SAFETY DATA SHEET Natural Poultry Mite Killer

Transcription

1 SAFETY DATA SHEET SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name 1.2. Relevant identified uses of the substance or mixture and uses advised against Identified uses Uses advised against Insecticide No specific uses advised against are identified Details of the supplier of the safety data sheet Supplier Agropharm Limited Overley Hill, B5061, Wellington, Telford, Shropshire, TF65HD. Tel: +44 (0) Fax: +44 (0) Emergency telephone number Emergency telephone +44 (0) (Monday to Friday 9:00-17:00 GMT) SECTION 2: Hazards identification 2.1. of the substance or mixture Physical hazards Flam. Liq. 1 - H224 Health hazards Environmental hazards Elicitation - EUH208 Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410 (67/548/EEC or 1999/45/EC) Environmental F+;R12. N;R50/53. The product contains a substance which is toxic to aquatic organisms and which may cause long-term adverse effects in the aquatic environment Label elements Pictogram Signal word Danger 1/7

2 Hazard statements Precautionary statements Supplementary precautionary statements H224 Extremely flammable liquid and vapour. H410 Very toxic to aquatic life with long lasting effects. EUH208 Contains d-limonene. May produce an allergic reaction. EUH208 Contains. May produce an allergic reaction. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P273 Avoid release to the environment. P233 Keep container tightly closed. P240 Ground/bond container and receiving equipment. P241 Use explosion-proof electrical equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P280 Wear protective gloves/protective clothing/eye protection/face protection. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P370+P378 In case of fire: Use foam, carbon dioxide, dry powder or water fog to extinguish. P391 Collect spillage. P403+P235 Store in a well-ventilated place. Keep cool. P501 Dispose of contents/container to 2.3. Other hazards Not known SECTION 3: Composition/information on ingredients 3.2. Mixtures PIPERONYL BUTOXIDE B.P. VET. 1-5% CAS number: EC number: M factor (Acute) = 1 M factor (Chronic) = 1 Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410 (67/548/EEC or 1999/45/EC) N;R50/53. d-limonene <1% CAS number: M factor (Acute) = 1 M factor (Chronic) = 1 Flam. Liq. 3 - H226 Skin Irrit. 2 - H315 Skin Sens. 1 - H317 Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410 (67/548/EEC or 1999/45/EC) Xi;R38. N;R50/53. R10,R43. 2/7

3 PYRETHRINS INCLUDING CINERINS <1% CAS number: EC number: M factor (Acute) = 100 M factor (Chronic) = 100 Acute Tox. 4 - H302 Acute Tox. 4 - H312 Acute Tox. 4 - H332 Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410 (67/548/EEC or 1999/45/EC) Xn;R20/21/22. N;R50/53. The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation Ingestion Skin contact Eye contact Move affected person to fresh air at once. Place unconscious person on their side in the recovery position and ensure breathing can take place. If breathing stops, provide artificial respiration. Get medical attention. Do not induce vomiting. Rinse mouth thoroughly with water. Give plenty of water to drink. Get medical attention. Wash skin thoroughly with soap and water. Get medical attention promptly if symptoms occur after washing. Rinse immediately with plenty of water. Remove any contact lenses and open eyelids wide apart. Continue to rinse for at least 15 minutes. Get medical attention promptly if symptoms occur after washing Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Extinguish with foam, carbon dioxide, dry powder or water fog. Water Special hazards arising from the substance or mixture Specific hazards Protection against nuisance dust must be used when the airborne concentration exceeds 10 mg/m3. Containers can burst violently or explode when heated, due to excessive pressure build-up. Hazardous combustion products Does not decompose when used and stored as recommended Advice for firefighters Protective actions during firefighting Special protective equipment for firefighters Fight advanced or massive fires from safe distance or protected location. Be aware of danger of explosion. Containers close to fire should be removed or cooled with water. Control run-off water by containing and keeping it out of sewers and watercourses. Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective clothing. SECTION 6: Accidental release measures 3/7

