SAFETY DATA SHEET. WAXIE Metal Sheen Stainless Steel Cleaner & Polish A Version 1.0 Revision Date 04/24/2015 Print Date 05/18/2015

Transcription

1 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Material name : WAXIE Metal Sheen Stainless Steel Cleaner & Polish Material number : Manufacturer or supplier's details Company : WAXIE Sanitary Supply Address : 9353 Waxie Way, San Diego CA Telephone : Emergency telephone numbers For a Medical Emergency : (CHEMTEL; 24 hours) For a Transportation : (CHEMTEL; 24 hours) Emergency SECTION 2. HAZARDS IDENTIFICATION Emergency Overview Appearance Color Odor Aerosol containing a liquefied gas clear characteristic GHS Classification Flammable aerosols : Category 1 Gases under pressure : Liquefied gas Skin irritation : Category 2 Skin sensitization : Category 1 GHS Label element Hazard pictograms : Signal word Hazard statements Precautionary statements : Danger : H222 Extremely flammable aerosol. H280 Contains gas under pressure; may explode if heated. H315 Causes skin irritation. H317 May cause an allergic skin reaction. : Prevention: P210 Keep away from heat, hot surfaces, sparks, open flames xxxxxxxxxxx Page 1 of 13

2 and other ignition sources. No smoking. P211 Do not spray on an open flame or other ignition source. P251 Pressurized container: Do not pierce or burn, even after use. P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P264 Wash skin thoroughly after handling. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves. Response: P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention. P362 Take off contaminated clothing and wash before reuse. Storage: P410 + P412 Protect from sunlight. Do not expose to temperatures exceeding 50 C/ 122 F. Disposal: P501 Dispose of contents/container in accordance with local regulation. Potential Health Effects Carcinogenicity: IARC ACGIH OSHA NTP No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH. No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture Hazardous components Chemical Name CAS-No. Concentration [%] Distillates (petroleum), hydrotreated heavy >= 50 - < 70 naphthenic Distillates (petroleum), hydrotreated light >= 20 - < 30 xxxxxxxxxxx Page 2 of 13

3 propane >= 5 - < 10 butane >= 5 - < 10 citral >= < 1 SECTION 4. FIRST AID MEASURES General advice If inhaled In case of skin contact In case of eye contact If swallowed : Move out of dangerous area. Show this safety data sheet to the doctor in attendance. Do not leave the victim unattended. : If unconscious place in recovery position and seek medical advice. If symptoms persist, call a physician. : If skin irritation persists, call a physician. Wash off immediately with plenty of water for at least 15 minutes. If on clothes, remove clothes. : Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist. If in eyes, rinse with water for 15 minutes. : Keep respiratory tract clear. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. DO NOT induce vomiting unless directed to do so by a physician or poison control center. SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media Unsuitable extinguishing media Specific hazards during firefighting : Alcohol-resistant foam Carbon dioxide (CO2) Dry chemical Water spray jet : High volume water jet : Do not allow run-off from fire fighting to enter drains or water courses. Hazardous combustion products : Carbon dioxide (CO2) Carbon monoxide Smoke xxxxxxxxxxx Page 3 of 13

4 Specific extinguishing methods Further information Special protective equipment for firefighters : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. : Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. For safety reasons in case of fire, cans should be stored separately in closed containments. Use a water spray to cool fully closed containers. : Wear self-contained breathing apparatus for firefighting if necessary. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and materials for containment and cleaning up : Use personal protective equipment. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapors accumulating to form explosive concentrations. Vapors can accumulate in low areas. : Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. : Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Sweep up or vacuum up spillage and collect in suitable container for disposal. SECTION 7. HANDLING AND STORAGE Advice on safe handling : Avoid exposure - obtain special instructions before use. Avoid contact with skin and eyes. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. Take precautionary measures against static discharges. Provide sufficient air exchange and/or exhaust in work rooms. Open drum carefully as content may be under pressure. Dispose of rinse water in accordance with local and national regulations. Persons susceptible to skin sensitization problems or asthma, xxxxxxxxxxx Page 4 of 13

