Revision Date 10-October-2014 Version 1 1. PRODUCT AND COMPANY IDENTIFICATION. INFOTRAC (International) (North America)

Transcription

1 SAFETY DATA SHEET Version 1 1. PRODUCT AND COMPANY IDENTIFICATION Product Identifier Product Name Foremost 1817 Citri-Kote Product Code 1817 Recommended Use of the Chemical and Restrictions on Use Recommended Use Industrial cleaner. Details of the Supplier of the Safety Data Sheet Supplier Address Delta Foremost Chemical Corporation 3915 Air Park St. Memphis, Tennessee Emergency Telephone Number Company Phone Number (901) Emergency Telephone INFOTRAC (International) (North America) Classification 2. HAZARDS IDENTIFICATION Skin Corrosion/Irritation Category 2 Aspiration toxicity Category 1 Flammable liquids Category 4 Signal Word DANGER Hazard Statements Causes skin irritation May be fatal if swallowed and enters airways Combustible liquid and vapor Appearance Yellow Emulsion Physical State Liquid Emulsion Odor Citrus Page 1 / 7

2 Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection Keep away from heat/sparks/open flames/hot surfaces. No smoking Keep container tightly closed Ground/bond container and receiving equipment Use explosion-proof equipment Use only non-sparking tools Take precautionary measures against static discharge Precautionary Statements - Response If skin irritation occurs: Get medical advice/attention IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower Wash contaminated clothing before reuse IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician Do NOT induce vomiting In case of fire: Use CO2, dry chemical, or foam for extinction Precautionary Statements - Storage Store locked up Store in a well-ventilated place. Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards Not Otherwise Classified (HNOC) May be harmful if swallowed May be harmful in contact with skin Other Hazards Very toxic to aquatic life with long lasting effects Very toxic to aquatic life 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No Weight-% Proprietary First Aid Measures 4. FIRST AID MEASURES General Advice Eye Contact Skin Contact Inhalation Provide this SDS to medical personnel for treatment. Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get immediate medical advice/attention. Wash affected areas with copious amount of soap and water. If there is dryness and skin irritation, use a skin cream or Vaseline on skin. If irritation persists, see physician. Remove exposed individual(s) to fresh air for 20 minutes. Consult a physician / poison center if individual's condition declines or if symptoms persist. Page 2 / 7

3 Ingestion Do not induce vomiting unless directed by medical personnel. If vomiting occurs, lean patient forward to maintain an open airway & prevent aspiration. Get immediate medical attention. Most Important Symptoms and Effects, both Acute and Delayed Symptoms May cause skin and eye irritation. Direct contact with eyes may cause temporary irritation. May cause nausea, vomiting, stomach ache, and diarrhea. May cause respiratory irritation. Indication of any Immediate Medical Attention and Special Treatment Needed Note to Physicians Aspiration into the lungs may occur during ingestion or vomiting, causing lung damage or even death due to chemical pneumonia. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Foam, carbon dioxide or dry chemical extinguisher. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media Water. Specific Hazards Arising from the Chemical Closed containers may explode due to buildup of pressure when exposed to extreme heat. Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Water may be used to cool closed containers to prevent pressure buildups and possible ignition or explosion when exposed to extreme heat. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions, Protective Equipment and Emergency Procedures Personal Precautions Wear protective clothing as described in Section 8 of this safety data sheet. ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Methods and Material for Containment and Cleaning Up Methods for Containment Methods for Cleaning Up Prevent further leakage or spillage if safe to do so. Absorb spill with inert material (e.g. dry sand or earth). Use clean non-sparking tools to collect absorbed material. Sweep up absorbed material and shovel into suitable containers for disposal. Discard any product, residue, disposable container or liner in full compliance with federal, state, and local regulations. For waste disposal, see section 13 of the SDS. 7. HANDLING AND STORAGE Precautions for Safe Handling Advice on Safe Handling Handle in accordance with good industrial hygiene and safety practice. Wash face, hands, and any exposed skin thoroughly after handling. Use personal protection recommended in Section 8. Keep away from heat/sparks/open flames/hot surfaces. No smoking. Use spark-proof tools and explosion-proof equipment. Take precautionary measures against static discharges. Keep container closed when not in use. Conditions for Safe Storage, Including any Incompatibilities Page 3 / 7

