Safety Data Sheet acc. to OSHA HCS

Transcription

1 Safety Data Sheet acc. to OSHA HCS Page 1/8 Printing date 05/27/2015 Reviewed on 05/27/ Identification Product identifier Trade name: CROCIDOLITE CRYSTALS Article number: CAS Number: EC number: Index number: Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. Application of the substance / the mixture Laboratory chemicals Details of the supplier of the safety data sheet Manufacturer/Supplier: Electron Microscopy Sciences 1560 Industry Road USA-Hatfield, PA Tel: Fax: sgkcck@aol.com Information department: Product safety department Emergency telephone number: ChemTrec Contract CCN Hazard(s) identification Classification of the substance or mixture GHS08 Health hazard Carc. 1A H350 May cause cancer. STOT RE 1 H372 Causes damage to organs through prolonged or repeated exposure. Classification according to Directive 67/548/EEC or Directive 1999/45/EC Toxic Carc. Cat. 1 May cause cancer. Toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed. Information concerning particular hazards for human and environment: Not applicable. Label elements Labelling according to EU guidelines: The product has been classified and marked in accordance with directives on hazardous materials. Code letter and hazard designation of product: Carc. Cat. 1 Toxic (Contd. on page 2) USA

2 Safety Data Sheet acc. to OSHA HCS Page 2/8 Printing date 05/27/2015 Reviewed on 05/27/2015 Trade name: CROCIDOLITE CRYSTALS (Contd. of page 1) Risk phrases: May cause cancer. Also toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed. Safety phrases: Avoid exposure - obtain special instructions before use. When using do not eat or drink. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Classification system: NFPA ratings (scale 0-4) Health = 3 Fire = 0 Reactivity = 0 HMIS-ratings (scale 0-4) HEALTH *3 FIRE 0 REACTIVITY 0 Health = *3 Fire = 0 Reactivity = 0 Other hazards Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable. 3 Composition/information on ingredients Chemical characterization: Substances CAS No. Description asbestos Identification number(s) EC number: Index number: First-aid measures Description of first aid measures General information: Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. After inhalation: Supply fresh air; consult doctor in case of complaints. After skin contact: Generally the product does not irritate the skin. After eye contact: Rinse opened eye for several minutes under running water. After swallowing: If symptoms persist consult doctor. Most important symptoms and effects, both acute and delayed No further relevant information available. Indication of any immediate medical attention and special treatment needed No further relevant information available. USA (Contd. on page 3)

3 Safety Data Sheet acc. to OSHA HCS Page 3/8 Printing date 05/27/2015 Reviewed on 05/27/2015 Trade name: CROCIDOLITE CRYSTALS (Contd. of page 2) 5 Fire-fighting measures Extinguishing media Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. Special hazards arising from the substance or mixture No further relevant information available. Advice for firefighters Protective equipment: No special measures required. 6 Accidental release measures Personal precautions, protective equipment and emergency procedures Not required. Environmental precautions: Do not allow to enter sewers/ surface or ground water. Methods and material for containment and cleaning up: Dispose contaminated material as waste according to item 13. Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. 7 Handling and storage Precautions for safe handling Open and handle receptacle with care. Information about protection against explosions and fires: Keep respiratory protective device available. Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles: No special requirements. Information about storage in one common storage facility: Not required. Further information about storage conditions: None. Specific end use(s) No further relevant information available. 8 Exposure controls/personal protection Additional information about design of technical systems: No further data; see item 7. Control parameters Components with limit values that require monitoring at the workplace: asbestos PEL Short-term value: 1 f/cc* ppm Long-term value: 0.1 f/cc mg/m³ *30-min; see 29 CFR REL See Pocket Guide Apps. A and C TLV 0.1 f/cc Additional information: The lists that were valid during the creation were used as basis. Exposure controls Personal protective equipment: General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. (Contd. on page 4) USA

4 Safety Data Sheet acc. to OSHA HCS Page 4/8 Printing date 05/27/2015 Reviewed on 05/27/2015 Trade name: CROCIDOLITE CRYSTALS (Contd. of page 3) Wash hands before breaks and at the end of work. Store protective clothing separately. Breathing equipment: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air. Protection of hands: Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: Tightly sealed goggles 9 Physical and chemical properties Information on basic physical and chemical properties General Information Appearance: Form: Solid material Color: White Odor: uncharacteristic Odour threshold: Not determined. ph-value: Not applicable. Change in condition Melting point/melting range: Boiling point/boiling range: 1500 C (2732 F) Undetermined. Flash point: Not applicable. Flammability (solid, gaseous): Product is not flammable. Ignition temperature: Decomposition temperature: Not determined. Auto igniting: Not determined. Danger of explosion: Product does not present an explosion hazard. Explosion limits: Lower: Not determined. (Contd. on page 5) USA

