2. HAZARDS IDENTIFICATION. Contact with eyes may cause irritation. Prolonged skin contact may cause skin irritation.

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1 Distributed by: Lmitas Ave City f Industry, CA Laguna inf@lagunaclay.cm WNW.lagunaclay.cm MATERIAL SAFETY DATA SHEET FEAAO Ferr Crpratin 4150 East 56th Street Cleveland, Ohi USA Emergency telephne number CHEMTREC: CHEMTREC (utside U.S.): Plant Number: I. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Prduct Name: Chemical Name: Synnym CAS-N.: Frmula: Prduct Cde: CC250-2 Glaze Frit, leadless 50 lb Date f Preparatin: 10/25/2011 bag Frit Glassy mixture f particle size reductin after milling TSCA Descriptin: "Frit is a mixture f inrganic chemical substances prduced by rapidly quenching a mlten, cmplex cmbinatin f materials, cnfining the chemical substances thus manufactured as nn-migratry cmpnents f glassy slid flakes r granules." HAZARDS IDENTIFICATION Emergency Overview Warning May cause respiratry tract, eye and skin irritatin. D nt breathe vapursldusl. Cntains crystalline silica which causes silicsis and lung cancer. Clr: Physical state: Odr: White Pwder Odrless HMIS 2' E NFPA Ptential Health Effects Principle rutes f expsure: Eye cntact: Skin cntact: Inhalatin: Ingestin: Chrnic txicity: Inhalatin, ingestin, skin and eye cntact. Cntact with eyes may cause irritatin. Prlnged skin cntact may cause skin irritatin. Dust r fumes frm firing irritating t respiratry tract. Fumes may cause lung inflammatin. May irritate digestive tract. Excessive inhalatin f fumes r dust may cause chemical pneumnitis, cyansis, and pulmnary edema. Respirable crystalline silica has been classified as a Grup I (sufficient evidence in humans fr carcingenicity) carcingenic by IARC and is listed by NTP as a substance which may reasnably be anticipated t be a carcingen. lng term inhalatin causes lung damage (silicsis and cancer). 3. COMPOSITION/INFORMATION ON INGREDIENTS Cm nents Frit" CAS Number Wei ht % 100% Ma cntain - see belw <0.5% Prduct name: CC250 2 Glaze Frit, Leadless 50 Lb bag Page 1 f5

2 The specific chemical identities are being withheld as a trade secret (29CFR ). * Frit, with CAS # [ ], is a mixture f inrganic chemical substances prduced by rapidly quenching a mlten, cmplex cmbinatin f materials, cnfining the chemical substances thus manufactured as nn-migratry cmpnents f glassy slid flakes r granules. These cmpnents are present as part f the Frit. 4. FIRST AID MEASURES Eye cntact: Skin cntact: Inhalatin: Ingestin: Ntes t physician: Rinse thrughly with plenty f water, als under the eyelids. Get medical attentin if irritatin develps. Wash ff immediately with sap and plenty f water. Get medical attentin if irritatin develps. Mve t fresh air. If breathing is difficult, give xygen. If symptms persist, call a physician. Drink plenty f water. D nt induce vmiting. Cnsull a physician if necessary. Treat symptmatically. 5. FIRE-FIGHTING MEASURES Flash pint (~C): Nn cmbustible Suitable extinguishing media: Hazardus decmpsitin prducts: Special prtective equipment fr firefighters: Unusual hazards: The prduct itself des nt burn. Use extinguishing measures that are apprpriate t lcal circumstances and the surrunding envirnment. Thermal decmpsitin can lead t release f irritating gases and vaprs. Heavy metal cmpunds. As in any fire, wear self-cntained breathing apparatus (pressure-demand, NIOSH apprved r equivalent) and full prtective gear. Nne knwn. 6. ACCIDENTAL RELEASE MEASURES Persnal precautins: Envirnmental precautins: Methds fr cleaning up: Avid dust frmatin. D nt breathe vaprs/dust. Avid cntact with skin, eyes and clthing. Use persnal prtective equipment. Ensure adequate ventilatin. Prevent further leakage r spillage if safe t d s. Prevent prduct frm entering drains. D nt flush int surface water r sanitary sewer system. Wear persnal prtective equipment. Use apprved industrial vacuum cleaner fr remval. Clean cntaminated surface thrughly. Dispse f prmptly. 7. HANDLING AND STORAGE Handling: Handle in accrdance with gd industrial hygiene and safety practice. Use nly in area prvided with apprpriate exhaust ventilatin. In case f insufficient ventilatin, wear suitable respiratry equipment. Avid cntact with skin, eyes and clthing. D nt eat, drink, r smke in areas f use r strage. Strage: Keep in a dry, cl and well-ventilated place. Expsure limits Minimize expsure in accrdance with gd hygiene practice. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Prduct name: CC250-2 Gla;z:e Frit, Leadless 50 Lb bag Page 2 f 5