4 6.1. Personal precautions, protective equipment and emergency procedures Personal precautions Wear protective clothing as described in Section 8 of this safety data sheet. Avoid inhalation of spray mist and contact with skin and eyes Environmental precautions Environmental precautions Avoid the spillage or runoff entering drains, sewers or watercourses Methods and material for containment and cleaning up Methods for cleaning up Absorb in vermiculite, dry sand or earth and place into containers Reference to other sections SECTION 7: Handling and storage 7.1. Precautions for safe handling Usage precautions Avoid inhalation of vapours/spray and contact with skin and eyes. Keep away from heat, sparks and open flame Conditions for safe storage, including any incompatibilities Storage precautions Keep away from heat, sparks and open flame. Aerosol cans: Must not be exposed to direct sunlight or temperatures above 50 C. Keep separate from food, feedstuffs, fertilisers and other sensitive material Specific end use(s) Specific end use(s) The identified uses for this product are detailed in Section 1.2. Usage description Pesticide SECTION 8: Exposure Controls/personal protection 8.1. Control parameters Occupational exposure limits PYRETHRINS INCLUDING CINERINS Long-term exposure limit (8-hour TWA): WEL Short-term exposure limit (15-minute): WEL WEL = Workplace Exposure Limit 1 mg/m³ 8.2. Exposure controls Appropriate engineering controls Eye/face protection Hygiene measures Respiratory protection Provide adequate general and local exhaust ventilation. Do not spray near eyes. Provide eyewash station. Wash hands at the end of each work shift and before eating, smoking and using the toilet. If ventilation is inadequate, suitable respiratory protection must be worn. SECTION 9: Physical and Chemical Properties 9.1. Information on basic physical and chemical properties Appearance Colour Odour Initial boiling point and range Aerosol. N/A Mild (or faint). Perfume. Gas liquified under pressure. 4/7

5 Flash point Extremely Flammable. C Auto-ignition temperature 250 C 9.2. Other information SECTION 10: Stability and reactivity Reactivity Reactivity Avoid high temperatures Chemical stability Stability Stable at normal ambient temperatures and when used as recommended Possibility of hazardous reactions Possibility of hazardous reactions Not known. Will not polymerise Conditions to avoid Conditions to avoid Avoid exposing aerosol containers to high temperatures or direct sunlight Incompatible materials Materials to avoid Flammable/combustible materials Hazardous decomposition products Hazardous decomposition products Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapours. Oxides of carbon. Oxides of nitrogen. SECTION 11: Toxicological information Information on toxicological effects Inhalation Ingestion Skin contact Eye contact Unlikely to be hazardous in normal use. Gas or vapour in high concentrations may irritate the respiratory system. Symptoms following overexposure may include the following: Coughing. No harmful effects expected from quantities likely to be ingested by accident. Skin irritation should not occur when used as recommended. May cause temporary eye irritation. SECTION 12: Ecological Information Ecotoxicity The product contains a substance which is harmful to aquatic organisms and which may cause long-term adverse effects in the aquatic environment Toxicity Toxicity Toxic to fish Persistence and degradability Persistence and degradability Not known Bioaccumulative potential Bioaccumulative potential No data available on bioaccumulation Mobility in soil Mobility Mobile Results of PBT and vpvb assessment 5/7

6 12.6. Other adverse effects Other adverse effects Not known. SECTION 13: Disposal considerations Waste treatment methods General information Disposal methods Do not puncture or incinerate, even when empty. No specific disposal method required. Empty containers must not be punctured or incinerated because of the risk of an explosion. SECTION 14: Transport information UN number UN No. (ADR/RID) 1950 UN No. (IMDG) 1950 UN No. (ICAO) 1950 UN No. (ADN) UN proper shipping name Proper shipping name (ADR/RID) Proper shipping name (IMDG) AEROSOLS AEROSOLS Proper shipping name (ICAO) AEROSOLS Proper shipping name (ADN) AEROSOLS Transport hazard class(es) ADR/RID class 2.2 ADR/RID classification code 5A,5O ADR/RID label 2.2 IMDG class 2.2 ICAO class/division 2.2 ADN class 2.2 Transport labels Packing group Environmental hazards Environmentally hazardous substance/marine pollutant No Special precautions for user EmS F-D, S-U ADR transport category 3 6/7

7 Tunnel restriction code (E) Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Chemical safety assessment No chemical safety assessment has been carried out. SECTION 16: Other information General information Revision comments Issued by The information contained in this Safety Data Sheet is believed to be true and correct, as of the issue date. The accuracy and completeness of this information and any recommendations, or suggestions are made without warranty or guarantee. Since the conditions of use are beyond the control of our company, it is the responsibility of the user to determine the conditions of safe use for this product. Change of Product Name Group Technical Director Revision date 14/10/2015 Revision 6 Supersedes date 13/03/2014 Risk phrases in full Hazard statements in full R10 Flammable. R11 Highly flammable. R12 Extremely flammable. R20/21/22 Harmful by inhalation, in contact with skin and if swallowed. R38 Irritating to skin. R43 May cause sensitisation by skin contact. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R65 Harmful: may cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. H224 Extremely flammable liquid and vapour. H226 Flammable liquid and vapour. H302 Harmful if swallowed. H312 Harmful in contact with skin. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H332 Harmful if inhaled. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. EUH208 Contains d-limonene. May produce an allergic reaction. This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use. 7/7