SAFETY DATA SHEET DRAFT VERSION. SECTION 1. Identification of the hazardous chemical substance or mixture and of the supplier or manufacturer

Transcription

1 SAFETY DATA SHEET DRAFT VERSION SECTION 1. Identification of the hazardous chemical substance or mixture and of the supplier or manufacturer GHS product identifier Other means of identification Product code Part A; GB 7 mils; Potlife 240 mins Recommended use of the chemical and restrictions on use Thermally Conductive Silicone Gap Filler Material used together with Part B. Recommended use Recommended restrictions Suppliers details Manufacturer/Supplier Address: n-emergency calls: Contact person: 1.4. Emergency telephone number Chemical Emergency Call CHEMTREC Day or Night Within USA and Canada: Outside USA and Canada: ne known. SECTION 2: Hazard identification The Bergquist Company West 78th Street Chanhassen, MN AEHMSDS@henkel.com Classification of the substance or mixture Physical hazards Health hazards Environmental hazards (Collect Calls Accepted) GHS label elements, including precautionary statements ne. Hazard symbols Signal word Hazard statement Precautionary statement Prevention Response Storage Disposal Other hazards which do not result in classification Supplemental information ne. The mixture does not meet the criteria for classification. Observe good industrial hygiene practices. Wash thoroughly after handling. Store away from incompatible materials. Dispose of waste and residues in accordance with local authority requirements. ne known. SECTION 3. Composition/information on ingredients Mixtures This product is not hazardous according to NMX-R-019-SCFI-2011 requirements, therefore a hazard label does not apply. This product contains no substances classified as hazardous to health or the environment according to NMX-R-019-SCFI SECTION 4. First-aid measures Description of necessary first-aid measures Move to fresh air. Get medical attention if symptoms occur. Inhalation Skin contact Wash skin with soap and water. Get medical attention if irritation persists after washing Version #: 00 1 / 6

2 Eye contact Ingestion Most important symptoms/effects, acute and delayed Indication of immediate medical attention and special treatment needed General information SECTION 5. Fire-fighting measures Suitable extinguishing media Unsuitable extinguishing media Specific hazards arising from the chemical Special protective actions for firefighters Fire fighting equipment/instructions General fire hazards Flush thoroughly with water. If irritation occurs, get medical assistance. Rinse mouth thoroughly. Get medical attention if any discomfort occurs. Under normal conditions of intended use, this material does not pose a risk to health. Treat symptomatically. Get medical attention if any discomfort develops. Use fire-extinguishing media appropriate for surrounding materials. ne known. ne. Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Selection of respiratory protection for firefighting: follow the general fire precautions indicated in the workplace. Move containers from fire area if you can do so without risk. This product is not flammable. SECTION 6. Measures that must be taken in the event of accidental spillage or an accidental leak Personal precautions, protective equipment and emergency procedures For non-emergency Avoid contact with skin and eyes. personnel For emergency responders Environmental precautions Methods and materials for containment and cleaning up Other issues relating to spills and releases SECTION 7. Handling and storage Precautions to ensure safe handling Conditions for safe storage, including any incompatibilities Keep unnecessary personnel away. Environmental manager must be informed of all major spillages. Sweep up or gather material and place in appropriate container for disposal. For waste disposal, see Section 13 of the SDS. Clean up in accordance with all applicable regulations. SECTION 8. Exposure controls/personal protection Control parameters Occupational exposure limits Biological limit values Control banding approach Appropriate engineering controls Provide adequate ventilation. Avoid contact with skin and eyes. Observe good industrial hygiene practices. Wear appropriate personal protective equipment (See Section 8). Store in closed original container in a dry place. Store away from incompatible materials. exposure limits noted for ingredient(s). biological exposure limits noted for the ingredient(s). data available. Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Individual protection measures, such as personal protective equipment Risk of contact: Wear approved safety goggles. Eye/face protection Skin protection Hand protection Other Respiratory protection Thermal hazards Use suitable protective gloves if risk of skin contact. Suitable gloves can be recommended by the glove supplier. If prolonged or repeated contact is likely, chemical resistant clothing is recommended. In case of inadequate ventilation, use respiratory protection. Wear appropriate thermal protective clothing, when necessary Version #: 00 2 / 6

