Avonley Road SE14 5ER London

Transcription

1 Date of issue:6/30/2015 Revision date:8/31/2015supersedes:6/30/2015 Version: 1.1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Article number : Product code : Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Main use category Industrial/Professional use spec Function or use category : Industrial use,professional use,consumer use : Used in closed systems : Lubricants and additives Uses advised against 1.3. Details of the supplier of the safety data sheet BARDAHL NL - OCD NEDERLAND BV Maxwellstraat GP Dordrecht - Nederland T F rjjonker@bardahl.nl Emergency telephone number Emergency number : +31 (0) During office hours: 8.30 t/m 17:00 h Country Organization/Company Address Emergency number Comment Guy's & St Thomas' Poisons Unit Medical Toxicology Unit, Guy's & St Thomas' Hospital Trust SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Avonley Road SE14 5ER London Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixture/Substance: SDS EU 2015: According to Regulation (EU) 2015/830 (REACH Annex II) Not classified 2.2. Label elements Labeling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display Security closing plug for children. Tactile warning 2.3. Other hazards SECTION 3: Composition/Information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] Alkyldithiophosphate de zinc (CAS No) (EC no) Skin Irrit. 2, H315 Eye Dam. 1, H318 Aquatic Chronic 2, H411 Organomolybdenum amide Aquatic Chronic 2, H411 11/18/2015 EN (English US) 1/7

2 Full text of H-phrases: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion special measures required. : Wash skin thoroughly with mild soap and water. : Irrigate copiously with clean, fresh water for at least 15 minutes, holding the eyelids apart. : Do NOT induce vomiting. Rinse mouth. Obtain emergency medical attention Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation Symptoms/injuries after skin contact Symptoms/injuries after eye contact Symptoms/injuries after ingestion 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media t expected to present a significant inhalation hazard under anticipated conditions of normal use. t expected to present a significant skin hazard under anticipated conditions of normal use. t expected to present a significant eye contact hazard under anticipated conditions of normal use. t expected to present a significant ingestion hazard under anticipated conditions of normal use. : Water haze. Foam. Powder. Dry chemical. : Do not use a heavy water stream Special hazards arising from the substance or mixture 5.3. Advice for firefighters Precautionary measures fire Firefighting instructions Protection during firefighting : Exercise caution when fighting any chemical fire. : Use water spray or fog for cooling exposed containers. : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Protective equipment For emergency responders Protective equipment : Wear suitable protective clothing and gloves. : Wear suitable protective clothing and gloves Environmental precautions Prevent entry to sewers and public waters. Notify authorities if product enters sewers or public waters Methods and material for containment and cleaning up For containment Methods for cleaning up Other information 6.4. Reference to other sections SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Handling temperature : < 40 C Hygiene measures 7.2. Conditions for safe storage, including any incompatibilities Storage conditions Storage temperature : < 40 C 7.3. Specific end use(s) : Impound and recover large spill by mixing it with inert granular solids. : Detergent. Take up liquid spill into absorbent material sand, saw dust, kieselguhr. : May be dangerously slippery if spilled. Use suitable disposal containers. : Avoid all unnecessary exposure. Both local exhaust and general room ventilation are usually required. : Wash hands and other exposed areas with mild soap and water before eat, drink or smoke and when leaving work. : Store in dry, cool, well-ventilated area. 11/18/2015 EN (English US) 2/7

3 SECTION 8: Exposure controls/personal protection 8.1. Control parameters Netherlands Grenswaarde TGG 8H (mg/m³) 5 mg/m³ (ACGIH TLV) 8.2. Exposure controls Personal protective equipment Hand protection Eye protection Skin and body protection Respiratory protection : Protective goggles. Gloves. : Wear suitable gloves resistant to chemical penetration. Recommended thickness of the material: 0.35 mm. Penetration time of glove material: 480 min : Safety glasses special clothing/skin protection equipment is recommended under normal conditions of use. special protection required where adequate ventilation is maintained. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Oily liquid. Color : Yellow-brown. Odor : Characteristic. Odor threshold ph Relative evaporation rate (butyl acetate=1) Melting point Freezing point Boiling point Flash point : > 200 C (ASTM D92) Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapor pressure Relative vapor density at 20 C Relative density Specific gravity / density : 878 kg/m³ (15 C) Solubility : Slightly soluble, the product remains on the water surface. Log Pow Viscosity, kinematic : 132 mm²/s (40 C) Viscosity, dynamic Explosive properties Oxidizing properties Explosion limits 9.2. Other information SECTION 10: Stability and reactivity Reactivity None under normal conditions Chemical stability Stable under normal conditions Possibility of hazardous reactions None under normal conditions. 11/18/2015 EN (English US) 3/7

