SAFETY DATA SHEET. Creation Date 15-Dec-2011 Revision Date 23-May-2017 Revision Number 3 AC ; AC ; AC ; AC

Transcription

1 SAFETY DATA SHEET Creation Date 15-Dec-2011 Revision Number 3 Product Name Cat No. : Synonyms Recommended Use Uses advised against 1. Identification Ethylenediaminetetraacetic acid AC ; AC ; AC ; AC (Ethylenedinitrilo)tetraacetic acid; EDTA; Edetic acid; Diaminoethanetetraacetic acid Laboratory chemicals. Not for food, drug, pesticide or biocidal product use Details of the supplier of the safety data sheet Company Fisher Scientific One Reagent Lane Fair Lawn, NJ Tel: (201) Acros Organics One Reagent Lane Fair Lawn, NJ Emergency Telephone Number For information US call: ACROS-01 / Europe call: Emergency Number US: / Europe: CHEMTREC Tel. No.US: / Europe: Hazard(s) identification Classification This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR ) Acute Inhalation Toxicity - Dusts and Mists Category 4 Serious Eye Damage/Eye Irritation Category 2 Specific target organ toxicity - (repeated exposure) Category 2 Target Organs - Respiratory system. Label Elements Signal Word Warning Hazard Statements Causes serious eye irritation Harmful if inhaled May cause damage to organs through prolonged or repeated exposure Page 1 / 7

2 Precautionary Statements Prevention Use only outdoors or in a well-ventilated area Wash face, hands and any exposed skin thoroughly after handling Wear eye/face protection Do not breathe dust/fume/gas/mist/vapors/spray Response Get medical attention/advice if you feel unwell Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Call a POISON CENTER or doctor/physician if you feel unwell Eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention Storage Store in a well-ventilated place. Keep container tightly closed Store locked up Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) None identified 3. Composition / information on ingredients Component CAS-No Weight % Ethylenediamine tetraacetic acid (EDTA) First-aid measures General Advice Eye Contact Skin Contact Inhalation Ingestion Most important symptoms/effects Notes to Physician Suitable Extinguishing Media Unsuitable Extinguishing Media If symptoms persist, call a physician. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Obtain medical attention if irritation persists. Wash off immediately with plenty of water for at least 15 minutes. If skin irritation persists, call a physician. Move to fresh air. If not breathing, give artificial respiration. Get medical attention if symptoms occur. Clean mouth with water and drink afterwards plenty of water. Get medical attention if symptoms occur. None reasonably foreseeable. Treat symptomatically 5. Fire-fighting measures Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Flash Point > 100 C / > 212 F Method - Autoignition Temperature 200 C / 392 F Page 2 / 7

3 Explosion Limits Upper Lower Sensitivity to Mechanical Impact Sensitivity to Static Discharge Specific Hazards Arising from the Chemical Thermal decomposition can lead to release of irritating gases and vapors. Keep product and empty container away from heat and sources of ignition. Hazardous Combustion Products Nitrogen oxides (NOx) Carbon monoxide (CO) Carbon dioxide (CO2) Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. NFPA Health 2 Flammability 1 Instability 0 Physical hazards - Personal Precautions Environmental Precautions 6. Accidental release measures Use personal protective equipment. Ensure adequate ventilation. Avoid dust formation. Should not be released into the environment. Do not flush into surface water or sanitary sewer system. Methods for Containment and Clean Sweep up or vacuum up spillage and collect in suitable container for disposal. Up Handling Storage Exposure Guidelines 7. Handling and storage Wear personal protective equipment. Ensure adequate ventilation. Avoid dust formation. Avoid ingestion and inhalation. Do not get in eyes, on skin, or on clothing. Keep in a dry, cool and well-ventilated place. Keep container tightly closed. 8. Exposure controls / personal protection This product does not contain any hazardous materials with occupational exposure limitsestablished by the region specific regulatory bodies. Engineering Measures Ensure adequate ventilation, especially in confined areas. Ensure that eyewash stations and safety showers are close to the workstation location. Personal Protective Equipment Eye/face Protection Skin and body protection Respiratory Protection Hygiene Measures Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR or European Standard EN166. Long sleeved clothing. Follow the OSHA respirator regulations found in 29 CFR or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Handle in accordance with good industrial hygiene and safety practice. Page 3 / 7