3 General hygiene considerations SECTION 9. Physical and chemical properties Appearance Odor Physical state Form Color Odor threshold ph Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Liquid. Liquid. Blue. Slight. Upper/lower flammability or explosive limits Flammability limit - lower (%) Flammability limit - upper (%) Explosive limit - lower (%) Explosive limit - upper (%) Vapor pressure Vapor density Solubility(ies) Partition coefficient (n-octanol/water) Auto-ignition temperature Decomposition temperature Viscosity Other information Bulk density Density Explosive properties Oxidizing properties VOC Insoluble in water. t available. 50 Pa s 3.10 g/cc (25 C) t explosive. t oxidizing. t available. SECTION 10. Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products The product is stable and non-reactive under normal conditions of use, storage and transport. Material is stable under normal conditions. Hazardous polymerization does not occur. Contact with incompatible materials. Strong oxidizing agents. SECTION 11. Toxicological information hazardous decomposition products are known. Information on likely routes of exposure Inhalation Vapors may irritate throat and respiratory system and cause coughing Version #: 00 3 / 6

4 Skin contact Eye contact Ingestion Symptoms related to the physical, chemical and toxicological characteristics Prolonged skin contact may cause temporary irritation. May cause eye irritation on direct contact. Ingestion may cause irritation and malaise. Under normal conditions of intended use, this material does not pose a risk to health. Delayed and immediate effects and also chronic effects from short and long term exposure Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization Respiratory sensitization Skin sensitization Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard Other information t expected to be acutely toxic. Prolonged skin contact may cause temporary irritation. Direct contact with eyes may cause temporary irritation. t a respiratory sensitizer. This product is not expected to cause skin sensitization. data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. t classifiable as to carcinogenicity to humans. This product is not expected to cause reproductive or developmental effects. t an aspiration hazard. ne known. SECTION 12. Ecotoxicological information Ecotoxicity Persistence and degradability Bioaccumulative potential Mobility in soil Other adverse effects The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. data is available on the degradability of this product. data available. SECTION 13. Disposal considerations Disposal methods Disposal instructions Local disposal regulations Hazardous waste code Waste from residues / unused products Contaminated packaging SECTION 14. Transport information SCT DOT ADR RID The product is insoluble in water. Expected to have low mobility in soil. other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. Dispose of contents/container in accordance with local/regional/national/international regulations. Dispose of in accordance with local regulations. Waste codes should be assigned by the user based on the application for which the product was used. Disposal recommendations are based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. Since emptied containers retain product residue, follow label warnings even after container is emptied Version #: 00 4 / 6

5 ADN IATA IMDG Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code SECTION 15. Regulatory information Safety, health and environmental regulations specific for the product in question This safety data sheet was prepared in accordance with the Official Mexican Standard (NOM-018-STPS-2015). Mexico. Substances subject to reporting for the pollutant release and transfer registry (PRTR) t listed. International regulations Montreal Protocol Stockholm Convention Rotterdam Convention Kyoto protocol Basel Convention International Inventories Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Canada Canada China Europe Europe Japan Korea New Zealand Philippines United States & Puerto Rico Domestic Substances List (DSL) n-domestic Substances List (NDSL) Inventory of Existing Chemical Substances in China (IECSC) European Inventory of Existing Commercial Chemical Substances (EINECS) European List of tified Chemical Substances (ELINCS) Inventory of Existing and New Chemical Substances (ENCS) Existing Chemicals List (ECL) New Zealand Inventory Philippine Inventory of Chemicals and Chemical Substances (PICCS) Toxic Substances Control Act (TSCA) Inventory *A "" indicates this product complies with the inventory requirements administered by the governing country(s). A "" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). SECTION 16. Other included information relevant to the preparation and updating of safety data sheets Revision date List of abbreviations References Draft version. t available. HSDB - Hazardous Substances Data Bank IARC Monographs. Overall Evaluation of Carcinogenicity National Toxicology Program (NTP) Report on Carcinogens Version #: 00 5 / 6

6 NFPA ratings Disclaimer The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates ( Henkel ) does not assume responsibility for any results obtained by persons over whose methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits Version #: 00 6 / 6

