Safety Data Sheet (SDS) OSHA HazCom Standard 29 CFR (g), Rev and GHS Rev 03.

Transcription

1 Page 1/8 * 1 Identification Product identifier Product description Lubricant Details of the supplier of the safety data sheet Manufacturer/Supplier: Synco Chemical Corporation 24 DaVinci Drive P.O. Box 405 Bohemia, NY Phone: info@super-lube.com Emergency telephone number: United States UK - National Poisons Emergency: (24 hour - health professionals only) Ireland - National Poisons Information Centre: * 2 Hazard(s) identification Classification of the substance or mixture The product is not classified as hazardous according to the Globally Harmonized System (GHS). Label elements GHS label elements Non-Regulated Material Hazard pictograms Non-Regulated Material Signal word Non-Regulated Material Hazard statements Non-Regulated Material Classification system: NFPA ratings (scale 0-4) Health = 0 Fire = 0 Reactivity = 0 HMIS-ratings (scale 0-4) HEALTH FIRE REACTIVITY Health = 0 Fire = 0 Reactivity = 0 * 3 Composition/information on ingredients Octadecanoic acid, chlorinated <3% Lubrizol 5056 <1% Polyisobutylene <3% Chemical characterization: Mixtures Description: Mixture of the substances listed below with nonhazardous additions. Dangerous Components: Mineral Oil <50% Polyalphaolefin <30% Acute Tox. 2, H300 (Contd. on page 2)

2 Page 2/ Polybutylene Acute Tox. 4, H332 Trade Secret Skin Irrit. 2, H315; Eye Irrit. 2A, H319; H C11-14 Branched Alykamines Aquatic Chronic 2, H411; Skin Irrit. 2, H315; Eye Irrit. 2A, H319; H401 * 4 First-aid measures (Contd. of page 1) <20% <3% 2.5% Description of first aid measures After inhalation: Supply fresh air. If required, provide artificial respiration. Consult doctor if symptoms persist. After skin contact: Immediately wash with water and soap and rinse thoroughly. If irritation occurs consult a doctor. After eye contact: Rinse opened eye for at least 15 minutes under running water. If symptoms persist, consult a doctor. After swallowing: Do not induce vomiting; immediately call for medical help. Most important symptoms and effects, both acute and delayed No further relevant information available. Indication of any immediate medical attention and special treatment needed No further relevant information available. * 5 Fire-fighting measures Extinguishing media Suitable extinguishing agents: Carbon dioxide, dry chemical, foam Special hazards arising from the substance or mixture Thermal decomposition will produce toxic oxides of carbon Water spray may be ineffective. Water should be used to cool closed containers to prevent pressure build up and possible autoignition or explosion when exposed to extreme heat. Oil will float on water and can spread any fire. Advice for firefighters Protective equipment: As in any fire, wear self-contained breathing apparatus pressure-demand (NIOSH approved or equivalent), and full protective gear to prevent contact with skin and eyes. * 6 Accidental release measures Personal precautions, protective equipment and emergency procedures Not required. Environmental precautions: Do not allow to enter sewers/ surface or ground water. Harmful to aquatic organisms. Methods and material for containment and cleaning up: Remove all sources of ignition. Absorb with liquid-binding material (ie. sand, diatomite, acid binders, universal binders, sawdust). Ensure adequate ventilation. Dispose contaminated material as waste according to section 13. Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. (Contd. on page 3)

3 Page 3/8 * 7 Handling and storage (Contd. of page 2) Precautions for safe handling Avoid contact with skin, eyes and clothing Ensure good ventilation/exhaustion at the workplace. Avoid breathing fume/gas/mist/vapors/spray. Information about protection against explosions and fires: No special measures required. Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles: Store in a cool, dry place away from sparks and flame. Store in a well ventilated place. Information about storage in one common storage facility: Store away from oxidizing agents. Further information about storage conditions: Keep receptacle tightly sealed. Store in cool, dry conditions in well sealed receptacles. Specific end use(s) No further relevant information available. * 8 Exposure controls/personal protection Additional information about design of technical systems: No further data; see section 7. Control parameters Components with occupational exposure limits: Mineral Oil ACGIH TLV Short-term value: 10 mg/m³ Long-term value: 5 mg/m³ OSHA PEL Long-term value: 5 mg/m³ Polyalphaolefin ACGIH TLV Short term 5mg/m³ TWA (mist) Long term 10 mg/m³ STEL (mist) OSHA PEL Short term 5 mg/m³ Additional information: The lists that were valid during the creation were used as basis. Exposure controls Personal protective equipment: General protective and hygienic measures: Local exhaust ventilation is recommended when general ventilation is not sufficient to control airborne contamination below occupational exposure limits. Breathing equipment: NIOSH/MSHA or EN approved respiratory protection is recommended for use in airborne concentrations exceeding exposure limits. Protection of hands: Protective gloves Material of gloves Chemical resistant (Contd. on page 4)

4 Page 4/8 (Contd. of page 3) Penetration time of glove material The exact break-through time has to be determined and observed by the manufacturer of the protective gloves. Eye protection: Safety glasses with side shields * 9 Physical and chemical properties Information on basic physical and chemical properties General Information Appearance: Form: Liquid Color: Translucent Odor: Mild Odor threshold: ph-value: Change in condition Melting point/melting range: Boiling point/boiling range: Flash point: 232 C (450 F) Flammability (solid, gaseous): Not applicable. Ignition temperature: Decomposition temperature: Auto igniting: Product is not selfigniting. Danger of explosion: Product does not present an explosion hazard. Explosion limits: Lower: Upper: Vapor pressure: Density: Relative density Vapour density Heavier than air Evaporation rate Faster than ether Solubility in / Miscibility with Water: Nil Partition coefficient (n-octanol/water): Viscosity: Dynamic: Kinematic: Other information No further relevant information available. 10 Stability and reactivity Reactivity No further relevant information available. Chemical stability Stable under normal conditions. Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. Possibility of hazardous reactions No dangerous reactions known. (Contd. on page 5)

