SAFETY DATA SHEET. None. None. The substance does not meet the criteria for classification.

Transcription

1 SAFETY DATA SHEET 1. Identification Product identifier Other means of identification Product code Synonyms Recommended use Recommended restrictions Brandt Sequestar 4.5% Fe EDTA 4.5% Iron Chelate Solution * Ferric ammonium EDTA Agriculture - Chelated Micronutrient - Refer to product label for application instructions ne known. Manufacturer/Importer/Supplier/Distributor information Manufacturer Company name Brandt Consolidated, Inc. Address 2935 South Koke Mill Road Springfield, IL Telephone United States Corporate Office Website msds@brandt.co Contact person EH&S / Regulatory Department Emergency phone number CHEMTREC (24 hours): USA, Canada, Puerto Rico Virgin Islands International Maritime +1 (703) Hazard(s) identification Physical hazards Health hazards Environmental hazards OSHA defined hazards Label elements Hazard symbol Signal word Hazard statement Precautionary statement Prevention Response Storage Disposal Hazard(s) not otherwise classified (HNOC) Supplemental information ne. ne. The substance does not meet the criteria for classification. Observe good industrial hygiene practices. Wash hands after handling. Store away from incompatible materials. Dispose of waste and residues in accordance with local authority requirements. ne known. ne. 3. Composition/information on ingredients Substances Chemical name Common name and synonyms CAS number % Water Ferric ammonium EDTA < 30 Tetraammonium Ethylenediaminetetraacetate < 1 1 / 6

2 *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Inhalation Skin contact Eye contact Ingestion Most important symptoms/effects, acute and delayed Indication of immediate medical attention and special treatment needed General information 5. Fire-fighting measures Suitable extinguishing media Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for firefighters Fire-fighting equipment/instructions Specific methods General fire hazards Move to fresh air. Call a physician if symptoms develop or persist. Wash off with soap and water. Get medical attention if irritation develops and persists. Rinse with water. Get medical attention if irritation develops and persists. Rinse mouth. Get medical attention if symptoms occur. Treat symptomatically. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Do not use water jet as an extinguisher, as this will spread the fire. During fire, gases hazardous to health may be formed. Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Move containers from fire area if you can do so without risk. Use standard firefighting procedures and consider the hazards of other involved materials. unusual fire or explosion hazards noted. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Methods and materials for containment and cleaning up Keep unnecessary personnel away. For personal protection, see section 8 of the SDS. Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Environmental precautions 7. Handling and storage Precautions for safe handling Conditions for safe storage, including any incompatibilities Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Avoid discharge into drains, water courses or onto the ground. Observe good industrial hygiene practices. Store in original tightly closed container. Keep out of the reach of children. Store away from incompatible materials (see Section 10 of the SDS). 8. Exposure controls/personal protection Occupational exposure limits Biological limit values Appropriate engineering controls exposure limits noted for ingredient(s). biological exposure limits noted for the ingredient(s). Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin protection Hand protection Wear appropriate chemical resistant gloves. 2 / 6

3 Other Respiratory protection Thermal hazards General hygiene considerations Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment. Respiratory protection not required. Wear appropriate thermal protective clothing, when necessary. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Odor Physical state Form Color Odor threshold ph Liquid. Liquid. Reddish-brown Very faint. Ammoniacal. Salt-Out / Crystallization Temp Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) Upper/lower flammability or explosive limits Flammability limit - lower (%) Flammability limit - upper (%) Explosive limit - lower (%) Explosive limit - upper (%) Vapor pressure < kpa at 25 C hpa estimated Vapor density Relative density Solubility(ies) Solubility (water) Partition coefficient (n-octanol/water) Auto-ignition temperature Decomposition temperature Viscosity Other information Molecular formula Percent volatile ph in aqueous solution Pounds per gallon degrees F C10H12FeN2O8.H4N 35.7 % as water estimated degrees F 10. Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid The product is stable and non-reactive under normal conditions of use, storage and transport. Material is stable under normal conditions. dangerous reaction known under conditions of normal use. Contact with incompatible materials. 3 / 6