4 10.4. Conditions to avoid Incompatible materials Strong oxidizers. acids. Bases Hazardous decomposition products SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Alkyldithiophosphate de zinc ( ) LD50 oral rat LD50 dermal rat Organomolybdenum amide LD50 oral rat LD50 dermal rat Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Viscosity, kinematic 2230 mg/kg > 2000 mg/kg > 5000 mg/kg > 2000 mg/kg 132 mm²/s (40 C) SECTION 12: Ecological information Toxicity Alkyldithiophosphate de zinc ( ) LC50 fish 1 EC50 Daphnia 1 EC50 72h algae [mg/l] 1 Organomolybdenum amide LC50 fish 1 EC50 Daphnia 1 EC50 72h algae [mg/l] 1 10 mg/l > 10 mg/l Persistence and degradability Persistence and degradability Not soluble in water, so only minimally biodegradable Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects 11/18/2015 EN (English US) 4/7

5 SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN : Dispose in a safe manner in accordance with local/national regulations UN number Not regulated for transport UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) Transport hazard class(es) ADR Transport hazard class(es) (ADR) IMDG Transport hazard class(es) (IMDG) IATA Transport hazard class(es) (IATA) ADN Transport hazard class(es) (ADN) RID Transport hazard class(es) (RID) Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) Environmental hazards Dangerous for the environment Marine pollutant Other information supplementary information available Special precautions for user - Overland transport - Transport by sea - Air transport - Inland waterway transport - Rail transport Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable 11/18/2015 EN (English US) 5/7

6 SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no REACH substances with Annex XVII restrictions Contains no REACH candidate substance Contains no REACH Annex XIV substances National regulations Germany VwVwS Annex reference 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV Netherlands SZW-lijst van kankerverwekkende stoffen SZW-lijst van mutagene stoffen NIET-limitatieve lijst van voor de voortplanting giftige stoffen Borstvoeding NIET-limitatieve lijst van voor de voortplanting giftige stoffen Vruchtbaarheid NIET-limitatieve lijst van voor de voortplanting giftige stoffen Ontwikkeling Denmark Classification remarks : Water hazard class (WGK) 2, hazardous to water (Classification according to VwVwS, Annex 4) : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) : Alkyldithiophosphate de zinc is listed : Alkyldithiophosphate de zinc is listed ne of the components are listed ne of the components are listed ne of the components are listed : Emergency management guidelines for the storage of flammable liquids must be followed Chemical safety assessment SECTION 16: Other information Indication of changes: 1.2 Function or use Modified category 8.2 Eye protection Added 8.2 Hand protection Modified Abbreviations and acronyms: Full text of H- and EUH-phrases: Abbreviations and acronyms: RID: Regulations Concerning the International Transport of Dangerous Goods by Rail ICAO: International Civil Aviation Organization ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonized System of Classification and labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) VOC: Volatile Organic Compounds (USA, EU) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent Aquatic Chronic 2 Hazardous to the aquatic environment - Chronic Hazard Category 2 Eye Dam. 1 Serious eye damage/eye irritation Category 1 Skin Irrit. 2 Skin corrosion/irritation Category 2 H315 Causes skin irritation H318 H411 Causes serious eye damage Toxic to aquatic life with long lasting effects SDS EU (REACH Annex II) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 11/18/2015 EN (English US) 6/7

7 11/18/2015 EN (English US) 7/7