: P&G PROFESSIONAL Disinfecting Degreaser - for surfaces with foodcontact (not for

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1 P&G PROFESSIONAL Disinfecting Degreaser - for surfaces with Date of issue: 14/04/2016 Revision date: : Version: 1.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Trade name : Mixture Product code : PA / Product group : P&G PROFESSIONAL Disinfecting Degreaser - for surfaces with foodcontact (not for grills) : Trade product 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Main use category Function or use category : Professional use : Washing and cleaning products (including solvent based products), Biocidal products (e.g. Disinfectants, pest control) Uses advised against No additional information available 1.3. Details of the supplier of the safety data sheet Procter & Gamble UK Brooklands, Weybridge, Surrey, KT13 0XP, UK Tel: Fax: Professional: customerservice@pgprof.com 1.4. Emergency telephone number Emergency number : (UK) Emergency Tel: (IRL) Emergency Tel: SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Eye Irrit. 2 H319 Full text of hazard classes and H-statements : see section 16 Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] Not classified Adverse physicochemical, human health and environmental effects No additional information available 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms (CLP) : Signal word (CLP) Hazard statements (CLP) Precautionary statements (CLP) 2.3. Other hazards Other hazards not contributing to the classification : Warning : H319 - Causes serious eye irritation : P102 - Keep out of reach of children P101 - If medical advice is needed, have product container or label at hand P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P501 - Dispose of contents/container to an appropriate local waste system : No presence of PBT and vpvb ingredients. SECTION 3: Composition/information on ingredients 3.1. Substance 14/04/2016 EN (English) 1/8

2 3.2. Mixture Name Product identifier % Classification according to Directive 67/548/EEC Alcohol Denat. (CAS No) (EC no) (EC index no) Propylene Glycol Butyl Ether (CAS No) (EC no) Ethanolamine (CAS No) (EC no) (REACH-no) C9-11 Pareth-8 (CAS No) (EC no) Polymer Classification according to Regulation (EC) No. 1272/2008 [CLP] 1-5 F; R11 Flam. Liq. 2, H225 Eye Irrit. 2, H Xi; R36/38 Skin Irrit. 2, H315 Eye Irrit. 2, H Xn; R20/21/22 C; R Xn; R22 Xi; R41 Acute Tox. 4 (Oral), H302 Acute Tox. 4 (Dermal), H312 Acute Tox. 4 (Inhalation:vapour), H332 Skin Corr. 1B, H314 STOT SE 3, H335 Aquatic Chronic 3, H412 Acute Tox. 4 (Oral), H302 Eye Dam. 1, H318 Benzalkonium Chloride (CAS No) (EC no) < 1 Xn; R22 C; R34 N; R50 Acute Tox. 4 (Oral), H302 Skin Corr. 1B, H314 Aquatic Acute 1, H400 (M=10) Full text of R- and H-phrases: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : IF INHALED: remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. : IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing and wash before reuse. If skin irritation occurs: Get immediate medical advice/attention. : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. : IF SWALLOWED: call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth. Do NOT induce vomiting Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation : Coughing. sneezing. Symptoms/injuries after skin contact : Redness. Swelling. dryness. Itching. Symptoms/injuries after eye contact : Severe pain. Redness. Swelling. Blurred vision. Symptoms/injuries after ingestion : Oral mucosal or gastro-intestinal irritation. Nausea. Vomiting. Excessive secretion. Diarrhoea Indication of any immediate medical attention and special treatment needed Refer to section 4.1. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2) Special hazards arising from the substance or mixture Fire hazard : No fire hazard. Non combustible. Explosion hazard : Product is not explosive. Reactivity : No dangerous reactions known Advice for firefighters Firefighting instructions Protection during firefighting : No specific firefighting instructions required. : In case of inadequate ventilation wear respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Protective equipment For emergency responders Protective equipment : Wear suitable gloves and eye/face protection. : Wear suitable gloves and eye/face protection Environmental precautions Consumer products ending up down the drain after use. Prevent soil and water pollution. Prevent spreading in sewers. 14/04/2016 EN (English) 2/8

