Material Safety Data Sheet SUNCLEAR-Z50

Transcription

1 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION A. PRODUCT NAME B. APPLICATION Cosmetics C. COMPANY IDENTIFICATION Company Name : Address : Sunjin Chemical Co.,Ltd Wonsi-dong, Danwon-gu, Ansan-si, Kyungki-do, Korea Telephone : HAZARDS IDENTIFICATION A. GHS CLASSIFICATION Hazard Class and Category Code(s) Aquatic Acute 1 Aquatic Chronic 1 Hazard statement Code(s) H400 - Very toxic to aquatic life H410 - Very toxic to aquatic life with long lasting effects B. WARNING LABELS, PICTOGRAMS, HAZARD STATEMENT AND PREVENTIVE MEASURE STATEMENT Pictograms : Signal Word : Hazard Statement : Warning H400 - Very toxic to aquatic life H410 - Very toxic to aquatic life with long lasting effects Precautionary Statement : P273 Avoid release to the environment. P391 Collect spillage. P501 Dispose of contents/container to C. HAZARDS NOT INCLUDED IN GHS CLASSIFICATION (NFPA RATING) Health : 2 Flammability : 0 Instability : 0 3. COMPOSITION / INFORMATION ON IGREDIENTS Chemical Name Other Name CAS No. %(w/w) Zinc White ~50 Page 1/7

2 Cyclopentasiloxane CYCLOPENTASILOXANE, DECAMETHYL ~50 PEG-10 Dimethicone - 10max Hydrogen Dimethicone Hydrogen Dimethicone max 4. FIRST AID MEASURES A. EYE CONTACT Immediately flush eyes with plenty of cool water for at least 15 minutes. Do not let victim rub eyes. Seek professional medical attention. B. SKIN CONTACT Immediately flush skin with water while removing contaminated clothing. Wash contaminated clothing before reuse. Should Irritation occur, seek professional medical attention. C. INHALATION Immediately remove victim to fresh air. If victim has stopped breathing, give artificial respiration and seek medical assistance. D. INGESTION Do not induce vomiting. Consult a physician or poison control unit. E. NOTE TO PHYSICIAN No information 5. FIRE FIGHTING MEASURES A. SUITABLE EXTINGUISHING MEDIA Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. B. SPECIFIC HAZARDS ARISING FROM THE CHEMICAL Thermal Decomposition Combustility and Explosiveness found No combustion and explosion hazard C. SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIRE FIGHTERS Wear self contained breathing apparatus for fire fighting if necessary. 6. ACCIDENTAL RELEASE MEASURES A. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES Avoid dust formation. Ensure adequate ventilation. B. ENVIRONMENTAL PRECAUTIONS Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. C. METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP Pick up and arrange disposal without creating dust. Keep in suitable, closed containers for disposal. 7. HANDLING AND STORAGE A. PRECAUTIONS FOR SAFE HANDLING Provide appropriate exhaust ventilation at places where dust is formed. Normal measures for preventive fire protection. B. CONDITION FOR SAFE STORAGE Keep container tightly closed in a dry and well-ventilated place. Page 2/7

3 Keep in a dry place. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION A. OCCUPATIONAL EXPOSURE LIMITS Korea ACGIH No information No information B. ENGINEERING MEASURES Local and/or general ventilation is recommended C. INDIVIDUAL PROTECTION MEASURES Respiratory Protection Eye Protection Wear suitable mask. Wear safety glasses or goggles. Provide an emergency eye wash fountain and quick drench shower Hand Protection Skin Protection Wear general gloves. No special protection required. Wear standard protective clothing 9. PHYSICAL AND CHEMICAL PROPERTIES A. PHYSICAL APPEARANCE Milky liquid B. ODOR Faint odor C. ODOR THRESHOLD No data available D. ph No data E. MELTING/FREEZING POINT No data F. INITIAL BOILING POINT/BOILING POINT RANGE 210 G. FLASH POINT Not Applicable H. EVAPORATION RATE Not Applicable I. FLAMMABILITY (GAS, SOLID) Not Applicable J. UPPER AND LOWER EXPLOSION LIMITS Not Applicable K. VAPOUR PRESSURE Not Applicable L. SOLUBILITY Insoluble to water M. RELATIVE VAPOUR DENSITY Not Applicable N. SPECIFIC GRAVITY 1.15 O. n-octanol/water PARTITION COEFFICIENT Not Applicable P. AUTOIGNITION TEMPERATURE Not Applicable Q. DECOMPOSITION TEMPERATURE Not Applicable R. VISCOSITY Not Applicable 10. STABILITY AND REACTIVITY Page 3/7

