Paint a bright future for your products.

Transcription

1 North America FE ATURI NG Paint a bright future for your products. Paints & Coatings and Building & Construction Materials Biocide Selection Guide for In-Can Preservation, Dry-Film Fungicide and Industrial Hygiene Applications Putting you in control.

2 From one region of the world to another, the experts of Dow Microbial Control stand ready to protect your products from microbial contamination. Let us help put you in control with: Biocide treatment recommendations Customer-specific formulation testing: Microbiological efficacy for in-can preservation Biocide stability Dry-film fungicide efficacy Algal testing Time-kill testing for product decontamination Problem solving Microbiological audits of manufacturing facilities Analytical support In-person and online training Unmatched expertise. Rely on the industry s most experienced team of experts in microbial control technologies. We offer expertise in application technology, regulatory issues and environmental research. Our products are carefully formulated based on the latest science and exhaustive performance testing. Beth A Browne, Ph.D. North American Customer Application Specialist for In-Can Preservation of Paints & Coatings, Latex Preservation, and Dry-Film Protection Regional presence, knowledge and support. The Dow Microbial Control Customer Application Centers are your source for the best microbial control products and services. Each center has a thorough knowledge of the unique challenges and opportunities of the region, providing you with local personalized support. Broadest portfolio. You have complex microbial control challenges. Our, KATHON,, and DOWICIL products are designed to meet those challenges. We understand your needs and we have the products and expertise needed to address them. The Dosemaster 2000 Portable Biocide Dosing System is a highly flexible and maneuverable drum dosing system.

3 In-can preservatives for Paints & Coatings Product Name Active Ingredient(s) Solvent Liquid or Solid Efficacy Against Bacteria (B) and Fungi (F) % Product for Use in Paints* USA (EPA) Registration Canada (PMRA) Mexico (COFEPRIS) DOWICIL QK-20 20% 2,2-dibromo-3- nitrilopropionamide (DBNPA) Glycol Liquid B/F % Yes Yes Yes 557 9% N-methyl benzisothiazolin-3-one (MBIT), 0.5% 5-chloro-2- methyl-4-isothiazolin- 3-one (CMIT) and 0.5% 2-methyl-4- isothiazolin-3-one (MIT) Proprietary Glycol Liquid B/F % Expected 2014 No No KATHON LX 1.5% 1.5% 5-chloro-2-methyl- 4-isothiazolin-3-one and 2-methyl-4-isothiazolin- 3-one (CMIT/MIT) Water Liquid B/F % Yes Yes Yes BT 2S 19% 1,2-benzisothiazolin- 3-one (BIT) Glycol Liquid B % Yes No Yes BT NV2 19% 1,2-benzisothiazolin- 3-one (BIT) Liquid B % Yes No Yes % 5-chloro-2- methyl-4-isothiazolin- 3-one and 2-methyl-4- isothiazolin-3-one (CMIT/ MIT) and 7.5% 2-bromo- 2-nitropropane-1,3-diol Water Liquid B/F % Yes No No % 1,2-benzisothiazolin- 3-one (BIT) and 10% 2-bromo-2- nitropropane-1,3-diol Liquid B % Yes No No DOWICIL 75 64% cis/trans 1-(3-chloroallyl)- 3,5,7-triaza-1- azoniaadamantane chloride (CTAC) N/A Solid B % Yes Yes No BP-10 10% 2-bromo-2- nitropropane-1,3-diol Glycol Liquid B % Yes No No BP-30 30% 2-bromo-2- nitropropane-1,3-diol Glycol Liquid B % Yes No Yes BP-PLUS 99% 2-bromo-2- nitropropane-1,3-diol N/A Solid B % Yes No No * The use range displayed represents a typical dosage range in paints in the United States. The product label must be consulted prior to use for appropriate dosage levels and instructions. Dosage levels vary by end-use. Not all end-uses are registered in California.