4 Storage Conditions Keep container tightly closed and store in a cool, dry and well-ventilated place. Store locked up. Incompatible Materials Strong oxidizing agents. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines The following information is given as general guidance Appropriate Engineering Controls Engineering Controls Good general mechanical ventilation. Local exhaust recommended. Individual Protection Measures, such as Personal Protective Equipment Eye/Face Protection Skin and Body Protection Respiratory Protection Goggles or face shield. Wear rubber or neoprene gloves, Rubber apron. For normal use, none necessary. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Information on Basic Physical and Chemical Properties 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State Liquid Emulsion Appearance Yellow Emulsion Odor Citrus Color Pale Yellow Odor Threshold Property Values Remarks Method ph Melting Point/Freezing Point Not applicable Boiling Point/Boiling Range 176 C / F Flash Point C / F Tag Closed Cup Evaporation Rate Not applicable Flammability (Solid, Gas) Upper Flammability Limits Not established Lower Flammability Limit Not established Vapor Pressure Not established Vapor Density Not established Specific Gravity 0.90 (1=Water) Water Solubility Emulsifier Solubility in Other Solvents Partition Coefficient Autoignition Temperature Decomposition Temperature Kinematic Viscosity Dynamic Viscosity Explosive Properties Oxidizing Properties Reactivity Not reactive under normal conditions. 10. STABILITY AND REACTIVITY Page 4 / 7

5 Chemical Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous Polymerization Hazardous polymerization does not occur. Conditions to Avoid Heat, flames and sparks. Incompatible Materials Strong oxidizing agents. Hazardous Decomposition Products None known based on information supplied. Information on Likely Routes of Exposure Product Information 11. TOXICOLOGICAL INFORMATION Eye Contact Skin Contact Inhalation Ingestion Direct contact with eyes may cause temporary irritation. Causes skin irritation. May be harmful in contact with skin. May cause irritation of respiratory tract. May be harmful if swallowed. Potential for aspiration if swallowed. Component Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 = 4400 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) - Information on Physical, Chemical and Toxicological Effects Symptoms Please see section 4 of this SDS for symptoms. Delayed and Immediate Effects as well as Chronic Effects from Short and Long-term Exposure Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. However, the product as a whole has not been tested. Chemical Name ACGIH IARC NTP OSHA Group 3 X IARC (International Agency for Research on Cancer) Group 3 IARC components are "not classifiable as human carcinogens" OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present Aspiration Hazard May be fatal if swallowed and enters airways. Numerical Measures of Toxicity Page 5 / 7

6 12. ECOLOGICAL INFORMATION Ecotoxicity Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects. Chemical Name Algae/aquatic plants Fish Toxicity to microorganisms : 96 h Pimephales promelas mg/l LC50 flow-through 35: 96 h Oncorhynchus mykiss mg/l LC50 Crustacea Persistence and Degradability Bioaccumulation Mobility Other Adverse Effects 13. DISPOSAL CONSIDERATIONS Waste Treatment Methods Disposal of Wastes Contaminated Packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. Disposal should be in accordance with applicable regional, national and local laws and regulations. Chemical Name California Hazardous Waste Status Toxic 14. TRANSPORT INFORMATION Note DOT Proper Shipping Name Hazard Class Packing Group IATA Proper Shipping Name Hazard Class Packing Group Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances. Combustible liquid, n.o.s. (Contains terpene hydrocarbons) Combustible liquid III Combustible liquid, n.o.s. (Contains terepene hydrocarbons) Combustible liquid III Page 6 / 7

7 IMDG Proper Shipping Name Combustible liquid, n.o.s. (Contains terpene hydrocarbons) Hazard Class Combustible liquid Packing Group III International Inventories Not Determined 15. REGULATORY INFORMATION Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances US Federal Regulations SARA 313 US State Regulations U.S. State Right-to-Know Regulations Not Determined 16. OTHER INFORMATION NFPA HMIS Health Hazards 0 Health Hazards 1 Flammability 2 Flammability 2 Instability 0 Physical Hazards 0 Special Hazards Personal Protection Revision Date Revision Note 10-October-2014 New format Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet Page 7 / 7