5 Page 5/8 Conditions to avoid Heat, flame and ignition sources. Incompatible materials: Strong oxidizing agents. Hazardous decomposition products: No dangerous decomposition products known. * 11 Toxicological information (Contd. of page 4) Information on toxicological effects Acute toxicity: LD/LC50 values that are relevant for classification: Trade Secret Oral LD50 >2000 mg/kg (rat) C11-14 Branched Alykamines Oral LD50 >2000 mg/kg (rat) Mineral Oil Oral LD50 >5000 mg/kg (rat) Primary irritant effect: on the skin: May be irritating. on the eye: May be irritating. Additional toxicological information: The product shows the following dangers according to internally approved calculation methods for preparations: Harmful Carcinogenic categories IARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to humans Group 2A - Probably carcinogenic to humans Group 2B - Possibly carcinogenic to humans Group 3 - Not classifiable as to its carcinogenicity to humans Group 4 - Probably not carcinogenic to humans NTP (National Toxicology Program) OSHA-Ca (Occupational Safety & Health Administration) * 12 Ecological information Toxicity Aquatic toxicity: Harmful to aquatic organisms. Persistence and degradability No further relevant information available. Bioaccumulative potential No further relevant information available. Mobility in soil No further relevant information available. Additional ecological information: General notes: Water hazard class 1 (Self-assessment): slightly hazardous for water Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable. Other adverse effects No further relevant information available. (Contd. on page 6)

6 Page 6/8 * 13 Disposal considerations (Contd. of page 5) Waste treatment methods Recommendation: Observe all federal, state and local environmental regulations when disposing of this material. Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. Uncleaned packagings: Recommendation: Disposal must be made according to official regulations. * 14 Transport information UN-Number DOT, ADR, ADN, IMDG, IATA Non-Regulated Material UN proper shipping name DOT, ADR, ADN, IMDG, IATA Non-Regulated Material Transport hazard class(es) DOT, ADR, ADN, IMDG, IATA Class Non-Regulated Material Packing group DOT, ADR, IMDG, IATA Non-Regulated Material Environmental hazards: Marine pollutant: No Special precautions for user Not applicable. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. Transport/Additional information: DOT Quantity limitations On passenger aircraft/rail: 5 L On cargo aircraft only: 60 L ADR Excepted quantities (EQ) Code: E0 Not permitted as Excepted Quantity IMDG Excepted quantities (EQ) Code: E4 Maximum net quantity per inner packaging: 1 ml Maximum net quantity per outer packaging: 500 ml UN "Model Regulation": - * 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Sara Section 355 (extremely hazardous substances): Section 313 (Specific toxic chemical listings): (Contd. on page 7)

7 Page 7/8 TSCA (Toxic Substances Control Act): Mineral Oil Polyalphaolefin Polybutylene Octadecanoic acid, chlorinated Polyisobutylene C11-14 Branched Alykamines Proposition 65 Chemicals known to cause cancer: Chemicals known to cause reproductive toxicity for females: Chemicals known to cause reproductive toxicity for males: Chemicals known to cause developmental toxicity: (Contd. of page 6) Carcinogenic categories EPA (Environmental Protection Agency) TLV (Threshold Limit Value established by ACGIH) NIOSH-Ca (National Institute for Occupational Safety and Health) GHS label elements Non-Regulated Material Hazard pictograms Non-Regulated Material Signal word Non-Regulated Material Hazard statements Non-Regulated Material National regulations: The product is subject to be labeled according with the prevailing version of the regulations on hazardous substances. State Right to Know Mineral Oil <50% Polyalphaolefin <30% Acute Tox. 2, H Polybutylene <20% Acute Tox. 4, H Octadecanoic acid, chlorinated <3% Trade Secret <3% Skin Irrit. 2, H315; Eye Irrit. 2A, H319; H Polyisobutylene <3% C11-14 Branched Alykamines <1% Aquatic Chronic 2, H411; Skin Irrit. 2, H315; Eye Irrit. 2A, H319; H401 Lubrizol 5056 <1% (Contd. on page 8)

8 Page 8/8 All ingredients are listed. Chemical safety assessment: A Chemical Safety Assessment has not been carried out. 16 Other information (Contd. of page 7) The information and recommendations in this safety data sheet are, to the best of our knowledge, accurate as of the date of issue. Nothing herein shall be deemed to create warranty, expressed or implied and shall not establish a legally valid contractual relationship. It is the responsibility of the user to determine applicability of this information and the suitability of the material or product for any particular purpose. Date of preparation / last revision 11/18/2014 / 16 Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) ADN: The European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association ACGIH: American Conference of Governmental Industrial Hygienists EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (USA) HMIS: Hazardous Materials Identification System (USA) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent Acute Tox. 2: Acute toxicity, Hazard Category 2 Acute Tox. 4: Acute toxicity, Hazard Category 4 Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2 Eye Irrit. 2A: Serious eye damage/eye irritation, Hazard Category 2A : Hazardous to the aquatic environment - AcuteHazard, Category 2 : Hazardous to the aquatic environment - AcuteHazard, Category 3 Aquatic Chronic 2: Hazardous to the aquatic environment - Chronic Hazard, Category 2 * Data compared to the previous version altered. SDS created by MSDS Authoring Services (877)