MATERIAL SAFETY DATA SHEET

Transcription

1 ISO-TEK 8540 MATERIAL SAFETY DATA SHEET 1. PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: GHOSTSHIELD ISO-TEK 8540 MANUFACTURER: KRETETEK INDUSTRIES STREET ADDRESS: 1000 N WEST STREET CITY, STATE, ZIP: WILMINGTON, DE INFORMATION PHONE: EMERGENCY PHONE: CHEMTREC DATE REVISED: 1/1/15 2. COMPOSITION OF COMPONENTS COMPONENTS CAS NO. OSHA PEL ACGIH TLV OSHA STEL TRIETHOXYOCTYLSILANE TRADE SECRET NONE NONE 3. FIRST AID MEASURES GENERAL INFORMATION: GET MEDICAL ATTENTION IF IRRITATION OR OTHER SYMPTOMS OCCUR. BEFORE SEEKING MEDICAL ATTENTION REMOVE CONTAMINATED CLOTHING AND SHOES. TAKE A COPY OF THE SAFETY DATA SHEET WHEN GOING FOR MEDICAL TREATMENT. AFTER INHALATION: IF INHALED AS AEROSOL, REMOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. AFTER CONTACT WITH THE SKIN: IF CONTACT WITH SKIN, IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER OR WITH WATER AND SOAP. AFTER CONTACT WITH THE EYES: IF CONTACT WITH EYES, IMMEDIATELY HOLD EYELIDS APART AND FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MIN. AFTER SWALLOWING: FOR INGESTION, IF CONSCIOUS, GIVE SEVERAL GLASSES OF WATER BUT DO NOT INDUCE VOMITING. IF VOMITING DOES OCCUR, GIVE ADDITIONAL FLUIDS. GET MEDICAL ATTENTION IMMEDIATELY. SHOW LABEL IF POSSIBLE. 4. FIRE-FIGHTING MEASURES FLAMMABLE PROPERTIES: PROPERTY: VALUE: METHOD: FLASH POINT...: 70 C (158 F) (EN 22719) SUSTAINED COMBUSTIBILITY...: > 100 C (> 212 F) (ISO 9038) BOILING POINT / BOILING RANGE...: 100 C (212 F) LOWER EXPLOSION LIMIT (LEL)...: NO DATA AVAILABLE UPPER EXPLOSION LIMIT (UEL)...: NO DATA AVAILABLE IGNITION TEMPERATURE...: 395 C (743 F) (-) NFPA HAZARD CLASS (COMB./FLAM.LIQUID)...: IIIA FIRE AND EXPLOSION HAZARDS: AS A RESULT OF HYDROLYSIS FLAMMABLE VAPORS MAY ACCUMULATE IN THE CONTAINER HEAD SPACE. EXPLOSION LIMITS FOR HYDROLYSIS PRODUCT: % V/V (ETHANOL). THIS MATERIAL WILL FLASH BUT DOES NOT SUSTAIN COMBUSTION. RECOMMENDED EXTINGUISHING MEDIA: WATER-MIST, CARBON DIOXIDE, DRY CHEMICAL OR ALCOHOL-RESISTANT FOAM. UNSUITABLE EXTINGUISHING MEDIA: NONE KNOWN. SPECIAL EXPOSURE HAZARDS ARISING FROM THE SUBSTANCE OR PREPARATION ITSELF, COMBUSTION PRODUCTS, RESULTING GASES: NOT APPLICABLE.

