3M United Kingdom Plc. 3M Centre, Cain Road, BRACKNELL Berkshire RG12 8HT UNITED KINGDOM

Size: px

Start display at page:

Download "3M United Kingdom Plc. 3M Centre, Cain Road, BRACKNELL Berkshire RG12 8HT UNITED KINGDOM"

Adelia Dixon
6 years ago
Views:

1 3M United Kingdom Plc 3M Centre Cain Road BRACKNELL Berkshire RG12 8HT UNITED KINGDOM ======================================================================== Safety Data Sheet ======================================================================== MSDS ID Release Date: 19/11/09 Version : Supersedes Date 16/10/07 Printed : 19/11/09 Page 1 of 22 Dear Customer, This is the cover sheet for the KIT MSDS. You will find the document numbers of the MSDS that belong to the kit here on this page. 1 INFORMATION REGARDING KIT Tradename: 3M Scotch-Weld 7236 Structural Epoxy Adhesive, White 1.2 Intended Use of Product: Two part structural adhesive for industrial applications M Product ID: FS Contact Address: 3M UK PLC 3M Centre, Cain Road, Bracknell, Berkshire, RG12 8HT 3M Ireland 3M House, Adelphi Centre, Dun Laoghaire, Co. Dublin 1.5 Address and Emergency Contact Number: tox.uk@mmm.com +44 (0) Kit Components: M Scotch-Weld 7236 Structural Epoxy Adhesive (Par M Scotch-Weld 7236 Structural Epoxy Adhesive (Par 2 KIT LABEL Label Version Number: Symbol(s): C N Risk Phrases: R34 R43 Corrosive. Dangerous to environment. Causes burns. May cause sensitisation by skin contact. R51/53 Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. Safety Phrases: S22 Do not breathe dust.

2 S23A Do not breathe vapour. S24/25 Avoid contact with the skin and eyes. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28C After contact with skin, wash immediately with plenty of water for 15 minutes. S36/37/39B Wear suitable protective clothing, gloves, and eye and face protection. S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S51 Use only in well ventilated areas. S61 Avoid release to the environment. Refer to special instructions/safety data sheets. 3M Contains epoxy resins. See information supplied by manufacturer. Disclosable Ingredients: Part A: 3,3'-Oxybis(ethyleneoxy)bis(propylamine) Part B: Epoxy resin (reaction product bisphenol A - epichlorhydrin, MW<700) M Scotch-Weld 7236 Structural Epoxy Adhesive (Part A)(Hardener 1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY/UNDERTAKING Tradename: 3M Scotch-Weld 7236 Structural Epoxy Adhesive (Part A)(Hardener) 1.2 Intended Use of Product: Structural adhesive for industrialm applications. 1.4 Contact Address: 3M UK PLC 3M Centre, Cain Road, Bracknell, Berkshire, RG12 8HT 3M Ireland 3M House, Adelphi Centre, Dun Laoghaire, Co. Dublin 1.5 Address and Emergency Contact Number: tox.uk@mmm.com +44 (0) HAZARDS IDENTIFICATION Risk Phrases: R34 Causes burns. R52/53 Harmful to aquatic organisms. May cause long-term adverse effects in the aquatic environment. 3 COMPOSITION/INFORMATION ON INGREDIENTS Ingredient name and classification CAS number Percentage ,3'-Oxybis(ethyleneoxy)bis (propylamine) EU Number: EINECS Vendor Classification: C: R34; R52/53 2,4,6-Tris(dimethylaminomethyl) phenol EU Number: EINECS EU Classification: Xn: R22; Xi: R36/38 Synthetic amorphous silica, fumed,