3 6.3. Methods and material for containment and cleaning up For containment Methods for cleaning up 6.4. Reference to other sections Refer to Sections 8 and 13. : Scoop absorbed substance into closing containers. : Small quantities of liquid spill: take up in non-combustible absorbent material and shovel into container for disposal. Large spills: contain released substance, pump into suitable containers. This material and its container must be disposed of in a safe way, and as per local legislation. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Do not eat, drink or smoke when using this product. Do not handle until all safety precautions have been read and understood Conditions for safe storage, including any incompatibilities Storage conditions : Store in original container. Refer to section 10. Incompatible products : Refer to section 10. Incompatible materials : Refer to section 10. Prohibitions on mixed storage Storage area 7.3. Specific end use(s) Cleaning/washing agents and additives. :. SECTION 8: Exposure controls/personal protection 8.1. Control parameters National limit values Alcohol Denat. ( ) : Store in a cool area. Store in a dry area. United Kingdom WEL TWA (mg/m³) 1920 mg/m³ United Kingdom WEL TWA (ppm) 1000 ppm United Kingdom WEL TWA (mg/m³) 2.5 mg/m³ United Kingdom WEL TWA (ppm) 1 ppm United Kingdom WEL STEL (mg/m³) 7.6 mg/m³ United Kingdom WEL STEL (ppm) 3 ppm Monitoring procedures: DNELS, PNECS, OEL DNEL/DMEL (Workers) Long-term - systemic effects, dermal Long-term - local effects, inhalation DNEL/DMEL (General population) Long-term - systemic effects,oral Long-term - systemic effects, dermal Long-term - local effects, inhalation PNEC (Water) PNEC aqua (freshwater) PNEC aqua (marine water) PNEC aqua (intermittent, freshwater) PNEC (Sediment) PNEC sediment (freshwater) PNEC sediment (marine water) PNEC (Soil) PNEC soil PNEC (STP) PNEC sewage treatment plant DNEL/DMEL (Workers) Long-term - systemic effects, dermal Long-term - systemic effects, inhalation 1 mg/kg bodyweight/day 3.3 mg/m³ 3.75 mg/kg bodyweight/day 0.24 mg/kg bodyweight/day 2 mg/m³ mg/l mg/l mg/l mg/kg dwt mg/kg dwt mg/kg dwt 100 mg/l 44 mg/kg bodyweight/day mg/m³ 14/04/2016 EN (English) 3/8

4 DNEL/DMEL (General population) Acute - local effects, dermal Long-term - systemic effects,oral Long-term - systemic effects, inhalation Long-term - systemic effects, dermal PNEC (Water) PNEC aqua (freshwater) PNEC aqua (marine water) PNEC aqua (intermittent, freshwater) PNEC (Sediment) PNEC sediment (freshwater) PNEC sediment (marine water) PNEC (Soil) PNEC soil PNEC (STP) PNEC sewage treatment plant 50 % in mixture 8.75 mg/kg bodyweight/day 33.8 mg/m³ 16 mg/kg bodyweight/day mg/l mg/l 5.25 mg/l 2.36 mg/kg dwt mg/kg dwt 0.16 mg/kg dwt 10 mg/l 8.2. Exposure controls Appropriate engineering controls : No additional information available Personal protective equipment Not required for normal conditions of use. Eye protection : Wear eye/face protection. Skin and body protection :. Respiratory protection : Environmental exposure controls Prevent that the undiluted product reaches surface waters. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Property Value Unit Test method/notes Appearance Physical state Colour Odour Liquid. Liquid No data available pleasant (perfume). Odour threshold ppm Perceived odor at typical use conditions ph 11 Melting point C Not available. This property is not Freezing point Not available. This property is not Boiling point 105 C TMR. A.2. BOILING TEMPERATURE Flash point 53 C Relative evaporation rate (butylacetate=1) Flammability (solid, gas) Not available. This property is not. This property is not relevant for liquid product forms Explosive limits g/m³ Not available. This property is not 14/04/2016 EN (English) 4/8