2 FIRE FIGHTING PROCEDURES: FIRE FIGHTERS SHOULD WEAR FULL PROTECTIVE CLOTHING INCLUDING A SELF-CONTAINED BREATHING APPARATUS. COOL ENDANGERED CONTAINERS WITH WATER. 5. STABILITY AND REACTIVITY GENERAL INFORMATION: IF STORED AND HANDLED IN ACCORDANCE WITH STANDARD INDUSTRIAL PRACTICES NO HAZARDOUS REACTIONS ARE KNOWN. CONDITIONS TO AVOID PROTECT AGAINST FROST. PROTECT FROM HEAT. MATERIALS TO AVOID: REACTS WITH: ACIDS AND ALKALIS. REACTION CAUSES THE FORMATION OF: ETHANOL. HAZARDOUS DECOMPOSITION PRODUCTS: ETHANOL FURTHER INFORMATION: HAZARDOUS POLYMERIZATION CANNOT OCCUR. 6. HAZARDOUS IDENTIFICATION HAZARDS CLASSIFICATIONS : HEALTH: 1 FLAMMABILITY: 2 REACTIVITY: 1 PERSONAL PROTECTIVE EQUIPMENT: I HAZARDOUS MATERIALS IDENTIFICATION SYSTEM AND HMIS ARE REGISTERED TRADEMARKS OF THE NATIONAL PAINT AND COATINGS ASSOCIATION. (HMIS CODES ARE BASED ON CONTACT WITH THE PRODUCT AS PACKAGED AND ANY HYDROLYSIS BY-PRODUCTS, IF PRESENT.) NOTE: RESPIRATORY PROTECTION IS ONLY RECOMMENDED IN THE EVENT THAT VENTILATION OR ENGINEERING CONTROLS ARE UNABLE TO MAINTAIN EXPOSURES BELOW RECOMMENDED LEVELS; OR IN THE EVENT OF A SPILL OR OTHER EMERGENCY RESPONSE SITUATION. CANADIAN WHMIS CLASSIFICATION: B3 EMERGENCY OVERVIEW AND POTENTIAL HAZARDS SIGNAL WORD: CAUTION PHYSICAL HAZARDS: THIS MATERIAL WILL FLASH BUT DOES NOT SUSTAIN COMBUSTION. OSHA COMBUSTIBLE LIQUID AND VAPOR. ACUTE HEALTH EFFECTS ROUTE OF ENTRY OR POSSIBLE CONTACT: EYES, SKIN, INHALATION, INGESTION EYE CONTACT: NO ACUTE TOXIC EFFECTS ARE EXPECTED. SKIN CONTACT: MAY CAUSE SLIGHT SKIN IRRITATION. INHALATION: NO ACUTE TOXIC EFFECTS ARE EXPECTED. IF INHALED AS AEROSOL LUNG DAMAGE IS POSSIBLE. INGESTION: NOT EXPECTED IN INDUSTRIAL USE. ADDITIONAL INFORMATION ON ACUTE HEALTH EFFECTS: THIS MATERIAL RELEASES ETHANOL UPON HYDROLYSIS. ETHANOL (CAS-NO ) IS AN IRRITANT TO THE EYES AND MUCOUS MEMBRANES. OVEREXPOSURE HAS BEEN SHOWN TO CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION. DIRECT CONTACT WITH THE EYES WILL CAUSE BURNING AND STINGING. FURTHER INFORMATION: CHRONIC HEALTH EFFECTS: NONE KNOWN. SEE "ADDITIONAL INFORMATION ON ACUTE HEALTH EFFECTS". MEDICAL CONDITIONS WHICH MAY BE AGGRAVATED BY EXPOSURE: UNKNOWN CARCINOGENS/REPRODUCTIVE TOXINS: THIS MATERIAL DOES NOT CONTAIN ANY REPRODUCTIVE TOXINS AT OR ABOVE OSHA OR WHMIS REPORTABLE LEVELS. THERE ARE NO CARCINOGENIC INGREDIENTS PRESENT AT OR OVER 0.1% IN THIS MATERIAL. 7. ACCIDENTAL RELEASE MEASURES PRECAUTIONS: WEAR PERSONAL PROTECTION EQUIPMENT. KEEP UNPROTECTED PERSONS AWAY. AVOID CONTACT WITH EYES AND SKIN. AVOID INHALING MISTS AND VAPOURS. IF MATERIAL IS RELEASED INDICATE RISK OF SLIPPING. HAZWOPER PPE LEVEL: D CONTAINMENT: PREVENT MATERIAL FROM ENTERING SURFACE WATERS, DRAINS OR SEWERS AND SOIL. CONTAIN ANY FLUID THAT RUNS OUT USING SUITABLE MATERIAL (E.G. EARTH). RETAIN CONTAMINATED WATER/EXTINGUISHING WATER. DISPOSE OF IN PRESCRIBED MARKED CONTAINERS. SPILLS OF MATERIAL WHICH COULD REACH SURFACE WATERS MUST BE REPORTED TO THE UNITED STATES COAST GUARD NATIONAL RESPONSE CENTER'S TOLL FREE PHONE NUMBER (800) METHODS FOR CLEANING UP: DO NOT FLUSH AWAY WITH WATER. FOR SMALL AMOUNTS: ABSORB WITH A LIQUID BINDING MATERIAL SUCH AS DIATOMACEOUS EARTH AND DISPOSE OF ACCORDING TO LOCAL/STATE/FEDERAL REGULATIONS. CONTAIN LARGER AMOUNTS AND PUMP UP INTO SUITABLE CONTAINERS. CLEAN ANY SLIPPERY COATING THAT REMAINS USING A DETERGENT / SOAP SOLUTION OR ANOTHER BIODEGRADABLE CLEANER. EXHAUST VAPOURS. FURTHER INFORMATION: ELIMINATE ALL SOURCES OF IGNITION.

