MATERIAL SAFETY DATA SHEET

Transcription

1 Page 1 of 8 MATERIAL SAFETY DATA SHEET SECTION 1 - IDENTIFICATION Product identifier Product Code(s) Product Use Chemical Family Supplier s name and address Heavy duty degreasing syrup Mixture. Manufacturer s name and address RBM Holdsolutions Unit th Street Surrey, British Columbia, Canada V3S 3W6 Information Telephone # 24 Hr. Emergency Tel # (604) Refer to supplier Refer to Supplier SECTION 2 - HAZARDS IDENTIFICATION Classification WHMIS information This product is a WHMIS Controlled Product. It meets one or more of the criteria for a controlled product provided in Part IV of the Canadian Controlled Products Regulations (CPR). WHMIS classification Class B3 (Combustible Liquids) Class D2B (Materials Causing Other Toxic Effects, Toxic Material) Emergency Overview OSHA This material is classified as hazardous under OSHA regulations (29CFR ). Hazardous classification Acute Health Hazard Flammable liquid Chronic Health Hazard Light gold liquid. Peach-like odour. Warning! Combustible liquid and vapour. Causes eye and skin irritation. Inhalation may cause respiratory irritation and central nervous system depression. May be harmful or fatal if swallowed. Aspiration may occur during swallowing or vomiting, resulting in lung injury. May cause skin sensitization. POTENTIAL HEALTH EFFECTS Signs and symptoms of short-term (acute) exposure Inhalation Skin Eyes May cause respiratory irritation. May cause headache, nausea, dizziness and other symptoms of central nervous system depression. May cause moderate skin irritation. May cause mild to moderate irritation. Ingestion May cause irritation to the mouth, throat and stomach. May be an aspiration hazard. Aspiration into the lungs during swallowing or subsequent vomiting may cause chemical pneumonitis, which can be fatal. Effects of long-term (chronic) exposure Prolonged or repeated skin contact may cause defatting and drying resulting in irritation and possible dermatitis. Carcinogenic status See TOXICOLOGICAL INFORMATION, Section 11. Additional health hazards Skin sensitizer. See TOXICOLOGICAL INFORMATION, Section 11. Potential environmental effects See ECOLOGICAL INFORMATION, Section 12.

2 Page 2 of 8 SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS CAS # Wt.% d-limonene SECTION 4 - FIRST AID MEASURES Inhalation Skin contact Eye contact Ingestion Notes For Physician Move to fresh air. If breathing has stopped, give artificial respiration. If breathing is difficult, give oxygen by qualified medical personnel only. Get medical attention. Wash affected areas with soap and water. Remove contaminated clothing and shoes. Obtain medical attention if irritation persists. Wash contaminated clothing before reuse. Flush with large amounts of water for 15 minutes. Get medical attention if irritation develops and persists. Do NOT induce vomiting. If vomiting occurs spontaneously, keep victim's head lowered (forward) to reduce the risk of aspiration. Never give anything by mouth to an unconscious person. Get medical attention immediately. Treat symptomatically. This product is a CNS depressant. SECTION 5 - FIRE FIGHTING MEASURES Fire hazards/conditions of flammability Flammability classification (OSHA 29 CFR ) Combustible Liquid Class III A. Oxidizing properties None known. Combustible liquid and vapour. Vapours are heavier than air and may spread along floors. Vapour can travel considerable distance and flashback to a source of ignition. Closed containers may rupture if exposed to excess heat or flame due to a build-up of internal pressure. Do not pressurize, cut, heat or weld empty containers. Empty containers retain residue (liquid and/or vapour) and can be dangerous. Explosion data Sensitivity to mechanical impact / static discharge Not expected to be sensitive to mechanical impact or static discharge. Vapours in the flammable range may be ignited by a static discharge of sufficient energy. Suitable extinguishing media Use media suitable to the surrounding fire such as water fog or fine spray, alcohol foams, carbon dioxide and dry chemical. Special fire-fighting procedures/equipment Hazardous combustion products NFPA Rating SECTION 6 - ACCIDENTAL RELEASE MEASURES Firefighters should wear proper protective equipment and self-contained breathing apparatus with full face piece operated in positive pressure mode. Move containers from fire area if safe to do so. Water spray may be useful in cooling equipment exposed to heat and flame. Carbon oxides, Hydrocarbons, and other irritating fumes and smoke. 0 - Minimal 1 - Slight 2 - Moderate 3 - Serious 4 - Severe Health 2 Flammability 2 Instability 0 Special Hazards

