CHEMICAL TRANSPORTATION, INC. HAZMAT SUBSTANCES & WASTE GUIDE WASTE TRANSPORTATION A COMMON SENSE APPROACH

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1 CHEMICAL TRANSPORTATION, INC. HAZMAT SUBSTANCES & WASTE GUIDE WASTE TRANSPORTATION A COMMON SENSE APPROACH

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3 CT, INC. PRESHIPMENT TRANSPORTER CHECKLIST WHERE IS MY WASTE??? US DOT NUMBER DOT FITNESS RATING CONTINGENCY PLAN SERVICE REFERENCES DRIVER TRAINING MATRIX POLLUTION COVERAGE SAFE NET STATISTICS LIST OF PERMITS SECURITY PLAN CRIMINAL HISTORY INSURANCE CERTS. CREDIT CHECK

4 COMPLIANCE GUIDE INDEX DOT HAZMAT REGULATIONS 49 CFR Page Part Description Name and phone number IX-XXII Emergency & regulatory contacts DOT violation assessments Incident notification requirements Hazardous materials tables Hazardous substance reportable quantities EPA waste codes/reportable quantities Shipping papers HAZMAT labeling of containers HAZMAT placarding Employee training Security plans HAZMAT loading & unloading HAZMAT segregation chart Leakers in transit Container standards FMCS driver pocket book Colors Emergency response guidebook

5 DOT ASSESSMENTS & PENALTIES 49 CFR CIVIL VIOLATIONS & PENALTIES Unintentional: (See guideline on page 36) $450 - $15,000 Intentional > $ 50,000 Intentional: (Property damage, injury, death, or release) > $100,000 Intentional: (Container or tanker certifications) > $ 50,000 Intentional: (Certifications with release, injury, or death) > $100,000 CRIMINAL VIOLATIONS & PENALTIES P R I S O N Intentional > 5 YEARS Intentional: (Property damage, injury, death, or release) > 10 YEARS

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7 CHEM. TRANS. INC. 12 HOUR INCIDENT TELEPHONE REPORT CFR RSPA/NRC or FATALITY ROAD CLOSURE/1 HOUR INJURY (requiring hospitalization) AIRCRAFT (flight plan altered) RELEASE (infectious material) RELEASE (radioactive) EVACUATION (1 hour or more) MARINE POLLUTANT (119 gl./882 lb.) > REPORTABLE QUANTITY PROPERTY DAMAGE: > $50,000 Note: CT INCIDENT REPORT REQUIRED WRITTEN REPORT FORM DOT F REQUIRED

8 CHEM. TRANS. INC. DOT FORM F REQUIRED 30 DAY REPORT CFR FOLLOW-UP (all telephonic reports) UNDECLARED SHIPMENT RELEASE (transit, loading, unloading) RELEASE (hazmat storage) SPEC. TANK (major structural damage) UNINTENTIONAL REALEASE (any) Note: CT INCIDENT REPORT REQUIRED

9 CHEM. TRANS. INC. NO INCIDENT REPORTS REQUIRED BY DOT CFR 49 PART 172 RELEASE NOT HAZMAT UNDECLARED SHIPMENT (air) PACKAGES 5.2 GL. LIQUID PACKAGES <66 POUNDS SOLID <1 PINT RELEASE (valves <1 PINT RELEASE (hoses/connections) seals, pumps) Note: CT incident report required/mind our bucket??

10 HAZMAT TABLES 49 CFR RQ= DESIGNATED REPORTABLE QUANTITY DOT DESCRIPTION= SHIPPING NAME OF PRODUCT OR WASTE HAZARD CLASS= NUMBER DESIGNATES DEGREE OF HAZARD UN/NA NUMBER= UNITED NATIONS/NORTH AMERICAN DESIGNATION PACKING GROUP= PG I, II or III (CONTAINER STANDARDS) WASTE = PRECEDES DOT DESCRIPTION OF HAZWASTE NOS= (USE TWO COMPOUNDS WITH LOWEST RQ)

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12 RQ REPORTABLE QUANTITY 49 CFR & HAZARDOUS SUBSTANCES ELEMENTS & COMPOUNDS HAZARDOUS WASTE STREAMS.BY EPA WASTE CODES INCLUDES MIXTURES AND SOLUTIONS RQ= QUANTITY IN 1 CONTAINER > MAX. CONCENTRATION BY WEIGHT Note: In the event of a release of a hazardous substance in a reportable quantity amount, the NRC shall immediately be notified ( )!!!

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15 HAZMAT BILLS OF LADING CFR ON A BOL, THE HAZMAT MUST BE ENTERED FIRST, OR MUST BE ENTERED IN CONTRASTING COLOR, OR X / RQ MUST BE ENTERED PRIOR TO THE PROPER DOT DESCRIPTION. Description, hazard class, UN/NA #, & PG must be included. Emergency Response # must be included. No abbreviations allowed, other than container descriptions. Waste stream numbers should be included. Hazard class for Combustible liquid, NOS need not be included. BOLs should be kept for a minimum of 2 years. For NOS, 2 constituents with lowest RQs must be included.