3 Cm nents OSHA ACG1H Frit 0.5 mglm J TWA Sb 0.5 mglm 3 TWA Sb 5 mg/m 3 TWA Zr 5 mglm 3 TWA Zr 5 mnim 3 Ceilinn Mn 0.2 m-;"'m 3 TWA Mn listed m 1m 3 TWA res irable fractin Engineering measures: Prvide apprpriate exhaust ventilatin at machinery and at places where dust r fumes can be generated. Ensure that eyewash statins and safety shwers are prximal t the wrkstatin lcatin. Eye prtectin: Skin and bdy prtectin: Hand prtectin: Respiratry prtectin: Hygiene measures: Safety glasses with side-shields. lightweight prtective clthing. Keep wrking clthes separately. Remve and wash cntaminated clthing befre re-use. Impervius glves. In case f insufficient ventilatin wear suitable respiratry equipment. Seek prfessinal advice prir t respiratr selectin and use. NIOSH-apprved respiratrs shuld be wrn where engineering cntrls and wrk practices d nt reduce expsure t r belw the PEL. Wash hands befre breaks and at the end f wrkday. Wash cntaminated clthing befre reuse. 9. PHYSICAL AND CHEMICAL PROPERTIES Clr: Odr: Biling pint/range (0C): Melting pint/range (OC): Vapr density: Evapratin Rate (Water = 1) VOC cntent (%) White Odrless Nn-vlatile Nn-vlatile Physical state: Mlecular weight: ph: Specific gravity (Water =1): Vapr pressure: Water slubility: Pwder Insluble 10. STABILITY AND REACTIVITY Stability: Plymerizatin Stable at nrmal cnditins. Will nt ccur. Hazardus decmpsitin prducts: N decmpsitin if stred nrmally. Thermal decmpsitin can lead t release f irritating gases and vaprs. Materials t avid: Cnditins t avid Nne knwn. Nne knwn. 11. TOXlCOLOGICAL INFORMATION Acute txicity: Chrnic Txicity: Carcingenic Effects: Target Organ Effects: Infrmatin given is based n data n the cmpnents and the txiclgy f similar prducts. Cntains crystalline silica which causes silicsis and lung cancer. Respirable crystalline silica has been classified as a Grup I (sufficient evidence in humans fr carcingenicity) carcingenic by IARC and is listed by NTP as a substance which may reasnably be anticipated t be a carcingen. Crystalline silica is als a knwn cause f silicsis, a nn-cancerus lung disease caused by excessive expsure t crystalline silica. Silica: Respiratry system. Cmpnent infrmatin, if any, is listed belw Prduct name: CC250 2 Glaze Frit, Leadless 50 Lb bag Page 3 f 5

4 Frit L050s and LC50s: OSHA - Select Carcingens: NTP; NTPS. Carcingen: 1ARC Grup 1: IARC - Grup 2A: IARC Grup 28; L050s and LC50s: OSHA - Select Carcingens: NTP; 1ARC Grup 1: Oral LD50 (Rat) = 2000 mg/kg Present Knwn Human Carcingen Reasnably Anticipated T Be A Human Carcingen Oral LD50 (Rat) = 500 mg/kg Present Knwn Human Carcingen 12. ECOLOGICAL INFORMATION Aquatic txicity: Persistence and degradability: N data is available n the prduct itself. Infrmatin given is based n data n the cmpnents and the ectxiclgy f similar prducts. N infrmatin available. 13. DISPOSAL CONSIDERATIONS Waste frm residues I unused prducts: I DOT (U.S.) Prper shipping name: Waste must be dispsed f in accrdance with federal, state and lcal envirnmental cntrl regulatins. Where pssible recycling is preferred t dispsal r incineratin. Nt regulated. 14. TRANSPORT INFORMATION TOG (Canada) Prper shipping name: Nt regulated. u.s. Regulatins: TSCA: 15. REGULATORY INFORMATION Nt SUbject t TSCA 12(b) Exprt Ntificatin SARA 313: Nt subject t the prvisins f SARA 313 Title III State Regulatins This prduct r its ingredients have been evaluated fr New Jersey, Pennsylvania, and Califmia Prp 65 supplier ntificatin requirements. Substances that are subject t ntificatin requirements, if any, are listed belw. Cm nenls Cm nents NJRTK: NJRTK State Re ulatin - CA Pr 65 Carcin en Canadian WHMIS WHM1$ hazard class: D2A Very txic materials Prduct name: CC250 2 Glai:e Frit, Leadless 50 Lb bag Page 4 f 5

5 internatjnallnventries TseA 8(b), Canadian OSUNOSl list EC N. Philippines (PICCS): Japan (ENCS): Krea (KECl): China (IECS): Australia (AICS): New Zealand (NZlC): r exempt. All ingredient(s) are listed n the DSL r NDSL r exempt. r exempt. 16. OTHER INFORMATION Fr Industrial Use Only. Prepared by: Ferr Technical Center Disclaimer: The infrmatin and recmmendatins cntained in this Material Safety Data Sheet have been cmpiled frm surces believed t be reliable and t represent the mst reasnable current pinin n the subject when the MSDS was prepared. N warranty, guaranty r representatin is made as t the crrectness r sufficiency f the infrmatin. The user f this prduct must decide what safety measures are necessary t safely use this prduct, either alne r in cmbinatin with ther prducts, and determine its envirnmental regulatry cmpliance bligatins under any applicable federal r state laws. End f Safety Data Sheet Distributed by: Lmitas Ave City f Industry, CA L,gun, inf@lagunaclay.cm wwwjagunaclay.cm Laguna inf@lagunaelay.em Prduct name: CC250-2 Glaze Frit, Leadless 50 Lb bag Page 5 f 5