SAFETY DATA SHEET. Creation Date 24-Nov-2010 Revision Date 19-Jan-2018 Revision Number 3

Transcription

1 SAFETY DATA SHEET Creation Date 24-Nov-2010 Revision Number 3 Product Name Cat No. : 1. Identification Manganese, powder, -325 mesh AC ; AC ; AC CAS-No Synonyms Recommended Use Uses advised against Laboratory chemicals. Not for food, drug, pesticide or biocidal product use Details of the supplier of the safety data sheet Company Fisher Scientific One Reagent Lane Fair Lawn, NJ Tel: (201) Acros Organics One Reagent Lane Fair Lawn, NJ Emergency Telephone Number For information US call: ACROS-01 / Europe call: Emergency Number US: / Europe: CHEMTREC Tel. No.US: / Europe: Hazard(s) identification Classification This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR ) Flammable solids Category 2 Serious Eye Damage/Eye Irritation Category 2 Label Elements Signal Word Warning Hazard Statements Flammable solid Causes serious eye irritation Page 1 / 7

2 Precautionary Statements Prevention Wash face, hands and any exposed skin thoroughly after handling Keep away from heat/sparks/open flames/hot surfaces. - No smoking Ground/bond container and receiving equipment Use explosion-proof electrical/ventilating/lighting/equipment Wear protective gloves/protective clothing/eye protection/face protection Eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention Fire In case of fire: Use CO2, dry chemical, or foam for extinction Hazards not otherwise classified (HNOC) None identified 3. Composition/Information on Ingredients Component CAS-No Weight % Manganese >95 4. First-aid measures Eye Contact Skin Contact Inhalation Ingestion Most important symptoms and effects Notes to Physician Suitable Extinguishing Media Unsuitable Extinguishing Media Flash Point Method - Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention. Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Obtain medical attention. Remove from exposure, lie down. Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Obtain medical attention. Clean mouth with water. Get medical attention.. Treat symptomatically 5. Fire-fighting measures Dry chemical. Autoignition Temperature Explosion Limits Upper Lower Sensitivity to Mechanical Impact Sensitivity to Static Discharge Specific Hazards Arising from the Chemical Combustible material. Hazardous Combustion Products None known Page 2 / 7

3 Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. NFPA Health 2 Flammability 2 Instability 0 Physical hazards N/A Personal Precautions Environmental Precautions 6. Accidental release measures Ensure adequate ventilation. Use personal protective equipment. See Section 12 for additional ecological information. Methods for Containment and Clean Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. Up Sweep up or vacuum up spillage and collect in suitable container for disposal. Handling Storage Exposure Guidelines 7. Handling and storage Avoid contact with skin and eyes. Do not breathe dust. Use explosion-proof equipment. Use only non-sparking tools. Keep in a dry, cool and well-ventilated place. Keep container tightly closed. Keep away from heat and sources of ignition. Keep under nitrogen. 8. Exposure controls / personal protection Component ACGIH TLV OSHA PEL NIOSH IDLH Mexico OEL (TWA) Manganese TWA: 0.02 mg/m 3 TWA: 0.1 mg/m 3 (Vacated) TWA: 1 mg/m 3 Ceiling: 5 mg/m 3 (Vacated) STEL: 3 mg/m 3 (Vacated) Ceiling: 5 mg/m 3 IDLH: 500 mg/m 3 TWA: 1 mg/m 3 STEL: 3 mg/m 3 TWA: 0.2 mg/m 3 TWA: 1 mg/m 3 STEL: 3 mg/m 3 Legend ACGIH - American Conference of Governmental Industrial Hygienists OSHA - Occupational Safety and Health Administration NIOSH IDLH: The National Institute for Occupational Safety and Health Immediately Dangerous to Life or Health Engineering Measures Ensure adequate ventilation, especially in confined areas. Personal Protective Equipment Eye/face Protection Skin and body protection Respiratory Protection Hygiene Measures Physical State Appearance Odor Odor Threshold ph Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR or European Standard EN166. Wear appropriate protective gloves and clothing to prevent skin exposure. No protective equipment is needed under normal use conditions. Handle in accordance with good industrial hygiene and safety practice. 9. Physical and chemical properties Powder Solid Dark brown Page 3 / 7

