Issuing Date: 25-May-2016 Revision Date: 25-May-2016 Version 1 1. IDENTIFICATION. Gillette Clinical Cool Wave Antiperspirant/Deodorant Clear Gel
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1 SAFETY DATA SHEET Issuing Date: 25-May-2016 Version 1 1. IDENTIFICATION Product Name Gillette Clinical Cool Wave Product Identifier Product Type: Recommended Use Manufacturer _RET_NG Finished Product - Consumer (Retail) Use Only Personal Beauty Care Product. The Procter & Gamble Company Sharon Woods Innovation Center Reed Hartman Highway Cincinnati OH Procter & Gamble Inc. P.O. Box 355, Station A Toronto, ON M5W 1C5 Professional Products: ; Retail Products: Address Emergency Telephone pgsds.im@pg.com Transportation (24 HR) CHEMTREC (U.S./ Canada) or Mexico toll free in country: HAZARD IDENTIFICATION "Consumer Products", as defined by the US Consumer Product Safety Act and which are used as intended (typical consumer duration and frequency), are exempt from the OSHA Hazard Communication Standard (29 CFR ). This SDS is being provided as a courtesy to help assist in the safe handling and proper use of the product. This product is classifed under 29CFR (d) and the Canadian Hazardous Products Regulation as follows:. Eye Damage / Irritation Signal Word Category 2B WARNING Hazard Statements Hazard pictograms Causes eye irritation Precautionary Statements Precautionary Statements - Response Wash hands thoroughly after handling IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Page 1 / 7
2 If eye irritation persists: Get medical advice/attention Precautionary Statements - Storage Precautionary Statements - Disposal Hazards not otherwise classified (HNOC) 3. COMPOSITION/INFORMATION ON INGREDIENTS Ingredients are listed according to 29CFR Appendix D and the Canadian Hazardous Products Regulation Chemical Name Synonyms Trade Secret CAS-No Weight % Ethanol Ethanol No Calcium chloride (CaCl2), dihydrate Calcium chloride (CaCl2), dihydrate No First aid measures for different exposure routes 4. FIRST AID MEASURES Eye contact Skin contact Ingestion Inhalation Most important symptoms/effects, acute and delayed IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. under normal use. Not an expected route of exposure. If swallowed:. Clean mouth with water and afterwards drink plenty of water. under normal use. May cause eye irritation. Indication of immediate medical attention and special treatment needed, if necessary Notes to Physician Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Unsuitable Extinguishing Media Special hazard Special protective equipment for fire-fighters Specific hazards arising from the Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.. known. As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.. Page 2 / 7
3 chemical 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Advice for emergency responders under normal use conditions. Use personal protective equipment as required. Methods and materials for containment and cleaning up Methods for containment Methods for cleaning up.. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Conditions for safe storage, including any incompatibilities Storage Conditions Incompatible products Keep containers tightly closed in a dry, cool and well-ventilated place. known. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines. Chemical Name CAS-No ACGIH TLV OSHA PEL Mexico PEL Ethanol STEL: 1000 ppm TWA: 1000 ppm TWA: 1900 mg/m 3 (vacated) TWA: 1000 ppm (vacated) TWA: 1900 mg/m 3 Mexico: TWA 1000 ppm Mexico: TWA 1900 mg/m 3 Chemical Name CAS-No Alberta Quebec Ontario TWAEV British Columbia Ethanol TWA: 1000 ppm TWA: 1000 ppm STEL: 1000 ppm STEL: 1000 ppm TWA: 1880 mg/m 3 TWA: 1880 mg/m 3 Calcium chloride (CaCl2), dihydrate TWA: 5 mg/m 3 No relevant exposure guidelines for other ingredients Exposure controls Engineering Measures Personal Protective Equipment Eye Protection Manufacturing Sites: Wear safety glasses with side shields (or goggles) Distribution, Workplace and Household Settings: Hand Protection Page 3 / 7
4 Skin and Body Protection Respiratory Protection 9. PHYSICAL AND CHEMICAL PROPERTIES Physical C Appearance Odor Odor threshold Solid colorless gel characteristic Property Values Note ph value 3-5 (as 1% solution) Melting/freezing point Boiling point/boiling range Flash point Evaporation rate Flammability (solid, gas) Flammability Limits in Air Upper flammability limit Lower Flammability Limit Vapor pressure Vapor density Relative density Water solubility Partition coefficient: n-octanol/water Autoignition temperature. Decomposition temperature. Viscosity of Product cP VOC Content (%) Products comply with US state and federal regulations for VOC content in consumer products. 10. STABILITY AND REACTIVITY Reactivity Stability Hazardous polymerization Hazardous Reactions Conditions to Avoid Materials to avoid under normal use conditions. Stable under normal conditions. Hazardous polymerization does not occur. under normal processing. under normal processing. in particular. Hazardous Decomposition Products under normal use conditions. Product Information Information on likely routes of exposure 11. TOXICOLOGICAL INFORMATION Inhalation Skin contact Ingestion Eye contact Avoid contact with eyes. Irritating to eyes. Delayed and immediate effects as well as chronic effects from short and long-term exposure Page 4 / 7
5 Acute toxicity Skin corrosion/irritation Serious eye damage/eye irritation Skin sensitization Respiratory sensitization Germ cell mutagenicity Neurological Effects Reproductive toxicity Developmental toxicity Teratogenicity STOT - single exposure STOT - repeated exposure Target Organ Effects Aspiration hazard Carcinogenicity Irritating to eyes. 12. ECOLOGICAL INFORMATION Ecotoxicity The product is not expected to be hazardous to the environment. Persistence and degradability Bioaccumulative potential Mobility Other adverse effects DISPOSAL CONSIDERATIONS Waste treatment Waste from Residues / Unused Products Contaminated packaging California Hazardous Waste Codes (non-household setting) Disposal should be in accordance with applicable regional, national and local laws and regulations. Disposal should be in accordance with applicable regional, national and local laws and regulations TRANSPORT INFORMATION DOT IMDG IATA Not regulated Not regulated Not regulated U.S. Federal Regulations 15. REGULATORY INFORMATION SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Page 5 / 7
6 CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material. Food and Drug Administration (FDA) The product described in this Safety Data Sheet is regulated under the Federal Food, Drug, and Cosmetics Act and is safe to use as per directions on container, box or accompanying literature (where applicable) Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) This product does not contain any substances regulated as hazardous air pollutants (HAPS) under Section 112 of the Clean Air Act Amendments of Clean Water Act This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR and 40 CFR ). California Proposition 65 This product is not subject to warning labeling under California Proposition 65. U.S. State Regulations (RTK). Chemical Name CAS-No New Jersey Propylene glycol X Ethanol X Chemical Name CAS-No Massachusetts Ethanol X Chemical Name CAS-No Pennsylvania Propylene glycol X Ethanol X Dipropylene Glycol X International Inventories United States Product is a personal care product and regulated under FDA. Canada This product is in compliance with CEPA for import by P&G. Legend United States Toxic Substances Control Act Section 8(b) Inventory (TSCA) CEPA - Canadian Environmental Protection Act Perfumes contained with the products comply with appropriate IFRA guidance. 16. OTHER INFORMATION Page 6 / 7
7 Issuing Date: 25-May-2016 Revision Date: 25-May-2016 Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of SDS Page 7 / 7
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