3 crystalline free Titanium dioxide EU Number: EINECS Bis(dimethylamino)methylphenol EU Number: EINECS Vendor Classification: C: R34 4 FIRST-AID MEASURES Eye Contact: Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention. 4.2 Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water for at least 15 minutes. Get immediate medical attention. Wash contaminated clothing and shoes before reuse. 4.3 Inhalation: If signs/symptoms develop, remove person to fresh air. If signs/symptoms persist, get medical attention. 4.4 Ingestion: Do not induce vomiting. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get immediate medical attention. 5 FIRE-FIGHTING MEASURES Suitable Extinguishing Media: Use fire extinguishers with class B extinguishing agents (e.g. dry chemical, carbon dioxide). 5.2 Unsuitable Extinguishing Media: Not specified. 5.3 Exposure Hazards: No unusual fire or explosion hazards are anticipated. 5.4 Combustion Products from Fire: 5.5 Fire-Fighting Procedures: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Water may be used to blanket the fire. Wear full protective equipment and a self-contained breathing apparatus. 6 ACCIDENTAL RELEASE MEASURES Personal Precautions: Please observe precautions from other sections of this MSDS. 6.2 Methods for Cleaning up: Ventilate the area with fresh air. Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Working from around the edges of the spill inward, cover with

4 bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapours, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapours in the spill area to burn or explode. Collect as much of the spilled material as possible. Clean up residue with an appropriate solvent selected by a qualified and authorised person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and MSDS. Collect the resulting residue containing solution. Place in a closed container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible. 7 HANDLING AND STORAGE Precautions for Safe Handling: Avoid eye contact. Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep container tightly closed. Avoid inhalation of vapours, mists or spray. Avoid skin contact. Avoid breathing of dust created by cutting, sanding, grinding or machining. For industrial or professional use only. Avoid contact with oxidising agents. 7.2 Precautions for Safe Storage: Keep container closed when not in use. - Ventilation: Keep container in a well-ventilated area. - Incompatible Materials/Conditions: Store away from acids. Store away from heat. Store out of direct sunlight. Store away from oxidising agents. 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Recommended Ventilation: Provide appropriate local exhaust for cutting, grinding, sanding or machining. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control dust, fume, or airborne particles. If ventilation is not adequate, use respiratory protection equipment. 8.2 Exposure Limits: Titanium dioxide ( ) HSE WEL TWA: 10 mg/m3 (total inhalable) 4 mg/m3 (respirable) 8.3 Exposure Controls: Eye Protection: Avoid eye contact. The following should be worn alone or in combination, as appropriate, to prevent eye contact: Safety glasses with side shields. Indirect vented goggles Hand Protection:

5 The following glove material(s) are recommended: Polyethylene or ethylene vinyl alcohol Skin Protection: Avoid skin contact Respiratory Protection: Avoid inhalation of vapours, mists or spray. Avoid breathing of dust created by cutting, sanding, grinding or machining. Select one of the following approved respirators based on airborne concentration of contaminants and in accordance with regulations: Half facepiece or fullface air-purifying respirator with organic vapour cartridges and P2 particulate prefilters. Half facepiece or fullface air-purifying respirator with organic vapour cartridges and P2 particulate prefilters. Half facepiece or fullface air-purifying respirator with organic vapour cartridges and P3 particulate prefilters Ingestion: Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep out of the reach of children. 9 PHYSICAL AND CHEMICAL PROPERTIES Appearance and Odour: White paste with amine odour. - ph: Not applicable - Boiling point/boiling range: >= 139 0C - Melting point/melting range: Not determined - Flash point: >= C (CC) - Autoflammability: Not applicable - Flammable Limits - LEL: Not applicable - Flammable Limits - UEL: Not applicable - Vapour pressure: Not applicable - Water Solubility: Negligible - Specific gravity: 1.1 (Water=1) - Vapour density: Not applicable - Volatile organic compounds: Not applicable - Evaporation rate: Not applicable - Viscosity: mpa.s (at 23 :C) - Percent Volatile: 0 % 10 STABILITY AND REACTIVITY Stability and Reactivity: Stable. Hazardous polymerisation will not occur Conditions to Avoid: None known.