5 Safety Data Sheet acc. to OSHA HCS Page 5/8 Printing date 05/27/2015 Reviewed on 05/27/2015 Trade name: CROCIDOLITE CRYSTALS Upper: Not determined. Vapor pressure: Not applicable. Density: Not determined. Relative density Not determined. Vapour density Not applicable. Evaporation rate Not applicable. Solubility in / Miscibility with Water: Insoluble. Partition coefficient (n-octanol/water): Not determined. Viscosity: Dynamic: Not applicable. Kinematic: Not applicable. Organic solvents: 0.0 % Solids content: % Other information No further relevant information available. (Contd. of page 4) 10 Stability and reactivity Reactivity Chemical stability Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. Possibility of hazardous reactions No dangerous reactions known. Conditions to avoid No further relevant information available. Incompatible materials: No further relevant information available. Hazardous decomposition products: No dangerous decomposition products known. 11 Toxicological information Information on toxicological effects Acute toxicity: Primary irritant effect: on the skin: No irritant effect. on the eye: No irritating effect. Sensitization: No sensitizing effects known. Additional toxicological information: Carcinogenic categories IARC (International Agency for Research on Cancer) asbestos 1 NTP (National Toxicology Program) asbestos K OSHA-Ca (Occupational Safety Health Administration) Substance is listed. USA (Contd. on page 6)

6 Safety Data Sheet acc. to OSHA HCS Page 6/8 Printing date 05/27/2015 Reviewed on 05/27/2015 Trade name: CROCIDOLITE CRYSTALS (Contd. of page 5) 12 Ecological information Toxicity Aquatic toxicity: No further relevant information available. Persistence and degradability No further relevant information available. Bioaccumulative potential No further relevant information available. Mobility in soil No further relevant information available. Additional ecological information: General notes: Water hazard class 3 (Self-assessment): extremely hazardous for water Do not allow product to reach ground water, water course or sewage system, even in small quantities. Danger to drinking water if even extremely small quantities leak into the ground. Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable. Other adverse effects No further relevant information available. 13 Disposal considerations Waste treatment methods Recommendation: Must not be disposed of together with household garbage. Do not allow product to reach sewage system. Uncleaned packagings: Recommendation: Disposal must be made according to official regulations. 14 Transport information UN-Number DOT, ADR, IMDG, IATA UN2590 UN proper shipping name DOT White asbestos ADR 2590 White asbestos IMDG, IATA WHITE ASBESTOS Transport hazard class(es) DOT, ADR, IMDG, IATA Class 9 Miscellaneous dangerous substances and articles Label 9 Packing group DOT, ADR, IMDG, IATA III Environmental hazards: Marine pollutant: No Special precautions for user Warning: Miscellaneous dangerous substances and articles Danger code (Kemler): 90 (Contd. on page 7) USA

7 Safety Data Sheet acc. to OSHA HCS Page 7/8 Printing date 05/27/2015 Reviewed on 05/27/2015 Trade name: CROCIDOLITE CRYSTALS EMS Number: F-A,S-A (Contd. of page 6) Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Transport/Additional information: Not applicable. DOT Quantity limitations On passenger aircraft/rail: Forbidden On cargo aircraft only: Forbidden ADR Excepted quantities (EQ) Code: E1 Maximum net quantity per inner packaging: 30 g Maximum net quantity per outer packaging: 1000 g IMDG Limited quantities (LQ) 1 kg Excepted quantities (EQ) Code: E2 Maximum net quantity per inner packaging: 30 g Maximum net quantity per outer packaging: 500 g UN "Model Regulation": UN2590, White asbestos, 9, III 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Sara Section 355 (extremely hazardous substances): Substance is not listed. Section 313 (Specific toxic chemical listings): Substance is not listed. TSCA (Toxic Substances Control Act): Substance is not listed. Proposition 65 Chemicals known to cause cancer: Substance is not listed. Chemicals known to cause reproductive toxicity for females: Substance is not listed. Chemicals known to cause reproductive toxicity for males: Substance is not listed. Chemicals known to cause developmental toxicity: Substance is not listed. Carcinogenic categories EPA (Environmental Protection Agency) asbestos A TLV (Threshold Limit Value established by ACGIH) asbestos A1 (Contd. on page 8) USA