4 Additional biocidal product offerings for in-can preservation of Building & Construction Materials Product Name Active Ingredient(s) Solvent Liquid or Solid Efficacy Against Bacteria (B) and Fungi (F) % Product for Use in Adhesives* USA (EPA) Registration Canada (PMRA) Mexico (COFEPRIS) DXN 87% 2,6-dimethyl-mdioxane-4-ol acetate N/A Liquid B/F % Yes No No UCARCIDE 25 25% Glutaraldehyde Water Liquid B/F % Yes Yes No UCARCIDE 50 50% Glutaraldehyde Water Liquid B/F % Yes Yes Yes DOWICIDE A 71.7% Sodium o-phenylphenol (Na OPP) N/A Solid B/F % Yes Yes No DOWICIDE 25L 25.3% Sodium o-phenylphenol (Na OPP) Water/ Glycol Liquid B/F % Yes No No DOWICIDE 1E 99.5% o-phenylphenol (OPP) N/A Solid B/F % Yes No No % 2-methyl-4- isothiazolin-3-one (MIT) Water Liquid B % Yes No Yes * The use range displayed represents a typical dosage range in most adhesive types in the United States. The product label must be consulted prior to use for appropriate dosage levels and instructions. Dosage levels vary by end-use. Not all end-uses are registered in California.

5 Dry-film fungicides for Paints and Building & Construction Materials Product Name Active Ingredient(s) Solvent Liquid or Solid Efficacy Against Bacteria (B), Fungi (F) and Algae (A) % Product for Use in Paints* (severe climate) USA (EPA) Registration Canada (PMRA) Mexico (COFEPRIS) ROZONE % 4,5-dichloro- 2-n-octyl-3(2H) isothiazolinone (DCOIT) Glycol Liquid B**/F/A*** % Yes Yes Yes % 4,5-dichloro- 2-n-octyl-3(2H) isothiazolinone (DCOIT) Liquid B**/F/A*** % Yes No Yes KATHON % 4,5-dichloro- 2-n-octyl-3(2H) isothiazolinone (DCOIT) Solvent Liquid B**/F/A*** % Yes No No SKANE M-8 45% 2-n-octyl-4- isothiazolin-3-one (OIT) Glycol Liquid F % (0.4%) Yes Yes Yes IPBC 20 20% 3-Iodo-2- propynylbutylcarbamate (IPBC) Solvent Liquid F % (4.0%) Yes No No IPBC 40 40% 3-Iodo-2- propynylbutylcarbamate (IPBC) Solvent Liquid F % (2.0%) Yes No No IPBC 40 LE 40% 3-Iodo-2- propynylbutylcarbamate (IPBC) Proprietary Liquid F % (2.0%) Yes No No IPBC % 3-Iodo-2- propynylbutylcarbamate (IPBC) N/A Solid F % (0.8%) Yes No No 404D 40% chlorothalonil (CTL) Liquid F % Yes No No % 2-n-octyl-4- isothiazolin-3-one (OIT), 7.5% carbendazim (BCM), 20% diuron Liquid F/A % Yes No No AMICAL FLOWABLE 40% diiodomethyl p-tolyl sulfone (DIMTS) Liquid F % Yes Yes No AMICAL 48 95% diiodomethyl p-tolyl sulfone (DIMTS) N/A Solid F % Yes Yes No Note: AMICAL products are not recommended for use in architectural coatings. * The use range displayed represents a typical dosage range in paints in the United States. The level in parentheses represents a use level permitted in severe climates. Use rates may differ between interior and exterior paints. The product label must be consulted prior to use for appropriate dosage levels and instructions. Dosage levels vary by end-use. Where necessary, a formulation density of 10 pounds per 1 gallon was used to calculate the biocide dosage. Not all end-uses are registered in California. **DCOIT has antibacterial activity, but DCOIT alone is not sufficient for in-can antibacterial protection. ***DCOIT may not provide adequate broad-spectrum protection against algae in all formulations and environments. Low Emission Technology. Patent-pending technology from Dow Microbial Control that offers environmentally preferred carriers. Biocide products maintain the benefits of using a solvent carrier without increasing VOC.