5 Property Value Unit Test method/notes Vapour pressure Not available. This property is not Relative density Solubility Log Pow Soluble in water. No data available Auto-ignition temperature Not available. This property is not Decomposition temperature C Not available. This property is not Viscosity 5 cp Explosive properties Oxidising properties. This product is not classified as explosive as it does not contain any substances which possesses explosive properties CLP (Art 14 (2)).. This product is not classified as oxidizing as it does not contain any substances which possesses oxidizing properties CLP (Art 14 (2)) Other information No additional information available SECTION 10: Stability and reactivity Reactivity No dangerous reactions known Chemical stability Stable under normal conditions Possibility of hazardous reactions Refer to section 10.1 on Reactivity Conditions to avoid Not required for normal conditions of use Incompatible materials Hazardous decomposition products None under normal use. SECTION 11: Toxicological information Information on toxicological effects Mixture P&G PROFESSIONAL Disinfecting Degreaser - for surfaces with Acute toxicity Not classified (*) Skin corrosion/irritation Not classified (*) Serious eye damage/irritation Causes serious eye irritation. Respiratory or skin sensitisation Not classified (*) Germ cell mutagenicity Not classified (*) Carcinogenicity Not classified (*) Reproductive toxicity Not classified (*) Specific target organ toxicity (single exposure) Not classified (*) Specific target organ toxicity (repeated Not classified (*) exposure) Aspiration hazard Not classified (*) (*) Based upon available data of the substances and/or the product, product classification criteria are not met. See Section 2 and Section 16 for applicable hazard classification and classification procedure, respectively. 14/04/2016 EN (English) 5/8

6 Substances in the mixture Acute toxicity: Benzalkonium Chloride ( ) LD50 oral rat > mg/kg bw LD50 oral rat //OECD 401 LD50 oral rat 3300 mg/kg bw (OECD 401) C9-11 Pareth-8 ( ) LD50 oral rat SECTION 12: Ecological information Toxicity Ecology - general Benzalkonium Chloride ( ) EC50 Daphnia 1 > mg/kg bw : No known adverse effects on the functioning of water treatment plants under normal use conditions as recommended. The product is not considered harmful to aquatic organisms nor to cause long-term adverse effects in the environment. = mg/l LC50 fishes 1 LC50 other aquatic organisms 1 EC50 Daphnia mg/l EC 440/2008 C.1; Cyprinus carpio 110 mg/l DIN 38412; Pseudomonas putida 65 mg/l EC 440/2008 C.2; Daphnia magna ErC50 (algae) 2.8 mg/l OECD 201; Pseudokirchneriella subcapitata NOEC (chronic) > 1000 mg/l OECD 209 NOEC chronic fish LC50 fishes mg/l OECD 210; Oryzias latipes > 560 mg/l OECD 203; Poecilia reticulata LC50 other aquatic organisms 1 > 1000 mg/l OECD 209 EC50 Daphnia 1 > 1000 mg/l OECD 202; Daphnia magna ErC50 (algae) NOEC chronic algae Persistence and degradability > 1000 mg/l OECD 201; Pseudokirchneriella subcapitata 560 mg/l OECD 201; Pseudokirchneriella subcapitata Persistence and degradability BOD (% of ThOD) Persistence and degradability Biodegradation Biodegradable. > 90 % ThOD OECD 301 A Biodegradable. 90 % OECD 301 E Bioaccumulative potential Bioaccumulative potential Not expected to bioaccumulate due to the low log Kow (log Kow < 4). Bioaccumulative potential Not expected to bioaccumulate due to the low log Kow (log Kow < 4) Mobility in soil Log Koc Results of PBT and vpvb assessment P&G PROFESSIONAL Disinfecting Degreaser - for surfaces with Results of PBT assessment No presence of PBT and vpvb ingredients Component This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vpvb criteria of REACH regulation, annex XIII This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vpvb criteria of REACH regulation, annex XIII 14/04/2016 EN (English) 6/8

