Material Safety Data Sheet

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1 Page of 5 Company Ivoclar Vivadent AG, Bendererstrasse 2, FL Schaan Principality of Liechtenstein. Commercial product name and supplier Commercial product name / Designation NFPA HMIS 0 H F R 0 C Application / Use Producer Supplier Pickling Solutions Ivoclar Vivadent, Inc. 75 Pineview Drive, Amherst NY 4228, USA Ivoclar Vivadent, Inc. 75 Pineview Drive, Amherst NY 4228, USA 2785 Skymark Ave., Unit Mississagua, ON L4W4Y3, Canada MSDS prepared by Andejeet Gulati. Tel. No Hour Emergency Assistance Emergency-Call USA- Infotrac: Emergency-Call Canada - Canutec: General MSDS Assistance US: Canada: Composition Chemical characterization Hazardous components CAS No Mixture of Water, Phosphoric Acid and Urea % Phosphoric acid C: Corrosive. R34: Causes burns. 3 Hazards identification Causes burns. Very toxic by inhalation, in contact with skin and if swallowed First aid measures Eye contact Skin contact Flush eyes with plenty of water (0-5 min.). Call a physician. Wash thoroughly with soap and water.

2 Page 2 of Ingestion Give large amounts of water. Seek medical advise. 4.4 Inhalation Remove to fresh air. Consult a physician Fire-fighting measures 5. Suitable extinguishing media Carbon dioxide, dry chemical and foam Extinguishing media to avoid Flash point None known. Test method: 5.4 Ignition temperature 5.5 Explosion limits Lower: Upper: 5.6 Wear protective clothing and use self-contained breathing apparatus. 6 Accidental release measures Clean up with absorbent material. Dispose of according to local and national regulations. Wash the area with soap and water. Prevent skin and eye contact Handling and storage Handling Industrial hygiene Storage Place of storage Fire- and explosion-protection Use only in a well ventilated area. Only adequately trained personnel should handle this product. Usual hygienic measures are necessary. Practice care and caution to avoid skin and eye contact. Keep containers tightly closed. Store in a well ventilated, cool, dry area. None. 8 Exposure controls / Personal protection Exposure controls Exposure limit values Provide adequate local ventilation. ACGIH (American Conference of Governmental Industrial Hygienists, USA) Threshold Limit Value (TLV) is... ppm (Ceiling). Phosphoric Acid.0

3 Date of printing eet No. 685 Page 3 of Occupational exposure controls Respiratory protection Hand protection Eye protection Other Atmospheric levels should be maintained below the exposure guideline. In poorly ventilated areas, use respiratory protection apparatus. Appropriate gloves. Safety goggles. Remove contaminated clothing immediately, wash skin area with water, and launder clothing. 8.4 Environmental exposure controls Physical and chemical properties Appearance Colour Odour Liquid yellowish none 9.4 Change of physical state Test method: Boiling point 43 F 07 F 9.5 Density.4 g/cm³ 9.6 Vapour pressure 0.03 mm Hg 9.7 Viscosity 9.8 Solubility 9.9 ph Part. coeff. n-octanol/water Evaporat. rate

4 Page 4 of Stability and reactivity Thermal decomposition During thermal decomposition, toxic and irritating gases/fumes may be released. 0.2 Hazardous decomposition products During thermal decomposition, toxic and irritating gases/fumes may be released. 0.3 Conditions / materials to avoid Strong acids. most metals Toxicological information Acute toxicity Subacute / Chronic toxicity Corrosive. Irritating to eyes, respiratory system and skin. Avoid eye and skin contact..3 None Ecological information Ecotoxicity Mobility Persistence and degradability Bioaccumulative potential The product must not enter effluent, ground water, surface water or the soil. 3 Disposal considerations Take to an approved landfill or a waste incineration plant, under conditions approved by the local authority. 4 Transport information 4. Transport at land ADR 8 RID 8 UN Number 805 Proper shipping name Kemler Number Phosphoric acid, solution 4.2 Transport at sea ADNR 8 IMDG UN Number 805 EMS Proper shipping name Marine pollutant MFAG Phosphoric acid, solution

5 Page 5 of Air transport ICAO / IATA-DGR 8 UN Number 805 Proper shipping name Phosphoric acid, solution 4.4 Passenger airplane Cargo Airplane Subsidiary Risk N/A Labels Corrosive Packing Instructions 89 max. 5 L Packing Instructions 82 max. 60 L Sample shipment not allowed by mail Regulatory information National regulations NFPA Storage This product does require classification according to the criteria of the EC Other information The above mentioned data correspond to our present state of knowledge and experience. The safety data sheet serves as description of the products in regard to necessary safety measures. The indications do not have the meaning of guarantees on properties. This safety data sheet has been generated with the safety database 'ChemManager', ASSiST Applied Software Solutions in Science and Technology AG, Weiherweg 3, CH-404 Oberwil, Switzerland

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