6 Biocides for industrial hygiene, rapid decontamination and product rework Product Name Active Ingredient(s) Solvent Liquid or Solid Efficacy Against Bacteria (B) and Fungi (F) USA (EPA) Registration Canada (PMRA) Mexico (COFEPRIS) DOWICIL QK-20 20% 2,2-dibromo-3- nitrilopropionamide (DBNPA) Glycol Liquid B/F Yes Yes Yes Industrial hygiene. Long-term preservatives and proper industrial hygiene practices are necessary for microbial protection of Paints & Coatings and Building & Construction Materials. A combinational approach of routine scheduled manual cleaning, along with biocide treatments, can provide the following benefits: Minimize wild strains of bacteria and fungi in manufacturing facilities before they become acclimated and well established Maximize in-can preservative longevity Decrease the number of contamination events to reduce customer complaints and costly product recalls Prevent recycled water, equipment and raw materials from becoming sources of microbial contamination in final products Maintain manufacturing efficiency Good housekeeping measures reduce microbial dissemination and include: Eliminating sources of stagnant water Flushing, draining, drying, capping/covering hoses Keeping tank lids closed Cleaning tanks to bare metal Establishing routine visual inspections and microbial sampling because clean does not mean microbe-free Dow Microbial Control offers: Industrial hygiene training Industrial hygiene audits of manufacturing facilities Post-audit evaluation kit

7 DOWICIL QK-20 is the solution to your plant hygiene needs. Broad spectrum of activity against bacteria, fungi and algae DBNPA active ingredient is fast acting, minimizing downtime and delays due to contamination DBNPA active ingredient is compliant with Green Seal GS-11 standards Easy to use Lacks the significant foaming associated with quaternary ammonium compounds (QAC s)/quats Fast-acting, short-term problem solver that kills microorganisms and then degrades Versatile product for numerous plant hygiene applications Contact Dow Microbial Control for DOWICIL QK-20 implementation strategies Half-life in Minutes Half-life of DBNPA at three temperatures versus ph (minutes) 100,000,000 10,000,000 1,000, ,000 10,000 1, half-life at 10 C in minutes half-life at 30 C in minutes half-life at 50 C in minutes ph of Solution DOWICIL QK-20 Antimicrobial Quick Dosage Reference Guide for Industrial Microbial Clean-up Applications Uses for DOWICIL QK-20 Process Water & Raw Material Clean Up ppm ( %) Direct Product Addition ppm ( %) Recycle Water/Recycle Product Clean Up/Recycle Wastewater ppm ( %) Standard Cleaning of Vessels, Storage Tanks/Containers, Piping and Hosing ppm ( %) Heavily Fouled Solution/ Equipment Cleaning 2000 ppm (0.20%) This diagram describes a process clarifying the three main process fits for a quick kill biocide: In-process treatment, co-treatment of finished products in combination with long term preservatives, or as a stand-alone material.

8 Help where you need it. With Customer Application Centers around the globe, expert assistance to help solve microbial challenges is always within reach no matter where you are. We offer fully equipped state-of-the-art laboratory capabilities and knowledgeable technical and sales assistance to help find solutions for you. North America Western Europe Central Eastern Europe Greater China Japan and Korea Latin America Middle East and Africa Indian Subcontinent Southeast Asia Australia and New Zealand Contact Information Central and Eastern Europe: Turkey Russia Poland Western Europe: (toll-free) (phone) (fax) North America: (toll-free) (phone) (fax) Middle East and Africa: UAE South Africa (toll-free) Greater China: Shanghai Beijing Guangzhou Taiwan Southeast Asia: Philippines Indonesia Singapore Thailand Vietnam Malaysia Australia and New Zealand: (phone) (fax) Japan and Korea: Japan Korea Indian Subcontinent: (phone) (fax) Latin America: (phone) (fax) Other Global Areas: (phone) (fax) NOTICE: No freedom from infringement of any patent owned by Dow or others is to be inferred. Because use conditions and applicable laws may differ from one location to another and may change with time, Customer is responsible for determining whether products and the information in this document are appropriate for Customer s use and for ensuring that Customer s workplace and disposal practices are in compliance with applicable laws and other government enactments. The product shown in this literature may not be available for sale and/or available in all geographies where Dow is represented. The claims made may not have been approved for use in all countries. Dow assumes no obligation or liability for the information in this document. References to Dow or the Company mean the Dow legal entity selling the products to Customer unless otherwise expressly noted. NO WARRANTIES ARE GIVEN; ALL IMPLIED WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE ARE EXPRESSLY EXCLUDED. Please note that not all products are registered in all regions for all applications. Please contact your local Dow representative for detailed technical information applicable to your individual situation. USE BIOCIDES SAFELY. ALWAYS READ THE LABEL AND PRODUCT INFORMATION BEFORE USE. Trademark of The Dow Chemical Company ( Dow ) or an affiliated company of Dow Form Number: /18/13-TCG