8 Safety Data Sheet acc. to OSHA HCS Page 8/8 Printing date 05/27/2015 Reviewed on 05/27/2015 Trade name: CROCIDOLITE CRYSTALS NIOSH-Ca (National Institute for Occupational Safety and Health) Substance is listed. (Contd. of page 7) Product related hazard informations: The product has been classified and marked in accordance with directives on hazardous materials. Hazard symbols: Carc. Cat. 1 Toxic Risk phrases: May cause cancer. Also toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed. Safety phrases: Avoid exposure - obtain special instructions before use. When using do not eat or drink. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. National regulations: Information about limitation of use: Workers are not allowed to be exposed to this hazardous material. Exceptions can be made by the authorities in certain cases. Chemical safety assessment: A Chemical Safety Assessment has not been carried out. 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Date of preparation / last revision 05/27/2015 / - Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association ACGIH: American Conference of Governmental Industrial Hygienists EINECS: European Inventory of Existing Commercial Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (USA) HMIS: Hazardous Materials Identification System (USA) Carc. 1A: Carcinogenicity, Hazard Category 1A STOT RE 1: Specific target organ toxicity - Repeated exposure, Hazard Category 1 USA

9 Safety data sheet according to 1907/2006/EC, Article 31 Page 1/7 Printing date Revision: Identification of the substance/mixture and of the company/undertaking Product identifier Trade name: CROCIDOLITE CRYSTALS Article number: CAS Number: EC number: Index number: Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. Application of the substance / the mixture Laboratory chemicals Details of the supplier of the safety data sheet Manufacturer/Supplier: Electron Microscopy Sciences 1560 Industry Road USA-Hatfield, PA Tel: Fax: sgkcck@aol.com ProSciTech Pty Ltd 11 Carlton Street, Kirwan QLD 4817 Australia Telephone Number: (07) :30am - 5:00pm, Monday to Friday (excluding Public Holidays) Emergency Contact: (07) :30am - 5:00pm, Monday to Friday (excluding Public Holidays) Emgrid Australia Pty. Ltd. P.O. Box 118 The Patch VIC 3792 Australia Tel: Fax: Website: Further information obtainable from: Product safety department Emergency telephone number: ChemTrec Contract CCN Hazards identification Classification of the substance or mixture Classification according to Directive 67/548/EEC or Directive 1999/45/EC Toxic Carc. Cat. 1 May cause cancer. Toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed. Information concerning particular hazards for human and environment: Not applicable. Label elements Labelling according to EU guidelines: The product has been classified and marked in accordance with EU Directives / Ordinance on Hazardous Materials. (Contd. on page 2) AU

10 Safety data sheet according to 1907/2006/EC, Article 31 Page 2/7 Printing date Revision: Trade name: CROCIDOLITE CRYSTALS Code letter and hazard designation of product: (Contd. of page 1) Carc. Cat. 1 Toxic Risk phrases: May cause cancer. Also toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed. Information concerning particular hazards for human and environment: Safety phrases: Avoid exposure - obtain special instructions before use. When using do not eat or drink. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Other hazards Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable. 3 Composition/information on ingredients Chemical characterisation: Substances CAS No. Description asbestos Identification number(s) EC number: Index number: First aid measures Description of first aid measures General information: Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. After inhalation: Supply fresh air; consult doctor in case of complaints. After skin contact: Generally the product does not irritate the skin. After eye contact: Rinse opened eye for several minutes under running water. After swallowing: If symptoms persist consult doctor. Most important symptoms and effects, both acute and delayed No further relevant information available. Indication of any immediate medical attention and special treatment needed No further relevant information available. 5 Firefighting measures Extinguishing media Suitable extinguishing agents: CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam. Special hazards arising from the substance or mixture No further relevant information available. (Contd. on page 3) AU