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17 HAZWASTE MANIFEST EPA FORM CFR & 40 CFR USED FOR TRACKING WASTE FROM CRADLE TO GRAVE ALL GENERATORS, TRANSPORTERS, TSDFs MUST HAVE ID INSTRUCTIONS: PAGE OF COMPLIANCE GUIDE CT PROCEDURES: -DISPATCH IMMEDIATELY NOTIFIED OF STORED LOADS -COPIES OF SHIPPING PAPERS IN PLACARD HOLDERS -WASTE TO BE STORED ONLY IN TRAILERS (EXCEPT BINS) -DRIVERS MAY NOT ALTER OR COMPLETE MANIFESTS -MANIFESTS MUST BE KEPT FOR 3 YEARS -FACILITY STORAGE MAX= 10 DAYS Note: Use of correct EPA ID Nos. is critical for reporting requirements. CESQG (Conditionally Exempt Small Quantity Generators) are exempt from most requirements.

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19 HAZWASTE MANIFEST CONTAINERS & UNITS OF MEASURE CFR 40 PART 262 CONTAINER TYPES BA = Burlap, cloth, plastic bags CF = Fiber or plastic cartons, boxes CM = Metal cartons, boxes, roll offs CW = Wooden boxes, cartons, cases CY = Cylinders DF = Fiberboard, plastic drums DM = Metal drums, barrels, kegs DT = Dump trucks DW = Wooden drums, barrels, kegs HG = Hopper gondola cars TC = Tank cars PT = Portable tanks TT = Cargo tanks (tank trucks) UNITS OF MEASURES G = Gallons (liquids only) K = Kilograms (PCBs) L = Liters M = Metric tons (1,000 kilograms) N = Cubic meters P = Pounds T = Tons Y = Cubic yards Note: Dark bold = Most commonly used by CT

20 NON BULK CONTAINER LABELS 49 CFR SHIPPING INFO: MIRROR MANIFEST OR BOL WASTE LOADED WITH CLOSURES UPWARD LIQUIDS: PACKAGE ORIENTATION UPRIGHT PRIMARY & SECONDARY LABELS APPLY APPLICATION: CONTAINERS < 110 GALLONS PORTABLE TANK < 1,000 GL (UNLESS PLACARDED) ALL OVERPACKED HAZMAT/HAZWASTE WASTE STREAM NUMBERS PRIMARY/SUBSIDIARY LABELS TOGETHER

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26 PLACARDING 49 CFR CARDS: AFFIXED ON EACH END AND SIDES OF TRAILER ALL BE OFFERED BY SHIPPER (ALMOST NEVER) LE I: PLACARD ANY AMOUNT (BULK OR CONTAINER) LE II: PLACARD 1,001 POUNDS OR MORE AGGREGATE RA EMPTY BULK CONTAINERS: REQUIRE PLACARDS & MANIFEST RA EMPTY NON BULK CONTAINERS: NO PLACARDS (EXCEPT P CODES) GEROUS PLACARDS = 2 OR MORE CATEGORIES (FROM 1 FACILITY < 2,205 LBS) BSIDIARY PLACARDS = Poison gas/ poison inhalation hazard/dangerous en wet hen 2,205 lbs. aggregate gross weight or more of one category is aded at ONE facility, the placard in table II must be applied! OAD CONTAINS NON BULK PACKAGES PPLIES ONLY TO TABLE II HAZMAT

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28 PLACARDING TABLE 1 gory of material (Hazard or division number and itional description, as appropriate) Placard name Placard design section reference ganic peroxide, Type B, id or solid, temperature trolled). terial poisonous by lation (see 171.8)) oactive Yellow III label only) EXPLOSIVES 1.1 EXPLOSIVES 1.2 EXPLOSIVES 1.3 POISON GAS DANGEROUS WHEN WET ORGANIC PEROXIDE POISON INHALATION HAZARD RADIOACTIVE IOACTIVE placard also required for exclusive use shipments of low specific

29 PLACARDING TABLE 2 ory of material (Hazard or division number and itional description, as appropriate) le liquid than organic peroxide, Type B, r solid, temperature lled). than material poisonous by ion)... Placard name EXPLOSIVES 1.4 EXPLOSIVES 1.5 EXPLOSIVES 1.6 FLAMMABLE GAS. NON-FLAMMABLE GAS FLAMMABLE... COMBUSTIBLE... FLAMMABLE SOLID.. SPONTANEOUSLY COMBUSTIBLE.. OXIDIZER. ORGANIC PEROXIDE POISON (None) CORROSIVE Class 9 (see (f)(9). Placard design section reference