7 12.6. Other adverse effects Other information : No other effects known. SECTION 13: Disposal considerations Waste treatment methods Regional legislation (waste) : Disposal must be done according to official regulations Disposal recommendations : The waste codes/waste designations below are in accordance with EWC. Waste must be delivered to an approved waste disposal company. The waste is to be kept separate from other types of waste until its disposal. Do not throw waste product into the sewer. Where possible recycling is preferred to disposal or incineration.. For handling waste, see measures described in section 7. Empty, uncleaned packaging need the same disposal considerations as filled packaging EURAL Waste code product : * - detergents containing dangerous substances * - packaging containing residues of or contaminated by dangerous substances SECTION 14: Transport information UN number UN proper shipping name Transport hazard class(es) Packing group Environmental hazards Special precautions for user Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code SECTION 15: Regulatory information Ingredient label : <5% Non-ionic surfactants; Disinfectants Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances CESIO recommendations : The surfactant(s) contained in this preparation complies(comply) with the biodegradability criteria as laid down in Regulation (EC) No.648/2004 on detergents. Data to support this assertion are held at the disposal of the competent authorities of the Member States and will be made available to them, at their direct request or at the request of a detergent manufacturer. Other information, restriction and prohibition regulations : Classification according to Regulation (EC) No. 1272/2008 [CLP]. Registration, Evaluation, Authorisation and Restriction of Chemicals Regulation (EC) No 1907/2006. Regulation (EC) No. 648/2004 of 31 March 2004 on detergents. Biocide Directive (98/8/EC). Dangerous Preparations Directive 1999/45/EC. Dangerous Substances Directive 67/548/EEC National regulations No additional information available Chemical safety assessment No chemical safety assessment has been carried out SECTION 16: Other information Indication of changes Indication of changes : 14/04/2016 EN (English) 7/8

8 16.2. Abbreviations and acronyms LC50: Lethal Concentration to 50 % of a test population. LD50: Lethal Dose to 50% of a test population (Median Lethal Dose). PBT: Persistent, Bioaccumulative and Toxic substance. PNEC(s): Predicted No Effect Concentration(s). vpvb: Very Persistent and Very Bioaccumulative. AND: European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways. ATE: Acute Toxicity Estimate Classification and procedure used to derive the classification for mixtures according to Regulation (EC) 1272/2008 [CLP] Classification according to Regulation (EC) No. 1272/2008 [CLP] Eye Irrit. 2 classification procedure Weight of evidence Expert judgment Relevant R-phrases and/or H-statements (number and full text) for mixture and substances Acute Tox. 4 (Dermal) Acute toxicity (dermal), Category 4 Acute Tox. 4 (Inhalation:vapour) Acute toxicity (inhalation:vapour) Category 4 Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Aquatic Acute 1 Hazardous to the aquatic environment AcuteHazard, Category 1 Aquatic Chronic 3 Hazardous to the aquatic environment Chronic Hazard, Category 3 Eye Dam. 1 Serious eye damage/eye irritation, Category 1 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Flam. Liq. 2 Flammable liquids, Category 2 Skin Corr. 1B Skin corrosion/irritation, Category 1B Skin Irrit. 2 Skin corrosion/irritation, Category 2 STOT SE 3 Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation H225 Highly flammable liquid and vapour H302 Harmful if swallowed H312 Harmful in contact with skin H314 Causes severe skin burns and eye damage H315 Causes skin irritation H318 Causes serious eye damage. H319 Causes serious eye irritation. H332 Harmful if inhaled H335 May cause respiratory irritation H400 Very toxic to aquatic life H412 Harmful to aquatic life with long lasting effects. R20/21/22 Harmful by inhalation, in contact with skin and if swallowed R22 Harmful if swallowed R34 Causes burns R36/38 Irritating to eyes and skin R41 Risk of serious damage to eyes R50 Very toxic to aquatic organisms C Corrosive N Dangerous for the environment Xi Irritant Xn Harmful Training advice Normal use shall imply use in accordance with the instructions on the packaging Further information Salts listed in Section 3 without a REACh Registration number are exempt, based on Annex V SDS P&G CLP This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 14/04/2016 EN (English) 8/8