6 10.3 Materials to Avoid: Strong oxidising agents. Strong acids Hazardous Decomposition: Under recommended usage conditions, hazardous decomposition products are not expected. Hazardous decomposition products may occur as a result of oxidation, heating, or reaction with another material. 11 TOXICOLOGICAL INFORMATION Effects from Eye Contact: - Corrosive (Eye Burns): Signs/symptoms may include cloudy appearance of the cornea, chemical burns, severe pain, tearing, ulcerations, significantly impaired vision or complete loss of vision. - Vapours released during curing may cause eye irritation. Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. - Dust created by cutting, grinding, sanding, or machining may cause eye irritation. Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision Effects from Skin Contact: - Corrosive (Skin Burns): Signs/symptoms may include localised redness, swelling, itching, intense pain, blistering, ulceration, and tissue destruction Effects from Inhalation: - Vapours released during curing may cause irritation of the respiratory system. Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. - Dust from cutting, grinding, sanding or machining may cause irritation of the respiratory system. Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, nose and throat pain Effects from Ingestion: - Gastrointestinal Corrosion: Signs/symptoms may include severe mouth, throat and abdominal pain, nausea, vomiting, and diarrhea; blood in the faeces and/or vomitus may also be seen. - May cause chemical gastrointestinal burns Other Effects and Information: Not specified. 12 ECOLOGICAL INFORMATION Environmental Data: 12.2 Mobility in Soil and Water: 12.3 Persistence/Biodegradability: 12.4 Bioaccumulation Potential:

7 12.5 Ecotoxicity Data: 12.6 Ecofate Data: 12.7 Special statements for 2001/58/EC: One or more components of this product have significant known or predicted environmental hazards, but a conservative assessment indicates a low environmental risk. Intended use and proper disposal are unlikely to cause the environmentally hazardous component(s) to enter the environment in quantities or by routes that could cause the adverse environmental impacts. 13 DISPOSAL CONSIDERATIONS Product as Sold: Cure (harden, set, or react) the product according to product instructions. Dispose of completely cured (or polymerised) wastes in a sanitary landfill. As a disposal alternative, incinerate in an industrial or commercial facility in the presence of a combustible material Product in Use: 13.3 Product after Use: 13.4 Product Packaging: 13.5 Potential for Recycling: 13.6 Special Instructions: Since regulations vary, consult applicable regulations or authorities before disposal. 14 TRANSPORT INFORMATION Transport Details: Please see the Annex to this document in which all transportation information is given. 15 REGULATORY INFORMATION Label Version Number: Symbol(s): C Corrosive. Risk Phrases: R34 Causes burns. R52/53 Harmful to aquatic organisms. May cause long-term adverse effects in the aquatic environment. Safety Phrases: S51 Use only in well ventilated areas. S23A Do not breathe vapour. S22 Do not breathe dust. S24/25 Avoid contact with the skin and eyes.

8 S36/37/39B Wear suitable protective clothing, gloves, and eye and face protection. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28C After contact with skin, wash immediately with plenty of water for 15 minutes. S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S61 Avoid release to the environment. Refer to special instructions/safety data sheets. Disclosable Ingredients: 3,3'-Oxybis(ethyleneoxy)bis(propylamine) Product Certifications: EINECS. 16 OTHER INFORMATION Complete list of risk phrases: R22 Harmful if swallowed. R34 Causes burns. R36 Irritating to eyes. R38 Irritating to skin. R43 May cause sensitisation by skin contact. R52 Harmful to aquatic organisms. R53 May cause long-term adverse effects in the aquatic environment Limitations on Use of Product: For industrial or professional use only Reissue date/reason for reissue: Updated transport section Regulatory Information: The following UK Regulations as amended may affect the product as supplied: The Chemicals (Hazard Information and Packaging for supply) Regulations, as amended; The Carriage of Dangerous Goods (Classification, Packaging and Labelling) and use of Transportable Pressure Receptacles Regulations 1996, as amended; The Control of Substances Hazardous to Health Regulations 1999 as amended; The Special Waste Regulations 1996, as amended; The Environmental Protection Act, 1990, as amended; The Health and Safety at Work Act, 1974, as amended. The information on this Safety Data Sheet is based on our experience and is correct to the best of our knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use (except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of the product in combination with other materials. For these reasons, it is important that customers carry out their own test to satisfy themselves as to the suitability of the product for their own intended applications.