3 8. PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: PHYSICAL STATE / FORM...: FLUID - EMULSION COLOUR...: WHITE ODOUR...: SLIGHT SAFETY PARAMETERS PROPERTY: VALUE: METHOD: MELTING POINT / MELTING RANGE...: -1 C (30 F) BOILING POINT / BOILING RANGE...: 100 C (212 F) FLASH POINT...: 70 C (158 F) (EN 22719) SUSTAINED COMBUSTIBILITY...: > 100 C (> 212 F) (ISO 9038) IGNITION TEMPERATURE...: 395 C (743 F) (-) LOWER EXPLOSION LIMIT (LEL)...: NO DATA AVAILABLE UPPER EXPLOSION LIMIT (UEL)...: NO DATA AVAILABLE VAPOUR PRESSURE...: 23 HPA AT 20 C (68 F) DENSITY...: 0.95 G/CM3 AT 20 C (68 F) WATER SOLUBILITY / MISCIBILITY...: COMPLETELY MISCIBLE FURTHER INFORMATION: RE: SOLUBILITY IN WATER: HYDROLYTIC DECOMPOSITION OCCURS. EXPLOSION LIMITS FOR RELEASED ETHANOL: %(V). 9. WASTE DISPOSAL PRODUCT DISPOSAL RECOMMENDATION: DISPOSE OF ACCORDING TO REGULATIONS BY INCINERATION IN A SPECIAL WASTE INCINERATOR. OBSERVE LOCAL/STATE/FEDERAL REGULATIONS. PACKAGING DISPOSAL RECOMMENDATION: COMPLETELY DISCHARGE CONTAINERS (NO TEAR DROPS, NO POWDER REST, SCRAPED CAREFULLY). CONTAINERS MAY BE RECYCLED OR RE- USED. OBSERVE LOCAL/STATE/FEDERAL REGULATIONS. 10. HANDLING AND STORAGE PRECAUTIONS FOR SAFE HANDLING: ENSURE ADEQUATE VENTILATION. KEEP AWAY FROM INCOMPATIBLE SUBSTANCES. SPILLED SUBSTANCE INCREASES RISK OF SLIPPING. PRECAUTIONS AGAINST FIRE AND EXPLOSION: FLAMMABLE VAPORS MAY ACCUMULATE AND FORM EXPLOSIVE MIXTURES WITH AIR IN CONTAINERS, PROCESS VESSELS, INCLUDING PARTIAL, EMPTY AND UNCLEANED CONTAINERS AND VESSELS, OR OTHER ENCLOSED SPACES. KEEP AWAY FROM SOURCES OF IGNITION AND DO NOT SMOKE. TAKE PRECAUTIONARY MEASURES AGAINST ELECTROSTATIC CHARGING. COOL ENDANGERED CONTAINERS WITH WATER. STORAGE - CONDITIONS FOR STORAGE ROOMS AND VESSELS: NONE KNOWN ADVICE FOR STORAGE OF INCOMPATIBLE MATERIALS: NOT APPLICABLE FURTHER INFORMATION FOR STORAGE: PROTECT AGAINST MOISTURE. KEEP CONTAINER TIGHTLY CLOSED AND STORE IN A COOL, WELL VENTILATED PLACE. MINIMUM TEMPERATURE ALLOWED DURING STORAGE AND TRANSPORTATION: 0 C (32 F) DO NOT ALLOW THIS MATERIAL TO FREEZE. MAXIMUM TEMPERATURE ALLOWED DURING STORAGE AND TRANSPORTATION: 40 C (104 F) 11. EXPOSURE CONTROLS ENGINEERING CONTROLS VENTILATION: USE ONLY WITH ADEQUATE VENTILATION. LOCAL EXHAUST: WHERE MIST OR VAPOR MAY BE GENERATED. LOCAL EXHAUST VENTILATION WHICH MEETS THE REQUIREMENTS OF ANSI Z9.2 IS RECOMMENDED TO CONTROL AIRBORNE CONTAMINANTS AT THE POINT OF USE. ASSOCIATE SUBSTANCES WITH SPECIFIC CONTROL PARAMETERS SUCH AS LIMIT VALUES MAXIMUM AIRBORNE CONCENTRATIONS AT THE WORKPLACE: CAS NO. MATERIAL TYPE MG/M3 PPM DUST FRACT ETHANOL OSHA PEL 1, ,000.0 RE ETHANOL (CAS NO ): STEL IS 1000 PPM; CARCINOGENICITY: A3 (ACGIH). PERSONAL PROTECTION EQUIPMENT (PPE)