7 SAFETY DATA SHEET DRAFT VERSION SECTION 1. Identification of the hazardous chemical substance or mixture and of the supplier or manufacturer GHS product identifier Other means of identification Product code Part B; GB 7, 10 mils; Potlife 240 mins Recommended use of the chemical and restrictions on use Thermally Conductive Silicone Gap Filler Material used together with Part A. Recommended use Recommended restrictions Suppliers details Manufacturer/Supplier Address: n-emergency calls: Contact person: 1.4. Emergency telephone number Chemical Emergency Call CHEMTREC Day or Night Within USA and Canada: Outside USA and Canada: ne known. SECTION 2: Hazard identification The Bergquist Company West 78th Street Chanhassen, MN Classification of the substance or mixture Physical hazards Health hazards Environmental hazards (Collect Calls Accepted) GHS label elements, including precautionary statements ne. Hazard symbols Signal word Hazard statement Precautionary statement Prevention Response Storage Disposal Other hazards which do not result in classification Supplemental information ne. The mixture does not meet the criteria for classification. Observe good industrial hygiene practices. Wash thoroughly after handling. Store away from incompatible materials. Dispose of waste and residues in accordance with local authority requirements. ne known. SECTION 3. Composition/information on ingredients Mixtures This product is not hazardous according to NMX-R-019-SCFI-2011 requirements, therefore a hazard label does not apply. This product contains no substances classified as hazardous to health or the environment according to NMX-R-019-SCFI SECTION 4. First-aid measures Description of necessary first-aid measures Move to fresh air. Get medical attention if symptoms occur. Inhalation Skin contact Wash skin with soap and water. Get medical attention if irritation persists after washing Version #: 00 1 / 6

8 Eye contact Ingestion Most important symptoms/effects, acute and delayed Indication of immediate medical attention and special treatment needed General information SECTION 5. Fire-fighting measures Suitable extinguishing media Unsuitable extinguishing media Specific hazards arising from the chemical Special protective actions for firefighters Fire fighting equipment/instructions General fire hazards Flush thoroughly with water. If irritation occurs, get medical assistance. Rinse mouth thoroughly. Get medical attention if any discomfort occurs. Under normal conditions of intended use, this material does not pose a risk to health. Treat symptomatically. Get medical attention if any discomfort develops. Use fire-extinguishing media appropriate for surrounding materials. ne known. ne. Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Selection of respiratory protection for firefighting: follow the general fire precautions indicated in the workplace. Move containers from fire area if you can do so without risk. This product is not flammable. SECTION 6. Measures that must be taken in the event of accidental spillage or an accidental leak Personal precautions, protective equipment and emergency procedures For non-emergency Avoid contact with skin and eyes. For personal protection, see section 8 of the SDS. personnel For emergency responders Environmental precautions Methods and materials for containment and cleaning up Other issues relating to spills and releases SECTION 7. Handling and storage Precautions to ensure safe handling Conditions for safe storage, including any incompatibilities Keep unnecessary personnel away. Environmental manager must be informed of all major spillages. Sweep up or gather material and place in appropriate container for disposal. For waste disposal, see Section 13 of the SDS. Clean up in accordance with all applicable regulations. SECTION 8. Exposure controls/personal protection Control parameters Occupational exposure limits Biological limit values Exposure guidelines Control banding approach Appropriate engineering controls Provide adequate ventilation. Avoid contact with skin and eyes. Observe good industrial hygiene practices. Wear appropriate personal protective equipment (See Section 8). Store in closed original container in a dry place. Store away from incompatible materials. exposure limits noted for ingredient(s). biological exposure limits noted for the ingredient(s). exposure standards allocated. data available. Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Individual protection measures, such as personal protective equipment Risk of contact: Wear approved safety goggles. Eye/face protection Skin protection Hand protection Other Respiratory protection Thermal hazards Use suitable protective gloves if risk of skin contact. Suitable gloves can be recommended by the glove supplier. If prolonged or repeated contact is likely, chemical resistant clothing is recommended. In case of inadequate ventilation, use respiratory protection. Wear appropriate thermal protective clothing, when necessary Version #: 00 2 / 6