5 allergies, chronic or recurrent respiratory disease should not be employed in any process in which this mixture is being used. Always replace cap after use. Do not breathe vapors or spray mist. Conditions for safe storage Materials to avoid : BEWARE: Aerosol is pressurized. Keep away from direct sun exposure and temperatures over 50 C. Do not open by force or throw into fire even after use. Do not spray on flames or red-hot objects. No smoking. Keep in a dry, cool and well-ventilated place. Observe label precautions. Electrical installations / working materials must comply with the technological safety standards. : Strong oxidizing agents SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Value type (Form of exposure) Distillates (petroleum), hydrotreated heavy naphthenic Distillates (petroleum), hydrotreated light Control parameters / Permissible concentration Basis TWA (Mist) 5 mg/m3 OSHA Z-1 TWA (Inhalable fraction) 5 mg/m3 ACGIH TWA 500 ppm OSHA Z-1 2,000 mg/m3 TWA 400 ppm OSHA P0 1,600 mg/m3 propane TWA 1,000 ppm ACGIH TWA 1,000 ppm NIOSH REL 1,800 mg/m3 TWA 1,000 ppm OSHA Z-1 1,800 mg/m3 TWA 1,000 ppm OSHA P0 1,800 mg/m3 butane TWA 800 ppm NIOSH REL 1,900 mg/m3 TWA 800 ppm 1,900 mg/m3 OSHA P0 Personal protective equipment xxxxxxxxxxx Page 5 of 13

6 Respiratory protection : Use respiratory protection unless adequate local exhaust ventilation is provided or exposure assessment demonstrates that exposures are within recommended exposure guidelines. Hand protection Remarks Eye protection Skin and body protection Hygiene measures : The suitability for a specific workplace should be discussed with the producers of the protective gloves. : Safety glasses Ensure that eyewash stations and safety showers are close to the workstation location. : impervious clothing Choose body protection according to the amount and concentration of the dangerous substance at the work place. : When using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : Aerosol containing a liquefied gas Color : clear Odor : characteristic Odor Threshold ph Melting point/freezing point Boiling point Flash point : not applicable Evaporation rate Flammability (solid, gas) : Extremely flammable aerosol. Upper explosion limit Lower explosion limit Vapour pressure Relative vapour density : 4,136 hpa (21 C) xxxxxxxxxxx Page 6 of 13

7 Density Solubility(ies) Water solubility Partition coefficient: n- octanol/water Auto-ignition temperature Thermal decomposition Viscosity Viscosity, kinematic Heat of combustion : g/cm3 : insoluble : not determined : kj/g SECTION 10. STABILITY AND REACTIVITY Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products : Stable : Stable under normal conditions. : No decomposition if stored and applied as directed. Vapors may form explosive mixture with air. : Heat, flames and sparks. Extremes of temperature and direct sunlight. : Strong oxidizing agents : Carbon oxides SECTION 11. TOXICOLOGICAL INFORMATION Acute toxicity Components: Distillates (petroleum), hydrotreated heavy naphthenic: Acute oral toxicity : LD50 rat: > 5,000 mg/kg Acute inhalation toxicity : LC50 rat: > 5 mg/l Exposure time: 4 h xxxxxxxxxxx Page 7 of 13

8 Acute dermal toxicity : LD50 rabbit: > 5,000 mg/kg Distillates (petroleum), hydrotreated light: Acute oral toxicity : LD50 rat: > 5,000 mg/kg Acute inhalation toxicity Acute dermal toxicity propane: Acute inhalation toxicity : LC50 rat: > 4.6 mg/l Exposure time: 6 h : LD50 rat: > 2,000 mg/kg : LC50 mouse: 1,237 mg/l Exposure time: 2 h LC50 rat: 658 mg/l Exposure time: 4 h LC50 rat: 1,355 mg/l butane: Acute inhalation toxicity : LC50 mouse: 1,237 mg/l Exposure time: 2 h LC50 rat: 1,355 mg/l Skin corrosion/irritation Product: Remarks: Irritating to skin. Serious eye damage/eye irritation Product: Remarks: Vapours may cause irritation to the eyes, respiratory system and the skin. Respiratory or skin sensitization Product: Remarks: Causes sensitisation. Germ cell mutagenicity xxxxxxxxxxx Page 8 of 13