4 RESPIRATORY PROTECTION: RESPIRATORY PROTECTION IS NOT NORMALLY REQUIRED. IF SPRAYING OR OTHER OPERATIONS WHICH GENERATE AN AEROSOL MIST ARE CONDUCTED, RESPIRATORY PROTECTION FOR EXPOSED PERSONNEL IS RECOMMENDED. A NIOSH APPROVED AIR PURIFYING RESPIRATOR EQUIPPED WITH UNIVERSAL MULTI-CONTAMINANT, MULTI- GAS/VAPOR CARTRIDGES AND AT LEAST P-99 SOLID/AEROSOL PARTICULATE FILTERS IS RECOMMENDED IF OVEREXPOSURE TO DUSTS, MISTS, OR VAPORS COULD OCCUR. HAND PROTECTION: ANY LIQUID-TIGHT RUBBER OR VINYL GLOVES. EYE PROTECTION: SAFETY GLASSES WITH SIDE SHIELDS OR CHEMICAL SAFETY GOGGLES. WHERE THERE IS RISK OF SPLASHING: TIGHT FITTING CHEMICAL SAFETY GOGGLES. OTHER PROTECTIVE CLOTHING OR EQUIPMENT: ADDITIONAL SKIN PROTECTION, SUCH AS SARANEX COATED TYVEK APRON, OVER-SLEEVES, LAB COAT, COVERALLS, OR PROTECTIVE SUIT SHOULD BE WORN IF SPLASHING COULD OCCUR. PROVIDE EYE BATH AND SAFETY SHOWER. GENERAL HYGIENE AND PROTECTION MEASURES: AVOID CONTACT WITH EYES, SKIN AND CLOTHING. AVOID BREATHING DUST/VAPOR/MIST/GAS/AEROSOL. WHEN HANDLING DO NOT EAT, DRINK, SMOKE OR APPLY COSMETICS. WASH THOROUGHLY AFTER HANDLING. 12. TOXICOLOGICAL INFORMATION INFORMATION ON TOXICOLOGICAL EFFECTS GENERAL INFORMATION: DATA DERIVED FOR THE PRODUCT AS A WHOLE ARE OF HIGHER PRIORITY THAN DATA FOR SINGLE INGREDIENTS. TOXICOLOGICAL TESTING HAS NOT BEEN CONDUCTED WITH THIS MATERIAL. THE TOXICOLOGY INFORMATION LISTED BELOW IS BASED ON THE COMPONENTS OF THE MATERIAL. ACUTE TOXICITY ASSESSMENT: FOR THIS ENDPOINT NO TOXICOLOGICAL TEST DATA IS AVAILABLE FOR THE WHOLE PRODUCT. ACUTE TOXICITY ESTIMATE (ATE): ATEMIX (ORAL): > 2000 MG/KG SKIN CORROSION/IRRITATION ASSESSMENT: FOR THIS ENDPOINT NO TOXICOLOGICAL TEST DATA IS AVAILABLE FOR THE WHOLE PRODUCT. SERIOUS EYE DAMAGE / EYE IRRITATION ASSESSMENT: FOR THIS ENDPOINT NO TOXICOLOGICAL TEST DATA IS AVAILABLE FOR THE WHOLE PRODUCT. RESPIRATORY OR SKIN SENSITIZATION ASSESSMENT: FOR THIS ENDPOINT NO TOXICOLOGICAL TEST DATA IS AVAILABLE FOR THE WHOLE PRODUCT. GERM CELL MUTAGENICITY ASSESSMENT: FOR THIS ENDPOINT NO TOXICOLOGICAL TEST DATA IS AVAILABLE FOR THE WHOLE PRODUCT. CARCINOGENICITY ASSESSMENT: FOR THIS ENDPOINT NO TOXICOLOGICAL TEST DATA IS AVAILABLE FOR THE WHOLE PRODUCT. REPRODUCTIVE TOXICITY ASSESSMENT: FOR THIS ENDPOINT NO TOXICOLOGICAL TEST DATA IS AVAILABLE FOR THE WHOLE PRODUCT. SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) ASSESSMENT: FOR THIS ENDPOINT NO TOXICOLOGICAL TEST DATA IS AVAILABLE FOR THE WHOLE PRODUCT. SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) ASSESSMENT: FOR THIS ENDPOINT NO TOXICOLOGICAL TEST DATA