3 Page 3 of 8 Personal precautions Environmental precautions Spill response/cleanup Prohibited materials Special spill response procedures Ensure clean-up is conducted by trained personnel only. Keep all other personnel upwind and away from the spill/release. All persons dealing with clean-up should wear the appropriate protective equipment including self-contained breathing apparatus. Refer to Section 8, EXPOSURE CONTROLS AND PERSONAL PROTECTION, for additional information on acceptable personal protective equipment. Ensure spilled product does not enter drains, sewers, waterways, or confined spaces. For large spills, dike the area to prevent spreading. Evacuate all personnel from affected areas and provide maximum explosion-proof ventilation. Restrict access to area until completion of clean-up. Remove all sources of ignition. Stop the spill at source if it is safe to do so. Contain and absorb spilled liquid with non-combustible, inert absorbent material (e.g. sand), then place absorbent material into a container for later disposal (see Section 13). Notify the appropriate authorities as required. Do not use combustible absorbents, such as sawdust. If a spill/release in excess of the EPA reportable quantity is made into the environment, immediately notify the national response center in the United States (phone ). US CERCLA Reportable quantity (RQ) None reportable. SECTION 7 - HANDLING AND STORAGE Safe Handling procedures Use in a well-ventilated area. Wear suitable protective equipment during handling. Avoid breathing vapours. Avoid contact with eyes, skin and clothing. Do not ingest. Keep away from heat, sparks, and open flames. Avoid contact with incompatible materials. Wash thoroughly after handling. Storage requirements Store in a cool, dry, well ventilated area, away from heat and ignition sources. Store away from incompatibles and out of direct sunlight. Storage area should be clearly identified, clear of obstruction and accessible only to trained and authorized personnel. Inspect periodically for damage or leaks. No smoking in the area. Incompatible materials Strong oxidizing agents; Lewis Acids. Special packaging materials Always keep in containers made of the same materials as the supply container. SECTION 8 - EXPOSURE CONTROLS AND PERSONAL PROTECTION Exposure Limits ACGIH TLV OSHA PEL TWA STEL PEL STEL d-limonene 30 ppm (AIHA WEEL) 3 ppm 6 ppm 3 ppm ; 6 mg/m³ Ventilation and engineering measures Use general or local exhaust ventilation to maintain air concentrations below recommended exposure limits. Use explosion-proof equipment. Respiratory protection Respiratory protection is required if the concentrations exceed the TLV. A NIOSH/MSHA approved air-purifying respirator with the appropriate chemical cartridges or a positive-pressure, air-supplied respirator may be used to reduce exposure. Skin protection Wear impervious gloves, such as nitrile rubber. Advice should be sought from glove suppliers.

4 Page 4 of 8 Eye / face protection Chemical splash goggles are recommended. A full face shield may also be necessary. Other protective equipment General hygiene considerations An eyewash station and safety shower should be made available in the immediate working area. Other equipment may be required depending on workplace standards. Handle in accordance with good industrial hygiene and safety practice. Avoid breathing vapour or mist. Avoid contact with eyes, skin and clothing. Do not eat, drink, smoke or use cosmetics while working with this product. Upon completion of work, wash hands before eating, drinking, smoking or use of toilet facilities. Remove and wash contaminated clothing before re-use. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical state Liquid. Appearance gold Odour Peach-like odour. Odour threshold ph Boiling point Specific gravity Melting/Freezing point -40 C Coefficient of water/oil distribution Vapour pressure 20 C / 68 F) Solubility in water Vapour density (Air = 1) Evaporation rate (n-butyl acetate = 1) Volatile organic Compounds (VOC's) Volatiles (% by weight) Flash point 72 C Flash point Method open cup Auto-ignition temperature Lower flammable limit (% by vol.) Upper flammable limit (% by vol.) Flame Projection Length Flashback observed Viscosity Absolute pressure of container SECTION 10 STABILITY AND REACTIVITIY Stability and reactivity Hazardous polymerization Stable under the recommended storage and handling conditions prescribed. Hazardous polymerization does not occur. Conditions to avoid Keep out of direct sunlight. Keep away from excessive heat, open flames, sparks and other possible sources of ignition. Do not use in areas without adequate ventilation. Materials To Avoid And Incompatibility See Section 7 (Handling and Storage) for further details. Hazardous decomposition products Refer to Section 5 for additional Hazardous combustion products. SECTION 11 - TOXICOLOGICAL INFORMATION Target organs Eyes, skin, respiratory system and digestive system. Routes of exposure Inhalation YES Skin Absorption NO Skin & Eyes YES Ingestion YES Toxicological data There is no available data for the product itself, only for the ingredients. See below for individual ingredient acute toxicity data. LC50(4hr) LD50 inh, rat (Oral, rat) (Rabbit, dermal)

