: Zinc Phosphate Tribasic Tetrahydrate

Transcription

1 SECTION 1: Identification Zinc Phosphate Tribasic Tetrahydrate Date of issue: 10/28/2015 Revision date: 10/28/2015 Supersedes: 06/01/2015 Version: Identification Product form : Substance Substance name : Zinc Phosphate Tribasic Tetrahydrate CAS No : Product code : 2987 Formula : Zn3(PO4)2.2H2O 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Food Additives in Nutrients Food industry: supplement 1.3. Details of the supplier of the safety data sheet Jost Chemical Co Lackland Rd. Saint Louis, Missouri T F justin.kuehnel@jostchemical.com Emergency telephone number Emergency number : CHEMTREC SECTION 2: Hazard(s) identification 2.1. Classification of the substance or mixture GHS-US classification Not classified 2.2. Label elements GHS-US labeling No labeling applicable 2.3. Other hazards 2.4. Unknown acute toxicity (GHS US) Not applicable SECTION 3: Composition/Information on ingredients 3.1. Substance Substance type : Mono-constituent Full text of H-phrases: see section Mixture Not applicable SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : If you feel unwell, seek medical advice. : Remove the victim into fresh air. Respiratory problems: consult a doctor/medical service. : Rinse with water. Soap may be used. Take victim to a doctor if irritation persists. : Rinse with water. Take victim to an ophthalmologist if irritation persists. : Rinse mouth with water. Immediately after ingestion: give lots of water to drink. Victim is fully conscious: immediately induce vomiting. Call Poison Information Centre ( Consult a doctor/medical service if you feel unwell Most important symptoms and effects, both acute and delayed Symptoms/injuries. Symptoms/injuries after inhalation : May cause respiratory irritation. Symptoms/injuries after skin contact : May cause moderate irritation. 10/28/2015 EN (English US) Page 1

2 Symptoms/injuries after eye contact Symptoms/injuries after ingestion : May cause slight irritation. : Gastrointestinal complaints Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Adapt extinguishing media to the environment. Unsuitable extinguishing media : No unsuitable extinguishing media known Special hazards arising from the substance or mixture Fire hazard : Non combustible. Explosion hazard on direct explosion hazard. No data available on indirect explosion hazard. Reactivity : On burning: release of toxic and corrosive gases/vapours (phosphorus oxides, zinc oxide) Advice for firefighters Precautionary measures fire Firefighting instructions Protection during firefighting : Exposure to fire/heat: keep upwind. Exposure to fire/heat: consider evacuation. Exposure to fire/heat: have neighbourhood close doors and windows. : Dilute toxic gases with water spray. Take account of environmentally hazardous firefighting water. Use water moderately and if possible collect or contain it. : Heat/fire exposure: compressed air/oxygen apparatus. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Protective equipment Emergency procedures Measures in case of dust release : Gloves. Protective clothing. Dust cloud production: compressed air/oxygen apparatus. See "Material-Handling" to select protective clothing. : Mark the danger area. Prevent dust cloud formation. No naked flames. : In case of dust production: keep upwind. Dust production: have neighbourhood close doors and windows For emergency responders 6.2. Environmental precautions Prevent soil and water pollution. Prevent spreading in sewers Methods and material for containment and cleaning up For containment : Contain released substance, pump into suitable containers. Consult "Material-handling" to select material of containers. Plug the leak, cut off the supply. Dam up the solid spill. Knock down/dilute dust cloud with water spray. Methods for cleaning up : Stop dust cloud by covering with sand/earth. Scoop solid spill into closing containers. See "Material-handling" for suitable container materials. Carefully collect the spill/leftovers. Clean contaminated surfaces with an excess of water Reference to other sections SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Comply with the legal requirements. Do not discharge the waste into the drain. Avoid raising dust. Keep away from naked flames/heat. Observe normal hygiene standards. Keep container tightly closed. Carry operations in the open/under local exhaust/ventilation or with respiratory protection. : Do not eat, drink or smoke when using this product. Always wash hands after handling the product Conditions for safe storage, including any incompatibilities Technical measures : Does not require any specific or particular technical measures. Comply with applicable regulations. Storage conditions : Keep container closed when not in use. Heat-ignition : heat sources. 10/28/2015 EN (English US) 2/6