4 A. CHEMICAL STABILITY Stable under recommended storage conditions. B. CONDITIONS TO AVOID no data available C. INCOMPATIBLE MATERIALS Strong oxidizing agents D. HAZARDOUS DECOMPOSITION PRODUCTS Hazardous decomposition products formed under fire conditions. - Zinc/zinc oxides 11. TOXICOLOGY INFORMATION A. INFORMATION ON THE LIKELY ROUTES OF EXPOSURE No information B. DELAYED AND IMMEDIATE EFFECTS AND ALSO CHRONIC EFFECTS FROM SHORT AND LONG TERM EXPOSURE Acute Toxicity Oral Cyclopentasiloxane LD mg / kg LD50 >24134 mg / kg Rat Skin Cyclopentasiloxane LD50 >16000 mg / kg Rabbit Inhalation LC50> 5.7 mg /l Rat Skin Corrosion/Irritation Slightly irritation or non-irritation. Rabbit Serious Eye Damage/Irritation Respiratory Slightly irritation. Rabbit Skin Sensitization Negative on patch test Carcinogenicity IARC NTP OSHA WISHA ACGIH Germ Cell Mutagenicity Reproductive Toxicity Specific Target Organ Toxicity - Single Exposure : Specific Target Organ Toxicity - Repeated Exposure : Aspiration Hazard Page 4/7

5 12. ECOLOGICAL INFORMATION A. TOXICITY Fish LC mg /l 96 hr Crustacean LC mg /l 48 hr Birds EC mg /l 72 hr B. PERSISTENCE AND DEGRADABILITY Persistence Degradability No data available No data available C. BIOACCUMULATIVE POTENTIAL Bioacculation No data available D. MOBILITY IN SOIL No data available E. OTHER ADVERSE EFFECTS No data available 13. DISPOSAL CONSIDERATIONS A. DISPOSAL METHODS Dispose the waste in accordance with all applicable regulations B. PRECATIONS No special precautions required 14. TRANSPORTATION INFORMATION A. UN NUMBER UN3082 B. PROPER SHIPPING NAME ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. C. TRANSPORTATION HAZARD CLASS(ES) 9 D. PACKING GROUP, IF APPLICABLE 3 E. Fire Emergency F-A Outflow Emergency S-F 15. REGULATORY INFORMATION A. SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS Korea US Federal OSHA CERCLA EPCRA Page 5/7

6 EPCRA 304 EPCRA 313 Rotterdam Convention(PIC) Stockholm Convention (POPs) Montreal Protocol EU Labeling mentioned in section 2 Hazard Symbols Risk phrase N : Dangerous for the environment R 50/53 : Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Safety phrase S60 : This material and container must be disposed of as hazardous waste. S61 : Avoid release to the environment. Refer to special instruction / Safety data sheets. 16. OTHER INFORMATION A. REFERENCES (1) ICSC (2002) (2) HSDB (2005) (3) IUCLID (2000) (4) IARC (5) ACGIH (6) NTP DB (7) DFGOT vol.2 (1991) (8) AQUIRE (2003) B. OTHER INFORMATION Date Issued FEB. 26, 2012 Version Number 1.1 Last revision JULY. 31, 2013 C. OTHERS The information and recommendations contained herein are, to the best of Sunjin Chemical Co., Ltd s knowledge and belief, accurate and reliable as of the last revision date. This document is offered in good faith. The information relates to the specific material designated, and may not be valid for such material used in combination with any other materials, in any process, or if used in a manner other than for which it is intended. Sunjin Chemical Co., Ltd, does not warrant or guarantee accuracy, reliability or completeness. It is the user s responsibility to satisfy himself as to the suitability and completeness of such information for his own particular use. Page 6/7

7 We do not accept liability for any lose or damage that may occur from the use of this information, nor do we either warranty against patent infringement Page 7/7