9 Carcinogenicity Reproductive toxicity Distillates (petroleum), hydrotreated heavy naphthenic: Distillates (petroleum), hydrotreated light: propane: butane: citral: STOT - single exposure STOT - repeated exposure Aspiration toxicity Further information Product: Remarks Components: Distillates (petroleum), hydrotreated light: Remarks SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Persistence and degradability Bioaccumulative potential Product: Partition coefficient: n- : Remarks octanol/water Components: butane : Partition coefficient: n- : Pow: 2.89 xxxxxxxxxxx Page 9 of 13

10 octanol/water citral : Partition coefficient: n- octanol/water Mobility in soil Other adverse effects Product: Regulation Remarks Additional ecological information : Pow: CFR Protection of Environment; Part 82 Protection of Stratospheric Ozone - CAA Section 602 Class I Substances This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). : An environmental hazard cannot be excluded in the event of unprofessional handling or disposal., Toxic to aquatic life with long lasting effects. Components: Distillates (petroleum), hydrotreated light : Additional ecological information SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : Dispose of in accordance with local regulations. The product should not be allowed to enter drains, water courses or the soil. Do not contaminate ponds, waterways or ditches with chemical or used container. Contaminated packaging : Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. Do not burn, or use a cutting torch on, the empty drum. xxxxxxxxxxx Page 10 of 13

11 SECTION 14. TRANSPORT INFORMATION Transportation Regulation: 49 CFR (USA): ORM-D, CONSUMER COMMODITY Transportation Regulation: IMDG (Vessel): UN1950, AEROSOLS, 2.1, - Limited quantity Transportation Regulation: IATA (Cargo Air): UN1950, Aerosols, flammable, 2.1, - Limited quantity Transportation Regulation: IATA (Passenger Air): UN1950, Aerosols, flammable, 2.1, - Limited quantity Transportation Regulation: TDG (Canada): UN1950, AEROSOLS, 2.1, - Limited quantity SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity This material does not contain any components with a CERCLA RQ. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards : Sudden Release of Pressure Hazard Acute Health Hazard Fire Hazard SARA 302 SARA 313 : SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. : SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. California Prop 65 This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. xxxxxxxxxxx Page 11 of 13

12 Health Instability SAFETY DATA SHEET The components of this product are reported in the following inventories: TSCA DSL AICS NZIoC PICCS IECSC On TSCA Inventory This product contains one or several components that are not on the Canadian DSL nor NDSL. Not in compliance with the inventory Not in compliance with the inventory Not in compliance with the inventory Not in compliance with the inventory Inventory Acronym and Validity Area Legend: AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TSCA (USA) SECTION 16. OTHER INFORMATION Further information NFPA: Flammability HMIS III: HEALTH FLAMMABILITY 3 4 PHYSICAL HAZARD 2 Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic OSHA GHS Label Information: Hazard pictograms : Signal word : Danger: Hazard statements : Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Causes skin irritation. May cause an allergic skin reaction. Precautionary statements : Prevention: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. Wash skin thoroughly after handling. Contaminated xxxxxxxxxxx Page 12 of 13

13 work clothing should not be allowed out of the workplace. Wear protective gloves. Response: IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/ attention. Take off contaminated clothing and wash before reuse. Storage: Protect from sunlight. Do not expose to temperatures exceeding 50 C/ 122 F. Disposal: Dispose of contents/container in accordance with local regulation. We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. Users should make their own investigations to determine the suitability and applicability of the information for their particular purposes. This SDS has been prepared by the Compliance Services organization supporting this manufacturer, supplier or distributor. xxxxxxxxxxx Page 13 of 13