4 Melting Point/Range 1260 C / 2300 F Boiling Point/Range 1900 C / 3452 F Flash Point Evaporation Rate Flammability (solid,gas) Flammability or explosive limits Upper Lower Vapor Pressure Vapor Density Specific Gravity Solubility Partition coefficient; n-octanol/water Autoignition Temperature Decomposition Temperature Viscosity Molecular Formula Mn Molecular Weight Stability and reactivity Reactive Hazard Stability Conditions to Avoid Incompatible Materials None known, based on information available Moisture sensitive. Incompatible products. Exposure to moisture. Acids, Bases, Halogens Hazardous Decomposition Products None under normal use conditions Hazardous Polymerization Hazardous Reactions Acute Toxicity Hazardous polymerization does not occur. None under normal processing. 11. Toxicological information Product Information Component Information Component LD50 Oral LD50 Dermal LC50 Inhalation Manganese LD50 = 9 g/kg ( Rat ) Not listed Not listed Toxicologically Synergistic Products Delayed and immediate effects as well as chronic effects from short and long-term exposure Irritation Sensitization Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Component CAS-No IARC NTP ACGIH OSHA Mexico Manganese Not listed Not listed Not listed Not listed Not listed Mutagenic Effects Reproductive Effects Developmental Effects.. Page 4 / 7

5 Teratogenicity STOT - single exposure STOT - repeated exposure Aspiration hazard Symptoms / effects,both acute and delayed Endocrine Disruptor Information Other Adverse Effects Ecotoxicity Do not empty into drains. Persistence and Degradability Bioaccumulation/ Accumulation Mobility Waste Disposal Methods. None known None known The toxicological properties have not been fully investigated. See actual entry in RTECS for complete information. 12. Ecological information Insoluble in water. Is not likely mobile in the environment due its low water solubility. 13. Disposal considerations Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. Chemical waste generators must also consult local, regional, and national hazardous waste regulations to ensure complete and accurate classification. 14. Transport information DOT UN-No UN3089 TDG UN-No UN3089 IATA UN-No 3089 Proper Shipping Name METAL POWDER, FLAMMABLE, N.O.S. IMDG/IMO UN-No 3089 Proper Shipping Name METAL POWDER, FLAMMABLE, N.O.S. International Inventories 15. Regulatory information Component TSCA DSL NDSL EINECS ELINCS NLP PICCS ENCS AICS IECSC KECL Manganese X X X - X X X Legend: X - Listed Page 5 / 7

6 E - Indicates a substance that is the subject of a Section 5(e) Consent order under TSCA. F - Indicates a substance that is the subject of a Section 5(f) Rule under TSCA. N - Indicates a polymeric substance containing no free-radical initiator in its inventory name but is considered to cover the designated polymer made with any free-radical initiator regardless of the amount used. P - Indicates a commenced PMN substance R - Indicates a substance that is the subject of a Section 6 risk management rule under TSCA. S - Indicates a substance that is identified in a proposed or final Significant New Use Rule T - Indicates a substance that is the subject of a Section 4 test rule under TSCA. XU - Indicates a substance exempt from reporting under the Inventory Update Rule, i.e. Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40 CFR 710(B). Y1 - Indicates an exempt polymer that has a number-average molecular weight of 1,000 or greater. Y2 - Indicates an exempt polymer that is a polyester and is made only from reactants included in a specified list of low concern reactants that comprises one of the eligibility criteria for the exemption rule. U.S. Federal Regulations TSCA 12(b) SARA 313 Component CAS-No Weight % SARA Threshold Values % Manganese > SARA 311/312 Hazard Categories CWA (Clean Water Act) See section 2 for more information Clean Air Act Component HAPS Data Class 1 Ozone Depletors Class 2 Ozone Depletors Manganese X - OSHA Occupational Safety and Health Administration CERCLA California Proposition 65 This product does not contain any Proposition 65 chemicals U.S. State Right-to-Know Regulations Component Massachusetts New Jersey Pennsylvania Illinois Rhode Island Manganese X X X X X U.S. Department of Transportation Reportable Quantity (RQ): DOT Marine Pollutant DOT Severe Marine Pollutant N N N U.S. Department of Homeland Security This product does not contain any DHS chemicals. Other International Regulations Mexico - Grade Prepared By 16. Other information Regulatory Affairs Thermo Fisher Scientific EMSDS.RA@thermofisher.com Page 6 / 7

7 Creation Date Revision Date Print Date Revision Summary 24-Nov Jan Jan-2018 This document has been updated to comply with the US OSHA HazCom 2012 Standard replacing the current legislation under 29 CFR to align with the Globally Harmonized System of Classification and Labeling of Chemicals (GHS). Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of SDS Page 7 / 7