IS AVAILABLE FOR THE WHOLE PRODUCT. ASPIRATION HAZARD ASSESSMENT: FOR THIS ENDPOINT NO TOXICOLOGICAL TEST DATA IS AVAILABLE FOR THE WHOLE PRODUCT. FURTHER TOXICOLOGICAL INFORMATION DATA RELATED TO INGREDIENTS: PRODUCT OF HYDROLYSIS (ETHANOL): ACCORDING TO LITERATURE, ETHANOL ( ) IRRITATES THE MUCOUS MEMBRANES, SLIGHTLY IRRITATES THE SKIN, DEGREASES THE SKIN, IS NARCOTIC AND MAY CAUSE LIVER DAMAGE. 13. ECOLOGICAL INFORMATION TOXICITY ASSESSMENT: FOR THE PRODUCT AS A WHOLE, NO TEST DATA IS AVAILABLE. PERSISTENCE AND DEGRADABILITY ASSESSMENT: SILANOL- AND/OR SILOXANOL-COMPOUNDS: BIOLOGICALLY NOT DEGRADABLE. DATA RELATED TO INGREDIENTS: PRODUCT OF HYDROLYSIS (ETHANOL): THE HYDROLYSIS PRODUCT (ETHANOL) IS READILY BIOLOGICALLY DEGRADABLE. BIOACCUMULATIVE POTENTIAL ASSESSMENT: BIOACCUMULATION IS NOT EXPECTED TO OCCUR. MOBILITY IN SOIL ASSESSMENT: FOR THE PRODUCT AS A WHOLE, NO TEST DATA IS AVAILABLE. OTHER ADVERSE EFFECTS: NONE KNOWN 14. TRANSPORT INFORMATION US DOT & CANADA TDG SURFACE OTHER INFORMATION...: THIS MATERIAL HAS BEEN TESTED AND DOES NOT SUSTAIN COMBUSTION. PROTECT FROM FREEZING, WHEN EXPOSED TO COLD TEMPERATURES APPROACHING 0 C (32 F) OR BELOW. TRANSPORT BY SEA IMDG-CODE AIR TRANSPORT ICAO-TI/IATA-DGR

5 15. ADDITIONAL INFORMATION ADDITIONAL INFORMATION: THIS MATERIAL SAFETY DATA SHEET (MSDS) MEETS THE REQUIREMENTS OF THE FEDERAL OSHA HAZARD COMMUNICATION STANDARD (29 CFR ). THIS PRODUCT HAS BEEN CLASSIFIED ACCORDING TO THE HAZARD CRITERIA OF THE CONTROLLED PRODUCTS REGULATIONS (CPR) AND THE MSDS CONTAINS ALL OF THE INFORMATION REQUIRED BY THE CPR. THIS INFORMATION RELATES TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN ANY PROCESS. SUCH INFORMATION IS TO THE BEST OF OUR KNOWLEDGE AND BELIEF ACCURATE AND RELIABLE AS OF THE DATE COMPILED. HOWEVER, NO REPRESENTATION, WARRANTY OR GUARANTEE EXPRESSED OR IMPLIED, IS MADE AS TO ITS ACCURACY, RELIABILITY OR COMPLETENESS. IT IS THE USER'S RESPONSIBILITY TO SATISFY HIMSELF AS TO THE SUITABILITY AND COMPLETENESS OF SUCH INFORMATION FOR HIS OWN PARTICULAR USE. WE DO NOT ACCEPT LIABILITY FOR ANY LOSS OR DAMAGE THAT MAY OCCUR FROM THE USE OF THIS INFORMATION. NOTHING HEREIN SHALL BE CONSTRUED AS A RECOMMENDATION FOR USES WHICH INFRINGE VALID PATENTS OR AS EXTENDING A LICENSE UNDER VALID PATENTS. THIS MSDS PROVIDES SELECTED REGULATORY INFORMATION ON THIS PRODUCT, INCLUDING ITS COMPONENTS. THIS IS NOT INTENDED TO INCLUDE ALL REGULATIONS. IT IS THE RESPONSIBILITY OF THE USER TO KNOW AND COMPLY WITH ALL APPLICABLE RULES, REGULATIONS AND LAWS RELATING TO THE PRODUCT BEING USED. VERTICAL LINES IN THE LEFT-HAND MARGIN INDICATE CHANGES COMPARED WITH THE PREVIOUS VERSION.