4 9. Physical and chemical properties Physical State Powder Solid Appearance White Odor Odorless Odor Threshold ph g/l (23 C) Melting Point/Range 220 C / 428 F Boiling Point/Range Flash Point > 100 C / > 212 F Evaporation Rate Flammability (solid,gas) Flammability or explosive limits Upper Lower Vapor Pressure C Vapor Density Specific Gravity 20 C Solubility 0.5 g/l (20 C) g/l (80 C) Partition coefficient; n-octanol/water Autoignition Temperature 200 C / 392 F Decomposition Temperature > 150 C Viscosity Molecular Formula C10 H16 N2 O8 Molecular Weight Stability and reactivity Reactive Hazard Stability Conditions to Avoid Incompatible Materials None known, based on information available Stable under normal conditions. Avoid dust formation. Incompatible products. Excess heat. Strong oxidizing agents, Strong bases, Metals, copper Hazardous Decomposition Products Nitrogen oxides (NOx), Carbon monoxide (CO), Carbon dioxide (CO2) Hazardous Polymerization Hazardous Reactions Acute Toxicity Hazardous polymerization does not occur. None under normal processing. 11. Toxicological information Product Information Component Information Component LD50 Oral LD50 Dermal LC50 Inhalation Ethylenediamine tetraacetic acid 4500 mg/kg ( Rat ) Not listed 1 mg/l (rat) (EDTA) >2000 mg/kg ( Rat ) Toxicologically Synergistic Products Delayed and immediate effects as well as chronic effects from short and long-term exposure Irritation Sensitization Carcinogenicity Irritating to eyes The table below indicates whether each agency has listed any ingredient as a carcinogen. Page 4 / 7

5 Component CAS-No IARC NTP ACGIH OSHA Mexico Ethylenediamine tetraacetic acid (EDTA) Not listed Not listed Not listed Not listed Not listed Mutagenic Effects Reproductive Effects Developmental Effects Teratogenicity STOT - single exposure STOT - repeated exposure Aspiration hazard Symptoms / effects,both acute and delayed Endocrine Disruptor Information Other Adverse Effects... None known Respiratory system The toxicological properties have not been fully investigated. 12. Ecological information Ecotoxicity Contains no substances known to be hazardous to the environment or that are not degradable in waste water treatment plants. Component Freshwater Algae Freshwater Fish Microtox Water Flea EC50: = 1.01 mg/l, 72h Not listed (Desmodesmus subspicatus) Ethylenediamine tetraacetic acid (EDTA) LC50: mg/l, 96h static (Pimephales promelas) LC50: mg/l, 96h static (Lepomis macrochirus) EC50: = 113 mg/l, 48h Static (Daphnia magna) Persistence and Degradability Bioaccumulation/ Accumulation Mobility Waste Disposal Methods DOT TDG IATA IMDG/IMO Soluble in water Persistence is unlikely based on information available.. Will likely be mobile in the environment due to its water solubility. 13. Disposal considerations Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. Chemical waste generators must also consult local, regional, and national hazardous waste regulations to ensure complete and accurate classification. 14. Transport information 15. Regulatory information All of the components in the product are on the following Inventory lists: X = listed International Inventories Component TSCA DSL NDSL EINECS ELINCS NLP PICCS ENCS AICS IECSC KECL Ethylenediamine tetraacetic X X X X X X X Page 5 / 7

6 acid (EDTA) Legend: X - Listed E - Indicates a substance that is the subject of a Section 5(e) Consent order under TSCA. F - Indicates a substance that is the subject of a Section 5(f) Rule under TSCA. N - Indicates a polymeric substance containing no free-radical initiator in its inventory name but is considered to cover the designated polymer made with any free-radical initiator regardless of the amount used. P - Indicates a commenced PMN substance R - Indicates a substance that is the subject of a Section 6 risk management rule under TSCA. S - Indicates a substance that is identified in a proposed or final Significant New Use Rule T - Indicates a substance that is the subject of a Section 4 test rule under TSCA. XU - Indicates a substance exempt from reporting under the Inventory Update Rule, i.e. Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40 CFR 710(B). Y1 - Indicates an exempt polymer that has a number-average molecular weight of 1,000 or greater. Y2 - Indicates an exempt polymer that is a polyester and is made only from reactants included in a specified list of low concern reactants that comprises one of the eligibility criteria for the exemption rule. U.S. Federal Regulations TSCA 12(b) SARA 313 SARA 311/312 Hazard Categories Acute Health Hazard Chronic Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard Yes Yes No No No CWA (Clean Water Act) Component Ethylenediamine tetraacetic acid (EDTA) Clean Air Act CWA - Hazardous Substances CWA - Reportable Quantities CWA - Toxic Pollutants CWA - Priority Pollutants X 5000 lb - - OSHA Occupational Safety and Health Administration CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Component Hazardous Substances RQs CERCLA EHS RQs Ethylenediamine tetraacetic acid (EDTA) 5000 lb - California Proposition 65 This product does not contain any Proposition 65 chemicals U.S. State Right-to-Know Regulations Component Massachusetts New Jersey Pennsylvania Illinois Rhode Island Ethylenediamine tetraacetic acid (EDTA) X X X - - U.S. Department of Transportation Reportable Quantity (RQ): DOT Marine Pollutant DOT Severe Marine Pollutant N N N U.S. Department of Homeland Security Page 6 / 7

7 This product does not contain any DHS chemicals. Other International Regulations Mexico - Grade Prepared By Creation Date Revision Date Print Date Revision Summary 16. Other information Regulatory Affairs Thermo Fisher Scientific EMSDS.RA@thermofisher.com 15-Dec May May-2017 This document has been updated to comply with the US OSHA HazCom 2012 Standard replacing the current legislation under 29 CFR to align with the Globally Harmonized System of Classification and Labeling of Chemicals (GHS). Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of SDS Page 7 / 7