9 M Scotch-Weld 7236 Structural Epoxy Adhesive (Part B) Base 1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY/UNDERTAKING Tradename: 3M Scotch-Weld 7236 Structural Epoxy Adhesive (Part B) Base 1.2 Intended Use of Product: Part of a structural adhesive for industrial applications M Product ID: Component only. This can only be purchased as part of a kit. 1.4 Contact Address: 3M UK PLC 3M Centre, Cain Road, Bracknell, Berkshire, RG12 8HT 3M Ireland 3M House, Adelphi Centre, Dun Laoghaire, Co. Dublin 1.5 Address and Emergency Contact Number: tox.uk@mmm.com +44 (0) HAZARDS IDENTIFICATION Risk Phrases: R36/38 Irritating to eyes and skin. R43 May cause sensitisation by skin contact. R51/53 Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. 3 COMPOSITION/INFORMATION ON INGREDIENTS Ingredient name and classification CAS number Percentage Epoxy resin (reaction product bisphenol A - epichlorhydrin, MW<700) EU Number: NLP EU Classification: Xi: R36/38; R43; N: R51-53 Calcium carbonate EU Number: EINECS Methylmethacrylate - butadiene - Trade Secret 7-13 styrene terpolymer Synthetic amorphous silica, fumed, crystalline free 3-(2,3-Epoxypropoxy)propyl trimethoxysilane EU Number: EINECS Vendor Classification: N: R51/53 3M Classification: Xi: R FIRST-AID MEASURES Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. 4.2 Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and shoes before reuse.

10 4.3 Inhalation: If signs/symptoms develop, remove person to fresh air. If signs/symptoms persist, get medical attention. 4.4 Ingestion: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. 5 FIRE-FIGHTING MEASURES Suitable Extinguishing Media: Use fire extinguishers with class B extinguishing agents (e.g. dry chemical, carbon dioxide). 5.2 Unsuitable Extinguishing Media: Not specified. 5.3 Exposure Hazards: No unusual fire or explosion hazards are anticipated. 5.4 Combustion Products from Fire: 5.5 Fire-Fighting Procedures: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Water may be used to blanket the fire. Wear full protective equipment and a self-contained breathing apparatus. 6 ACCIDENTAL RELEASE MEASURES Personal Precautions: Please observe precautions from other sections of this MSDS. 6.2 Methods for Cleaning up: Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapours, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapours in the spill area to burn or explode. Contain spill. Collect as much of the spilled material as possible. Clean up residue with an appropriate solvent selected by a qualified and authorised person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and MSDS. Collect the resulting residue containing solution. Place in a closed container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible. 7 HANDLING AND STORAGE Precautions for Safe Handling: Avoid eye contact. Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep container tightly closed. Avoid inhalation of vapours, mists or spray. Avoid skin contact. Avoid breathing of dust created by

11 cutting, sanding, grinding or machining. For industrial or professional use only. Avoid contact with oxidising agents. 7.2 Precautions for Safe Storage: Keep container closed when not in use. - Ventilation: Keep container in a well-ventilated area. - Incompatible Materials/Conditions: Store away from acids. Store away from oxidising agents. 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Recommended Ventilation: Provide appropriate local exhaust for cutting, grinding, sanding or machining. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below

===================================================================== === Safety Data Sheet

3M United Kingdom Plc 3M Centre Cain Road BRACKNELL Berkshire RG12 8HT UNITED KINGDOM ===================================================================== === Safety Data Sheet =====================================================================