4 Incompatible materials Hazardous decomposition products Strong oxidizing agents. hazardous decomposition products are known. 11. Toxicological information Information on likely routes of exposure Ingestion Expected to be a low ingestion hazard. Inhalation Skin contact Eye contact Symptoms related to the physical, chemical and toxicological characteristics Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization Respiratory sensitization Skin sensitization Germ cell mutagenicity Carcinogenicity adverse effects due to inhalation are expected. adverse effects due to skin contact are expected. Prolonged skin contact may cause temporary irritation. This product is not expected to cause skin sensitization. data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. OSHA Specifically Regulated Substances (29 CFR ) Reproductive toxicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard 12. Ecological information Ecotoxicity Components This product is not expected to cause reproductive or developmental effects. The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Species Tetraammonium Ethylenediaminetetraacetate (CAS ) Aquatic Fish LC50 Bluegill (Lepomis macrochirus) * Estimates for product may be based on additional component data not shown. Persistence and degradability data is available on the degradability of this product. Bioaccumulative potential Mobility in soil Other adverse effects 13. Disposal considerations Disposal instructions Local disposal regulations Hazardous waste code data available. Test Results mg/l, 96 hours other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose in accordance with all applicable regulations. The waste code should be assigned in discussion between the user, the producer and the waste disposal company. 4 / 6

5 Waste from residues / unused products Contaminated packaging Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. 14. Transport information DOT t regulated as dangerous goods. IATA t regulated as dangerous goods. IMDG t regulated as dangerous goods. 15. Regulatory information US federal regulations All components are on the U.S. EPA TSCA Inventory List. This product is not known to be a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR TSCA Section 12(b) Export tification (40 CFR 707, Subpt. D) CERCLA Hazardous Substance List (40 CFR 302.4) SARA 304 Emergency release notification OSHA Specifically Regulated Substances (29 CFR ) Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Delayed Hazard - Fire Hazard - Pressure Hazard - Reactivity Hazard - SARA 302 Extremely hazardous substance SARA 311/312 Hazardous chemical SARA 313 (TRI reporting) Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR ) Safe Drinking Water Act (SDWA) US state regulations US. Massachusetts RTK - Substance List US. New Jersey Worker and Community Right-to-Know Act US. Pennsylvania Worker and Community Right-to-Know Law US. Rhode Island RTK 5 / 6

6 US. California Proposition 65 WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. International Inventories Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Canada Canada China Europe Europe Japan Korea New Zealand Philippines Domestic Substances List (DSL) n-domestic Substances List (NDSL) Inventory of Existing Chemical Substances in China (IECSC) European Inventory of Existing Commercial Chemical Substances (EINECS) European List of tified Chemical Substances (ELINCS) Inventory of Existing and New Chemical Substances (ENCS) Existing Chemicals List (ECL) New Zealand Inventory Philippine Inventory of Chemicals and Chemical Substances (PICCS) United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date Revision date Version # 02 Disclaimer Revision Information Brandt Consolidated, Inc. cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. While the information contained herein are presented in good faith and believed to be accurate, it is provided for your guidance only. Because many factors may affect processing or application, we recommend that you make tests to determine the suitability of a product for your particular purpose prior to use. warranties of any kind, either expressed or implied, including warranties of merchantability or fitness for a particular purpose, are made regarding products described or information set forth, or that the products, or information may be used without infringing the intellectual property rights of others. In no case shall the information provided be considered a part of our terms and conditions of sale. Further, you expressly understand and agree that the information furnished by our company hereunder are given gratis and we assume no obligation or liability for the information given or results obtained, all such being given and accepted at your risk. This document has undergone significant changes and should be reviewed in its entirety. 6 / 6