11 Safety data sheet according to 1907/2006/EC, Article 31 Page 3/7 Printing date Revision: Trade name: CROCIDOLITE CRYSTALS Advice for firefighters Protective equipment: No special measures required. (Contd. of page 2) 6 Accidental release measures Personal precautions, protective equipment and emergency procedures Not required. Environmental precautions: Do not allow to enter sewers/ surface or ground water. Methods and material for containment and cleaning up: Dispose contaminated material as waste according to item 13. Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. 7 Handling and storage Precautions for safe handling Open and handle receptacle with care. Information about fire - and explosion protection: Keep respiratory protective device available. Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles: No special requirements. Information about storage in one common storage facility: Not required. Further information about storage conditions: None. Specific end use(s) No further relevant information available. 8 Exposure controls/personal protection Additional information about design of technical facilities: No further data; see item 7. Control parameters Ingredients with limit values that require monitoring at the workplace: asbestos NES 0.1 f/ml Additional information: The lists valid during the making were used as basis. Exposure controls Personal protective equipment: General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing Wash hands before breaks and at the end of work. Store protective clothing separately. Respiratory protection: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device. Protection of hands: Protective gloves (Contd. on page 4) AU

12 Safety data sheet according to 1907/2006/EC, Article 31 Page 4/7 Printing date Revision: Trade name: CROCIDOLITE CRYSTALS (Contd. of page 3) The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: Tightly sealed goggles 9 Physical and chemical properties Information on basic physical and chemical properties General Information Appearance: Form: Solid material Colour: White Odour: Uncharacteristic. Odour threshold: Not determined. ph-value: Not applicable. Change in condition Melting point/melting range: 1500 C Boiling point/boiling range: Undetermined. Flash point: Not applicable. Flammability (solid, gaseous): Product is not flammable. Ignition temperature: Decomposition temperature: Not determined. Self-igniting: Not determined. Danger of explosion: Product does not present an explosion hazard. Explosion limits: Lower: Upper: Not determined. Not determined. Vapour pressure: Not applicable. Density: Not determined. Relative density Not determined. Vapour density Not applicable. Evaporation rate Not applicable. Solubility in / Miscibility with water: Insoluble. (Contd. on page 5) AU

13 Safety data sheet according to 1907/2006/EC, Article 31 Page 5/7 Printing date Revision: Trade name: CROCIDOLITE CRYSTALS Partition coefficient (n-octanol/water): Not determined. Viscosity: Dynamic: Kinematic: Not applicable. Not applicable. Solvent content: Organic solvents: 0.0 % VOC (EC) 0.00 % Solids content: % Other information No further relevant information available. (Contd. of page 4) 10 Stability and reactivity Reactivity Chemical stability Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. Possibility of hazardous reactions No dangerous reactions known. Conditions to avoid No further relevant information available. Incompatible materials: No further relevant information available. Hazardous decomposition products: No dangerous decomposition products known. 11 Toxicological information Information on toxicological effects Acute toxicity: Primary irritant effect: on the skin: No irritant effect. on the eye: No irritating effect. Sensitisation: No sensitising effects known. CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) Carc. Cat Ecological information Toxicity Aquatic toxicity: No further relevant information available. Persistence and degradability No further relevant information available. Bioaccumulative potential No further relevant information available. Mobility in soil No further relevant information available. Additional ecological information: General notes: Water hazard class 3 (German Regulation) (Self-assessment): extremely hazardous for water Do not allow product to reach ground water, water course or sewage system, even in small quantities. Danger to drinking water if even extremely small quantities leak into the ground. Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable. (Contd. on page 6) AU

14 Safety data sheet according to 1907/2006/EC, Article 31 Page 6/7 Printing date Revision: Trade name: CROCIDOLITE CRYSTALS Other adverse effects No further relevant information available. (Contd. of page 5) 13 Disposal considerations Waste treatment methods Recommendation Must not be disposed together with household garbage. Do not allow product to reach sewage system. Uncleaned packaging: Recommendation: Disposal must be made according to official regulations. 14 Transport information UN-Number ADG, IMDG, IATA UN2590 UN proper shipping name ADG 2590 WHITE ASBESTOS IMDG, IATA WHITE ASBESTOS Transport hazard class(es) ADG, IMDG, IATA Class 9 Miscellaneous dangerous substances and articles. Label 9 Packing group ADG, IMDG, IATA III Environmental hazards: Marine pollutant: No Special precautions for user Warning: Miscellaneous dangerous substances and articles. Danger code (Kemler): 90 EMS Number: F-A,S-A Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Transport/Additional information: Not applicable. ADG Limited quantities (LQ) 5 kg Excepted quantities (EQ) Code: E1 Maximum net quantity per inner packaging: 30 g Maximum net quantity per outer packaging: 1000 g Transport category 3 Tunnel restriction code E (Contd. on page 7) AU