30 HAZMAT EMPLOYEE TRAINING CFR ENERAL AWARENESS/FAMILIARIZATION OF HAZMAT UNCTION SPECIFIC TRAINING PENDING WORK DUTIES AFETY TRAINING EMERGENCY RESPONSE (USE OF ER GUIDE) HAZARDS ASSOCIATED WITH WORK PLACE HAZCOM ACCIDENT PREVENTION PPE = FOR PROTECTION AGAINST EXPOSURE SECURITY AWARENESS TRAINING (d): A HAZMAT EMPLOYER SHALL ENSURE THAT EACH OF ITS ZMAT EMPLOYEES IS TESTED BY APPROPRIATE MEANS ON THE AINING SUBJECTS COVERED

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32 SECURITY PLANS 49 CFR APPLICABILITY: te controlled quantities of Class 7 material 5 lbs. of 1.1, 1.2, & 1.3 explosive materials.6 qt. per package of poisonous by inhalation materials k liquid or gas hazmat = 3,500 gallons k solid hazmat = cu. yd. uantity of hazmat requiring placarding per Subpart F nts/toxins regulated by the Centers for Disease Control COMPONENTS: - Risk assessment - Personnel Security - En route security - Unauthorized access

33 LOADING AND UNLOADING 49 CFR NTAINERS: MUST BE SECURED AGAINST MOVEMENT SMOKING: FLAMMABLES, EXPLOSIVES, OXIDIZERS NDBRAKE SET WITH WHEELS BLOCKED OLS: STOWED AWAY FROM CONTAINERS PERATURE: TAKE REASONABLE CARE S AND BUNGS TIGHT (DID SHIPPER VENT??) IDATE: LABELS, MARKING, AND PROFILE NUMBERS UM COUNT: COUNT CONTAINERS AS LOADED/UNLOADED LK CONTAINERS: DRIVER IN ATTENDANCE AT ALL TIMES DRIVER MUST HAVE UNOBSTRUCTED VIEW OF TANKS & HOSES NTAINERS MUST BE DOT SPEC.

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35 NERAL SEGREGATION REQUIREMENTS 49 CFR OSE TO PREVENT: mbustion and/or evolution of considerable heat lution of flammable, toxic, or asphyxiate gases mation of corrosive substances mation of unstable substances EGATION CHART: ay not be loaded, transported, or stored in same vehicle ame as X, UNLESS separated such that in the event of leakage, ngling will not occur under normal conditions. You may not load class 8 lass 4 or 5, unless known to be compatible.

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37 LEAKERS IN TRANSIT 49 CFR WHEN PRACTIBLE, MOVE VEHICLE TO SECURE LOCATION REPAIR PACKAGE (WHEN SAFE, PRACTICABLE, AND HAVE TRAINING) OVERPACK WITH RESPECTIVE MARKING, LABELS, & PROFILE # NOTE ACTION TAKEN IN DESCREPANCY SECTION OF SHIPPING PAPER UNSAFE CONTAINER MAY BE STORED PENDING PROPER DISPOSITION REFER TO CT EMERGENCY RESPONSE PLAN LOCATED IN POWER UNIT REFER TO ER GUIDE IN COMPLIANCE GUIDE e: CT incident report required, along with immediate notification to dispatch Other reporting requirements may apply OL BOX SPILL KITS SPECT CONTAINERS DO NOT ACCEPT

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41 CONTAINER STANDARDS PACKAGING REQUIREMENTS FOR HAZMAT 49 CFR NUFACTURER MUST MARK EVERY CONTAINER MEETING UN EC. TERS IDENTIFYING PERFORMANCE STANDARDS: X MEETS STANDARDS FOR PG I, II,& III Y MEETS STANDARDS FOR PG II, & III Z ONLY MEETS STANDARDS FOR PG III ANDARDS FOR CONTAINERS NORMALLY USED BY CT 1A1 = NON REMOVABLE HEAD STEEL DRUM BUNG 1A2 = REMOVABLE HEAD STEEL DRUM OPEN-TOP 1G = MULTIPLE PLY FIBER DRUM 1H1 = NON REMOVABLE HEAD PLASTIC DRUM 1H2 = REMOVABLE HEAD PLASTIC DRUM 4G = CORRUGATED FIBERBOARD BOX te: Hazmat may not be transported in non-spec. containers!

42 ERGENCY RESPONSE GUIDES 2004 DOT GUIDE BOOK OW SECTION: REFERENCE ER GUIDE # BY UN OR NA ID NUMBER SECTION: REFERENCE ER GUIDE # BY CHEMICAL NAME GE SECTION: EMERGENCY RESPONSE GUIDES (1 ST RESPONDER) N SECTION: ISOLATION & PROTECTIVE ACTION DISTANCES

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