9 General hygiene considerations SECTION 9. Physical and chemical properties Appearance Odor Physical state Form Color Odor threshold ph Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Liquid. Liquid. White. Slight. Upper/lower flammability or explosive limits Flammability limit - lower (%) Flammability limit - upper (%) Explosive limit - lower (%) Explosive limit - upper (%) Vapor pressure Vapor density Solubility(ies) Partition coefficient (n-octanol/water) Auto-ignition temperature Decomposition temperature Viscosity Other information Bulk density Density Explosive properties Oxidizing properties VOC Insoluble in water. t available. 50 Pa s 3.10 g/cc (25 C) t explosive. t oxidizing. t available. SECTION 10. Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products The product is stable and non-reactive under normal conditions of use, storage and transport. Material is stable under normal conditions. Hazardous polymerization does not occur. Contact with incompatible materials. Strong oxidizing agents. SECTION 11. Toxicological information hazardous decomposition products are known. Information on likely routes of exposure Inhalation Vapors may irritate throat and respiratory system and cause coughing Version #: 00 3 / 6

10 Skin contact Eye contact Ingestion Symptoms related to the physical, chemical and toxicological characteristics Prolonged skin contact may cause temporary irritation. May cause eye irritation on direct contact. Ingestion may cause irritation and malaise. Under normal conditions of intended use, this material does not pose a risk to health. Delayed and immediate effects and also chronic effects from short and long term exposure Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization Respiratory sensitization Skin sensitization Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard Other information t expected to be acutely toxic. Prolonged skin contact may cause temporary irritation. Direct contact with eyes may cause temporary irritation. t a respiratory sensitizer. This product is not expected to cause skin sensitization. data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. t classifiable as to carcinogenicity to humans. This product is not expected to cause reproductive or developmental effects. t an aspiration hazard. ne known. SECTION 12. Ecotoxicological information Ecotoxicity Persistence and degradability Bioaccumulative potential Mobility in soil Other adverse effects The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. data is available on the degradability of this product. data available. SECTION 13. Disposal considerations Disposal methods Disposal instructions Local disposal regulations Hazardous waste code Waste from residues / unused products Contaminated packaging SECTION 14. Transport information SCT DOT ADR RID The product is insoluble in water. Expected to have low mobility in soil. other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. Dispose of contents/container in accordance with local/regional/national/international regulations. Dispose of in accordance with local regulations. Waste codes should be assigned by the user based on the application for which the product was used. Disposal recommendations are based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. Since emptied containers retain product residue, follow label warnings even after container is emptied Version #: 00 4 / 6

11 ADN IATA IMDG Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code SECTION 15. Regulatory information Safety, health and environmental regulations specific for the product in question This safety data sheet was prepared in accordance with the Official Mexican Standard (NOM-018-STPS-2015). Mexico. Substances subject to reporting for the pollutant release and transfer registry (PRTR) t listed. International regulations Montreal Protocol Stockholm Convention Rotterdam Convention Kyoto protocol Basel Convention International Inventories Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Canada Canada China Europe Europe Japan Korea New Zealand Philippines United States & Puerto Rico Domestic Substances List (DSL) n-domestic Substances List (NDSL) Inventory of Existing Chemical Substances in China (IECSC) European Inventory of Existing Commercial Chemical Substances (EINECS) European List of tified Chemical Substances (ELINCS) Inventory of Existing and New Chemical Substances (ENCS) Existing Chemicals List (ECL) New Zealand Inventory Philippine Inventory of Chemicals and Chemical Substances (PICCS) Toxic Substances Control Act (TSCA) Inventory *A "" indicates this product complies with the inventory requirements administered by the governing country(s). A "" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). SECTION 16. Other included information relevant to the preparation and updating of safety data sheets Revision date List of abbreviations References Draft version. t available. HSDB - Hazardous Substances Data Bank IARC Monographs. Overall Evaluation of Carcinogenicity National Toxicology Program (NTP) Report on Carcinogens Version #: 00 5 / 6

12 NFPA ratings Disclaimer The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates ( Henkel ) does not assume responsibility for any results obtained by persons over whose methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits Version #: 00 6 / 6