15 Safety data sheet according to 1907/2006/EC, Article 31 Page 7/7 Printing date Revision: Trade name: CROCIDOLITE CRYSTALS IMDG Limited quantities (LQ) 1 kg Excepted quantities (EQ) Code: E2 Maximum net quantity per inner packaging: 30 g Maximum net quantity per outer packaging: 500 g (Contd. of page 6) 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Australian Inventory of Chemical Substances Substance is not listed. Standard for the Uniform Scheduling of Medicines and Poisons Substance is not listed. Labelling according to EU guidelines: The product has been classified and marked in accordance with EU Directives / Ordinance on Hazardous Materials. Code letter and hazard designation of product: Carc. Cat. 1 Toxic Risk phrases: May cause cancer. Also toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed. Safety phrases: Avoid exposure - obtain special instructions before use. When using do not eat or drink. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. National regulations: Information about limitation of use: Workers are not allowed to be exposed to this hazardous material. Exceptions can be made by the authorities in certain cases. Chemical safety assessment: A Chemical Safety Assessment has not been carried out. 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. AU

16 Safety Data Sheet acc. to OSHA HCS Page 1/9 Printing date 05/27/2015 Reviewed on 05/27/ Identification Product identifier Trade name: CROCIDOLITE CRYSTALS Article number: CAS Number: EC number: Index number: Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. Application of the substance / the mixture Laboratory chemicals Details of the supplier of the safety data sheet Manufacturer/Supplier: Electron Microscopy Sciences 1560 Industry Road USA-Hatfield, PA Tel: Fax: sgkcck@aol.com Information department: Product safety department Emergency telephone number: ChemTrec Contract CCN Hazard(s) identification Classification of the substance or mixture GHS08 Health hazard Carc. 1A H350 May cause cancer. STOT RE 1 H372 Causes damage to organs through prolonged or repeated exposure. Classification according to Directive 67/548/EEC or Directive 1999/45/EC Toxic Carc. Cat. 1 May cause cancer. Toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed. Information concerning particular hazards for human and environment: Not applicable. Label elements Labelling according to EU guidelines: The product has been classified and marked in accordance with directives on hazardous materials. Code letter and hazard designation of product: Carc. Cat. 1 Toxic (Contd. on page 2) CA

17 Safety Data Sheet acc. to OSHA HCS Page 2/9 Printing date 05/27/2015 Reviewed on 05/27/2015 Trade name: CROCIDOLITE CRYSTALS (Contd. of page 1) Risk phrases: May cause cancer. Also toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed. Safety phrases: Avoid exposure - obtain special instructions before use. When using do not eat or drink. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Hazard description: WHMIS-symbols: D2A - Very toxic material causing other toxic effects Classification system: NFPA ratings (scale 0-4) Health = 3 Fire = 0 Reactivity = 0 HMIS-ratings (scale 0-4) HEALTH *3 FIRE 0 REACTIVITY 0 Health = *3 Fire = 0 Reactivity = 0 Other hazards Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable. 3 Composition/information on ingredients Chemical characterization: Substances CAS No. Description asbestos Identification number(s) EC number: Index number: First-aid measures Description of first aid measures General information: Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. After inhalation: Supply fresh air; consult doctor in case of complaints. After skin contact: Generally the product does not irritate the skin. After eye contact: Rinse opened eye for several minutes under running water. (Contd. on page 3) CA

18 Safety Data Sheet acc. to OSHA HCS Page 3/9 Printing date 05/27/2015 Reviewed on 05/27/2015 Trade name: CROCIDOLITE CRYSTALS (Contd. of page 2) After swallowing: If symptoms persist consult doctor. Most important symptoms and effects, both acute and delayed No further relevant information available. Indication of any immediate medical attention and special treatment needed No further relevant information available. 5 Fire-fighting measures Extinguishing media Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. Special hazards arising from the substance or mixture No further relevant information available. Advice for firefighters Protective equipment: No special measures required. 6 Accidental release measures Personal precautions, protective equipment and emergency procedures Not required. Environmental precautions: Do not allow to enter sewers/ surface or ground water. Methods and material for containment and cleaning up: Dispose contaminated material as waste according to item 13. Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. 7 Handling and storage Precautions for safe handling Open and handle receptacle with care. Information about protection against explosions and fires: Keep respiratory protective device available. Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles: No special requirements. Information about storage in one common storage facility: Not required. Further information about storage conditions: None. Specific end use(s) No further relevant information available. 8 Exposure controls/personal protection Additional information about design of technical systems: No further data; see item 7. Control parameters Components with limit values that require monitoring at the workplace: asbestos EV Long-term value: 0.1 f/cc ppm Additional information: The lists that were valid during the creation were used as basis. Exposure controls Personal protective equipment: General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. (Contd. on page 4) CA

