard pictograms : Signal word : Danger: Hazard statements : Causes serious eye damage. Causes skin irritation. Precautionary statements : Prevention: Wear protective gloves/ eye protection/ face protection. Wash.? thoroughly after handling. Response: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If skin irritation occurs: Get medical advice/ attention. IF ON SKIN: Wash with plenty of water/.?. Storage: Store locked up. Disposal: Dispose of contents/container in accordance with local regulation. Version: 1.0 Revision Date: 05/30/2015 Print Date: 06/05/2015 We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. Users should make their own investigations to determine the suitability and applicability of the information for their particular purposes. 8 / 9

9 This SDS has been prepared by the Compliance Services organization supporting this manufacturer, supplier or distributor. Zep Inc. markets products under well recognized and established brand names such as Zep, Zep Commercial,Zep Professional, Enforcer, National Chemical, Selig, Misty, Next Dimension, Petro, i-chem, TimeMist, TimeWick, MicrobeMax, Country Vet, Konk, Original Bike Spirits, Blue Coral, Black Magic, Rain-X, Niagara National, FC Forward Chemicals,Rexodan, Mykal, and a number of private labeled brands. 9 / 9