3 Storage area Packaging materials : Store in a dry area. Meet the legal requirements. : SUITABLE MATERIAL: wood. polyethylene. glass. SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Appropriate engineering controls Personal protective equipment : Ensure good ventilation of the work station. Extraction to remove dust at its source. : Dust production: dust mask with filter type P1. Gloves. Safety glasses. Materials for protective clothing : Wear suitable protective clothing, gloves and eye/face protection. Hand protection : Impermeable protective gloves. Eye protection : Safety glasses. In case of dust production: protective goggles. Skin and body protection : Protective clothing. Respiratory protection : Dust production: dust mask with filter type P1. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Solid Appearance : Crystalline solid. Powder. Color : Colourless to white Odor : Odourless Odor threshold ph : 7 (10 %) Melting point : > 105 C Freezing point Boiling point : Not applicable Flash point : Not applicable Relative evaporation rate (butyl acetate=1) Flammability (solid, gas) Explosion limits Explosive properties Oxidizing properties Vapor pressure Relative density : Relative vapor density at 20 C Specific gravity / density : kg/m³ Molecular mass : g/mol Solubility : Insoluble in water. Substance sinks in water. Soluble in ammonium hydroxide. Soluble in acids. Water: 0.03 g/l Log Pow Auto-ignition temperature Decomposition temperature Viscosity Viscosity, kinematic Viscosity, dynamic 9.2. Other information VOC content : Not applicable 10/28/2015 EN (English US) 3/6

4 Other properties : Substance has neutral reaction. SECTION 10: Stability and reactivity Reactivity On burning: release of toxic and corrosive gases/vapours (phosphorus oxides, zinc oxide) Chemical stability Stable under normal conditions Possibility of hazardous reactions No dangerous reactions known under normal conditions of use Conditions to avoid None under recommended storage and handling conditions (see section 7) Incompatible materials Hazardous decomposition products On heating/burning: release of toxic and corrosive gases/vapors phosphorus oxides. Zinc oxide. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Symptoms/injuries after inhalation Symptoms/injuries after skin contact Symptoms/injuries after eye contact Symptoms/injuries after ingestion ph: 7 (10 %) ph: 7 (10 %) (Not applicable) : May cause respiratory irritation. : May cause moderate irritation. : May cause slight irritation. : Gastrointestinal complaints. SECTION 12: Ecological information Toxicity Ecology - general : Dangerous for the environment. Ecology - air as dangerous for the ozone layer (Regulation (EC) No 1005/2009). Ecology - water : Severe water pollutant (surface water). Ground water pollutant. Highly toxic to aquatic organisms. 10/28/2015 EN (English US) 4/6

5 12.2. Persistence and degradability Bioaccumulative potential Mobility in soil Other adverse effects Effect on the global warming : No known ecological damage caused by this product. SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT Not regulated for transport TDG : Remove waste in accordance with local and/or national regulations. Transport by sea UN-No. (IMDG) : 3077 Class (IMDG) : 9 - Miscellaneous dangerous compounds EmS-No. (1) : F-A EmS-No. (2) : S-F Air transport UN-No. (IATA) : 3077 Class (IATA) : 9 - Miscellaneous Dangerous Goods Packing group (IATA) : III - Minor Danger SECTION 15: Regulatory information US Federal regulations All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory This product or mixture does not contain a toxic chemical or chemicals in excess of the applicable de minimis concentration as specified in 40 CFR (a) subject to the reporting requirements of section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part International regulations CANADA EU-Regulations National regulations Zinc Phosphate Tribasic Tetrahydrate ( ) Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China) Listed on NZIoC (New Zealand Inventory of Chemicals) US State regulations 10/28/2015 EN (English US) 5/6

6 SECTION 16: Other information Indication of changes : This sheet was updated (refer to the date at the top of this page). Revision date : 10/28/2015 NFPA health hazard NFPA fire hazard NFPA reactivity : 0 - Exposure under fire conditions would offer no hazard beyond that of ordinary combustible materials. : 0 - Materials that will not burn. : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. HMIS III Rating Health Flammability Physical : 0 Minimal Hazard - No significant risk to health : 0 Minimal Hazard - Materials that will not burn : 0 Minimal Hazard - Materials that are normally stable, even under fire conditions, and will NOT react with water, polymerize, decompose, condense, or self-react. Non-Explosives. SDS US (GHS HazCom 2012) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 10/28/2015 EN (English US) 6/6