19 Safety Data Sheet acc. to OSHA HCS Page 4/9 Printing date 05/27/2015 Reviewed on 05/27/2015 Trade name: CROCIDOLITE CRYSTALS (Contd. of page 3) Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Store protective clothing separately. Breathing equipment: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air. Protection of hands: Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: Tightly sealed goggles 9 Physical and chemical properties Information on basic physical and chemical properties General Information Appearance: Form: Solid material Color: White Odor: uncharacteristic Odour threshold: Not determined. ph-value: Not applicable. Change in condition Melting point/melting range: 1500 C Boiling point/boiling range: Undetermined. Flash point: Not applicable. Flammability (solid, gaseous): Product is not flammable. Ignition temperature: Decomposition temperature: Not determined. Auto igniting: Not determined. Danger of explosion: Product does not present an explosion hazard. (Contd. on page 5) CA

20 Safety Data Sheet acc. to OSHA HCS Page 5/9 Printing date 05/27/2015 Reviewed on 05/27/2015 Trade name: CROCIDOLITE CRYSTALS Explosion limits: Lower: Upper: Not determined. Not determined. Vapor pressure: Not applicable. Density: Not determined. Relative density Not determined. Vapour density Not applicable. Evaporation rate Not applicable. Solubility in / Miscibility with Water: Insoluble. Partition coefficient (n-octanol/water): Not determined. Viscosity: Dynamic: Not applicable. Kinematic: Not applicable. Organic solvents: 0.0 % Solids content: % Other information No further relevant information available. (Contd. of page 4) 10 Stability and reactivity Reactivity Chemical stability Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. Possibility of hazardous reactions No dangerous reactions known. Conditions to avoid No further relevant information available. Incompatible materials: No further relevant information available. Hazardous decomposition products: No dangerous decomposition products known. 11 Toxicological information Information on toxicological effects Acute toxicity: Primary irritant effect: on the skin: No irritant effect. on the eye: No irritating effect. Sensitization: No sensitizing effects known. Additional toxicological information: Carcinogenic categories IARC (International Agency for Research on Cancer) asbestos 1 NTP (National Toxicology Program) asbestos K (Contd. on page 6) CA

21 Safety Data Sheet acc. to OSHA HCS Page 6/9 Printing date 05/27/2015 Reviewed on 05/27/2015 Trade name: CROCIDOLITE CRYSTALS OSHA-Ca (Occupational Safety Health Administration) Substance is listed. (Contd. of page 5) 12 Ecological information Toxicity Aquatic toxicity: No further relevant information available. Persistence and degradability No further relevant information available. Bioaccumulative potential No further relevant information available. Mobility in soil No further relevant information available. Additional ecological information: General notes: Water hazard class 3 (Self-assessment): extremely hazardous for water Do not allow product to reach ground water, water course or sewage system, even in small quantities. Danger to drinking water if even extremely small quantities leak into the ground. Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable. Other adverse effects No further relevant information available. 13 Disposal considerations Waste treatment methods Recommendation: Must not be disposed of together with household garbage. Do not allow product to reach sewage system. Uncleaned packagings: Recommendation: Disposal must be made according to official regulations. 14 Transport information UN-Number DOT, TDG, IMDG, IATA UN2590 UN proper shipping name DOT White asbestos TDG 2590 White asbestos IMDG, IATA WHITE ASBESTOS Transport hazard class(es) DOT, TDG, IMDG, IATA Class 9 Miscellaneous dangerous substances and articles Label 9 Packing group DOT, TDG, IMDG, IATA III (Contd. on page 7) CA