5 Page 5 of mg/kg (mouse) 3000 mg/kg d-limonene 4400 mg/kg > 5000 mg/kg Carcinogenic status Reproductive effects Teratogenicity Mutagenicity Epidemiology > 1210 mg/m³ (> 1.21 mg/l) (mist) (mouse) 1720 mg/kg 1000 mg/kg No components are listed as carcinogens by ACGIH, IARC, OSHA or NTP. Not expected to cause reproductive effects. Not expected to be a teratogen. Not expected to be mutagenic in humans. Sensitization to material May cause an allergic skin reaction (e.g. swelling, rash and eczema). No data available to indicate product or components may be respiratory sensitizers. Synergistic materials Irritancy Moderate skin irritant. Mild to moderate eye irritant. other important hazards None known. Conditions aggravated by overexposure Pre-existing skin, eye and respiratory disorders. SECTION 12 - ECOLOGICAL INFORMATION Ecotoxicity See the following tables for individual ingredient ecotoxicity data. Ecotoxicity data The acute toxicity of the product is measured to be Toxicity to fish - LC50/96h/Oncorhynchus mykiss (rainbow trout) = 20 mg/l Toxicity to daphnia - EC50/48h/Daphnia magna (Water flea) = 27 ppm Toxicity to algae - EC50/72h/algae = 40 mg/l CAS No LC50 / 96h Toxicity to Fish NOEC / 21 day M Factor d-limonene mg/l (Fathead minnow) mg/l (Fathead 1 minnow) mg/l (common carp) 1.2 mg/l/30 days (Japanese ricefish) CAS No Toxicity to Daphnia EC50 / 48h NOEC / 21 day M Factor d-limonene mg/l (Daphnia 1 magna) mg/l (Water flea) 0.85 mg/l

6 Page 6 of 8 CAS No Toxicity to Algae EC50 / 96h or 72h NOEC / 96h or 72h M Factor d-limonene Mobility Persistence Bioaccumulation potential Other Adverse Environmental effects SECTION 13 - DISPOSAL CONSIDERATIONS Handling for Disposal Methods of Disposal RCRA SECTION 14 TRANPORT INFORMATION 2.5 mg/l/72hr (Green algae) No data is available on the product itself. 1 mg/l/72hr No data is available on the product itself. Contains d-limonene; ;. d-limonene is considered to be rapidly biodegradable. is not considered readily biodegradable. is considered to be readily biodegradable. No data is available on the product itself. Contains d-limonene; Distillates (petroleum),. The log Kow value for d-limonene is 4.57 and the bioconcentration factor (BCF) is 660, suggesting d-limonene may bioaccumulate (HSDB). The log Kow value for is and the bioconcentration factor (BCF) is , suggesting may bioaccumulate (IUCLID). No data is available on the product itself. Handle waste according to recommendations in Section 7. Improper disposal can cause damage to the environment. Dispose in accordance with all applicable federal, state, provincial and local regulations. If this product, as supplied, becomes a waste in the United States, it may meet the criteria of a hazardous waste as defined under RCRA, Title 40 CFR 261. It is the responsibility of the waste generator to determine the proper waste identification and disposal method. For disposal of unused or waste material, check with local, state and federal environmental agencies. Regulatory Information UN Number Shipping Name Class TDG Not regulated. not regulated Packing Group none Label TDG Additional information Not regulated unless shipping internationally by sea. 49CFR/DOT Not regulated. not regulated none 49CFR/DOT Additional information SECTION 15 - REGULATORY INFORMATION US Federal Information Components listed below are present on the following U.S. Federal chemical lists