22 Safety Data Sheet acc. to OSHA HCS Page 7/9 Printing date 05/27/2015 Reviewed on 05/27/2015 Trade name: CROCIDOLITE CRYSTALS Environmental hazards: Marine pollutant: No Special precautions for user Warning: Miscellaneous dangerous substances and articles Danger code (Kemler): 90 EMS Number: F-A,S-A Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Transport/Additional information: Not applicable. DOT Quantity limitations On passenger aircraft/rail: Forbidden On cargo aircraft only: Forbidden TDG Excepted quantities (EQ) Code: E1 Maximum net quantity per inner packaging: 30 g Maximum net quantity per outer packaging: 1000 g IMDG Limited quantities (LQ) 1 kg Excepted quantities (EQ) Code: E2 Maximum net quantity per inner packaging: 30 g Maximum net quantity per outer packaging: 500 g UN "Model Regulation": UN2590, White asbestos, 9, III (Contd. of page 6) 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Sara Section 355 (extremely hazardous substances): Substance is not listed. Section 313 (Specific toxic chemical listings): Substance is not listed. TSCA (Toxic Substances Control Act): Substance is not listed. Proposition 65 Chemicals known to cause cancer: Substance is not listed. Chemicals known to cause reproductive toxicity for females: Substance is not listed. Chemicals known to cause reproductive toxicity for males: Substance is not listed. Chemicals known to cause developmental toxicity: Substance is not listed. (Contd. on page 8) CA

23 Safety Data Sheet acc. to OSHA HCS Page 8/9 Printing date 05/27/2015 Reviewed on 05/27/2015 Trade name: CROCIDOLITE CRYSTALS (Contd. of page 7) Carcinogenic categories EPA (Environmental Protection Agency) asbestos A TLV (Threshold Limit Value established by ACGIH) asbestos A1 NIOSH-Ca (National Institute for Occupational Safety and Health) Substance is listed. Canadian substance listings: Canadian Domestic Substances List (DSL) Substance is not listed. Canadian Ingredient Disclosure list (limit 0.1%) Substance is listed. Canadian Ingredient Disclosure list (limit 1%) Substance is not listed. Product related hazard informations: The product has been classified and marked in accordance with directives on hazardous materials. Hazard symbols: Carc. Cat. 1 Toxic Risk phrases: May cause cancer. Also toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed. Safety phrases: Avoid exposure - obtain special instructions before use. When using do not eat or drink. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. National regulations: Information about limitation of use: Workers are not allowed to be exposed to this hazardous material. Exceptions can be made by the authorities in certain cases. Chemical safety assessment: A Chemical Safety Assessment has not been carried out. 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Date of preparation / last revision 05/27/2015 / - Abbreviations and acronyms: IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association ACGIH: American Conference of Governmental Industrial Hygienists EINECS: European Inventory of Existing Commercial Chemical Substances (Contd. on page 9) CA

24 Safety Data Sheet acc. to OSHA HCS Page 9/9 Printing date 05/27/2015 Reviewed on 05/27/2015 Trade name: CROCIDOLITE CRYSTALS CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (USA) HMIS: Hazardous Materials Identification System (USA) WHMIS: Workplace Hazardous Materials Information System (Canada) Carc. 1A: Carcinogenicity, Hazard Category 1A STOT RE 1: Specific target organ toxicity - Repeated exposure, Hazard Category 1 (Contd. of page 8) CA

25 Safety data sheet according to 1907/2006/EC, Article 31 Page 1/7 Printing date Revision: SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Trade name: CROCIDOLITE CRYSTALS Article number: CAS Number: EC number: Index number: Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. Application of the substance / the mixture Laboratory chemicals 1.3 Details of the supplier of the safety data sheet Manufacturer/Supplier: Electron Microscopy Sciences 1560 Industry Road USA-Hatfield, PA Tel: Fax: sgkcck@aol.com Further information obtainable from: Product safety department 1.4 Emergency telephone number: ChemTrec Contract CCN SECTION 2: Hazards identification 2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 GHS08 health hazard Carc. 1A H350 May cause cancer. STOT RE 1 H372 Causes damage to organs through prolonged or repeated exposure. 2.2 Label elements Labelling according to Regulation (EC) No 1272/2008 The substance is classified and labelled according to the CLP regulation. Hazard pictograms GHS08 Signal word Danger Hazard-determining components of labelling: asbestos Hazard statements H350 May cause cancer. H372 Causes damage to organs through prolonged or repeated exposure. (Contd. on page 2) GB

26 Safety data sheet according to 1907/2006/EC, Article 31 Page 2/7 Printing date Revision: Trade name: CROCIDOLITE CRYSTALS (Contd. of page 1) Precautionary statements P260 Do not breathe dust/fume/gas/mist/vapours/spray. P281 Use personal protective equipment as required. P264 Wash thoroughly after handling. P308+P313 IF exposed or concerned: Get medical advice/attention. P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. 2.3 Other hazards Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable. SECTION 3: Composition/information on ingredients 3.1 Chemical characterisation: Substances CAS No. Description asbestos Identification number(s) EC number: Index number: SECTION 4: First aid measures 4.1 Description of first aid measures General information: Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. After inhalation: Supply fresh air; consult doctor in case of complaints. After skin contact: Generally the product does not irritate the skin. After eye contact: Rinse opened eye for several minutes under running water. After swallowing: If symptoms persist consult doctor. 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. SECTION 5: Firefighting measures 5.1 Extinguishing media Suitable extinguishing agents: CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam. 5.2 Special hazards arising from the substance or mixture No further relevant information available. 5.3 Advice for firefighters Protective equipment: No special measures required. SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures Not required. 6.2 Environmental precautions: Do not allow to enter sewers/ surface or ground water. 6.3 Methods and material for containment and cleaning up: Dispose contaminated material as waste according to item 13. (Contd. on page 3) GB

27 Safety data sheet according to 1907/2006/EC, Article 31 Page 3/7 Printing date Revision: Trade name: CROCIDOLITE CRYSTALS 6.4 Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. (Contd. of page 2) SECTION 7: Handling and storage 7.1 Precautions for safe handling Open and handle receptacle with care. Information about fire - and explosion protection: Keep respiratory protective device available. 7.2 Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles: No special requirements. Information about storage in one common storage facility: Not required. Further information about storage conditions: None. 7.3 Specific end use(s) No further relevant information available. SECTION 8: Exposure controls/personal protection Additional information about design of technical facilities: No further data; see item Control parameters Ingredients with limit values that require monitoring at the workplace: Not required. Additional information: The lists valid during the making were used as basis. 8.2 Exposure controls Personal protective equipment: General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing Wash hands before breaks and at the end of work. Store protective clothing separately. Respiratory protection: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device. Protection of hands: Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. (Contd. on page 4) GB

28 Safety data sheet according to 1907/2006/EC, Article 31 Page 4/7 Printing date Revision: Trade name: CROCIDOLITE CRYSTALS Eye protection: (Contd. of page 3) Tightly sealed goggles SECTION 9: Physical and chemical properties 9.1 Information on basic physical and chemical properties General Information Appearance: Form: Solid material Colour: White Odour: Uncharacteristic. Odour threshold: Not determined. ph-value: Not applicable. Change in condition Melting point/melting range: 1500 C Boiling point/boiling range: Undetermined. Flash point: Not applicable. Flammability (solid, gaseous): Product is not flammable. Ignition temperature: Decomposition temperature: Not determined. Self-igniting: Not determined. Danger of explosion: Product does not present an explosion hazard. Explosion limits: Lower: Upper: Not determined. Not determined. Vapour pressure: Not applicable. Density: Not determined. Relative density Not determined. Vapour density Not applicable. Evaporation rate Not applicable. Solubility in / Miscibility with water: Insoluble. Partition coefficient (n-octanol/water): Not determined. Viscosity: Dynamic: Kinematic: Not applicable. Not applicable. Solvent content: Organic solvents: 0.0 % VOC (EC) 0.00 % Solids content: % (Contd. on page 5) GB

29 Safety data sheet according to 1907/2006/EC, Article 31 Page 5/7 Printing date Revision: Trade name: CROCIDOLITE CRYSTALS 9.2 Other information No further relevant information available. (Contd. of page 4) SECTION 10: Stability and reactivity 10.1 Reactivity 10.2 Chemical stability Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications Possibility of hazardous reactions No dangerous reactions known Conditions to avoid No further relevant information available Incompatible materials: No further relevant information available Hazardous decomposition products: No dangerous decomposition products known. SECTION 11: Toxicological information 11.1 Information on toxicological effects Acute toxicity: Primary irritant effect: on the skin: No irritant effect. on the eye: No irritating effect. Sensitisation: No sensitising effects known. CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) Carc. 1A SECTION 12: Ecological information 12.1 Toxicity Aquatic toxicity: No further relevant information available Persistence and degradability No further relevant information available Bioaccumulative potential No further relevant information available Mobility in soil No further relevant information available. Additional ecological information: General notes: Water hazard class 3 (German Regulation) (Self-assessment): extremely hazardous for water Do not allow product to reach ground water, water course or sewage system, even in small quantities. Danger to drinking water if even extremely small quantities leak into the ground Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable Other adverse effects No further relevant information available. SECTION 13: Disposal considerations 13.1 Waste treatment methods Recommendation Must not be disposed together with household garbage. Do not allow product to reach sewage system. (Contd. on page 6) GB