7 Page 7 of 8 CAS # TSCA Inventory CERCLA Reportable Quantity(RQ) (40 CFR ) SARA TITLE III Sec. 302, Extremely Hazardous Substance, 40 CFR 355 SARA TITLE III Sec. 313, 40 CFR 372, Specific Toxic Chemical Toxic Chemical de minimus Concentration Yes No d-limonene Yes No Yes No SARA TITLE III Sec. 311 and 312, MSDS Requirements, 40 CFR 370 Hazard Classes Fire Hazard; Acute Health Hazard. Chronic Health Hazard. Under SARA Sections 311 and 312, the EPA has established threshold quantities for the reporting of hazardous chemicals. The current thresholds are 500 pounds for the threshold planning quantity (TPQ), whichever is lower, for extremely hazardous substances and 10,000 pounds for all other hazardous chemicals. US State Right to Know Laws The following chemicals are specifically listed by individual States CAS # California Proposition 65 Listed Type of Toxicity CA State "Right to Know" Lists MA MN NJ PA RI No No No No No No No d-limonene No No No No No No No No Yes Yes Yes Yes Yes Yes Canadian Information WHMIS information Refer to Section 2 for a WHMIS Classification for this product. Canadian Environmental Protection Act (CEPA) information All ingredients listed appear on the Domestic Substances List (DSL). This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and this MSDS contains all the information required by the CPR. SECTION 16 - OTHER INFORMATION HMIS Rating - Chronic hazard 0 - Minimal 1 - Slight 2 - Moderate 3 - Serious 4 - Severe * Health 2 Flammability 2 Reactivity 0 Legend ACGIH American Conference of Governmental Industrial Hygienists CAS Chemical Abstract Services CERCLA Comprehensive Environmental Response, Compensation, and Liability Act of 1980 CFR Code of Federal Regulations CNS Central Nervous System DOT Department of Transportation HMIS Hazardous Materials Identification System HSDB Hazardous Substances Data Bank IARC International Agency for Research on Cancer Inh Inhalation LC Lethal Concentration LD Lethal Dose MSHA Mine Safety and Health Administration Not Applicable Not Available

8 Page 8 of 8 References NFPA National Fire Protection Association NIOSH National Institute of Occupational Safety and Health NOEC No observable effect concentration NTP National Toxicology Program OSHA Occupational Safety and Health Administration PEL Permissible exposure limit RCRA Resource Conservation and Recovery Act RTECS Registry of Toxic Effects of Chemical Substances SARA Superfund Amendments and Reauthorization Act STEL Short Term Exposure Limit TDG Canadian Transportation of Dangerous Goods Act & Regulations TLV Threshold Limit Values TWA Time Weighted Average WHMIS Workplace Hazardous Materials Identification System 1. ACGIH, Threshold Limit Values and Biological Exposure Indices for International Agency for Research on Cancer Monographs, searched Canadian Centre for Occupational Health and Safety, CCInfoWeb databases (Chempendium, HSDB and RTECs). (2013) 4. Material Safety Data Sheet from manufacturer. 5. US EPA Title III List of Lists - October California Proposition 65 List - November 8, 2013 Prepared for Telephone (604) Direct all enquiries to Prepared by ICC The Compliance Center Inc. http// DISCLAIMER OF LIABILITY This Material Safety Data Sheet was prepared by ICC The Compliance Center Inc using information provided by / obtained from and CCOHS Web Information Service. The information in the Material Safety Data Sheet is offered for your consideration and guidance when exposed to this product. ICC The Compliance Center Inc and expressly disclaim all expressed or implied warranties and assume no responsibilities for the accuracy or completeness of the data contained herein. The data in this MSDS does not apply to use with any other product or in any other process. This Material Safety Data Sheet may not be changed, or altered in any way without the expressed knowledge and permission of ICC The Compliance Center Inc and. Preparation Date (mm/dd/yyyy) 11/19/2013 END OF DOCUMENT